Effect of Ag, Pd and Co promoters on the Selective Catalytic Reduction (SCR) of NOx by ethanol over sulfated ceria-zirconia catalysts

2012 ◽  
Vol 191 (1) ◽  
pp. 65-74 ◽  
Author(s):  
Alexandre Westermann ◽  
Bruno Azambre ◽  
Alain Koch
2019 ◽  
Vol 9 (3) ◽  
pp. 718-730 ◽  
Author(s):  
Jian-Wen Shi ◽  
Yao Wang ◽  
Ruibin Duan ◽  
Chen Gao ◽  
Baorui Wang ◽  
...  

Non-manganese-based metal oxides are promising catalysts for the NH3-SCR (selective catalytic reduction) of NOx at low temperatures.


Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1035
Author(s):  
Baiyu Fan ◽  
Ziyin Zhang ◽  
Caixia Liu ◽  
Qingling Liu

The Fe/(SZr) and S(Fe/Zr) sulfated iron-based catalysts, prepared by impregnation methods through changing the loading order of Fe2O3 and SO42− on ZrO2, were investigated on selective catalytic reduction (SCR) of NOx by ammonia. It was studied that the existent forms of Fe2O3 and SO42− on the surface of catalysts were affected by the loading order. The Fe/(SZr) catalyst surface had isolated Fe2O3 and SO42− species and followed both the L-H mechanism and the E-R mechanism, whereas the S(Fe/Zr) catalyst contained SO42− specie and sulfate only and mainly followed the E-R pathway. These factors affected the redox ability and NH3 adsorption, which might be key to the SCR reaction.


2011 ◽  
Vol 356-360 ◽  
pp. 974-979 ◽  
Author(s):  
Xian Long Zhang ◽  
Bo Wen Shi ◽  
Xue Ping Wu ◽  
Wei Ping Jiang ◽  
Bao Jun Yang ◽  
...  

Palygorskite supported manganese oxide catalysts (MnOx/PG) were prepared for lower temperature selective catalytic reduction (SCR) of NOx by NH3. Catalyst’s SCR activity was estimated at varied temperatures. Catalyst’s properties were characterized by XRD, NH3adsorption and TPD. Results showed that MnOx/PG catalyst was highly active for SCR at low-temperature. It was also found that NH3 was mainly adsorbed on palygorskite in two forms. Weakly adsorbed NH3, which was seldom inhibited by loading of MnOx, but was more favorable to SCR. Whereas strongly adsorbed NH3was more likely to be inhibited by MnOx loading but was inessential for SCR.


ChemCatChem ◽  
2018 ◽  
Vol 10 (7) ◽  
pp. 1499-1511 ◽  
Author(s):  
Yu Liu ◽  
Jun Zhao ◽  
Jong-Min Lee

2019 ◽  
Vol 4 (6) ◽  
pp. 975-985 ◽  
Author(s):  
Ling Zhang ◽  
Qinming Wu ◽  
Xiangju Meng ◽  
Ulrich Müller ◽  
Mathias Feyen ◽  
...  

Metal-exchanged zeolites with small pore sizes have attracted much attention in recent years due to their application in the selective catalytic reduction (SCR) of NOx in diesel engines.


2013 ◽  
Vol 295-298 ◽  
pp. 364-369 ◽  
Author(s):  
Jun Lin Xie ◽  
Zheng Bing Fu ◽  
Feng He ◽  
De Fang

Amorphous phase MnOx/TiO2 catalysts were prepared by two different methods, their catalytic activities for low temperature selective catalytic reduction (SCR) of NOx with NH3 in the presence of excess oxygen were investigated. The catalysts were characterized by XRD, XPS and HRTEM. The results showed that the catalyst prepared by soft template method had better catalytic active than those prepared by sol-gel method, its catalytic property could reach 98.2% at 200°C. From the microstructure characterization, it could be known that the catalyst prepared by soft template had the shape of nanorod, this shape was contributed to the dispersion of the manganese oxides and possessed higher surface lattice oxygen concentration. Furthermore, narrow slit-shaped pores associated with rod-like particles could provide efficient transport pathways to reactant molecules and products. Due to these, the catalyst performed catalytic active very well.


Sign in / Sign up

Export Citation Format

Share Document