Preparation and characterization of ITQ-29/polysulfone mixed-matrix membranes for gas separation: Effect of zeolite composition and crystal size

2012 ◽  
Vol 73 ◽  
pp. 116-122 ◽  
Author(s):  
Clara Casado-Coterillo ◽  
Jaime Soto ◽  
María T. Jimaré ◽  
Susana Valencia ◽  
Avelino Corma ◽  
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2014 ◽  
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pp. 611-619 ◽  
Author(s):  
Haixiang Sun ◽  
Cheng Ma ◽  
Tao Wang ◽  
Yanyan Xu ◽  
Bingbing Yuan ◽  
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2013 ◽  
Vol 23 (6) ◽  
pp. 432-438
Author(s):  
Hye Rim Song ◽  
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Seung Eun Nam ◽  
Young Kyu Hwang ◽  
Jong San Chang ◽  
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Polymers ◽  
2018 ◽  
Vol 10 (1) ◽  
pp. 51 ◽  
Author(s):  
Fynn Weigelt ◽  
Prokopios Georgopanos ◽  
Sergey Shishatskiy ◽  
Volkan Filiz ◽  
Torsten Brinkmann ◽  
...  

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Mehtap Safak Boroglu ◽  
Ismail Boz ◽  
Busra Kaya

Abstract In our study, the synthesis of zeolitic imidazolate framework (ZIF-12) crystals and the preparation of mixed matrix membranes (MMMs) with various ZIF-12 loadings were targeted. The characterization of ZIF-12 and MMMs were carried out by Fourier transform infrared spectroscopy analysis, thermogravimetric analysis, scanning electron microscopy (SEM), and thermomechanical analysis. The performance of MMMs was measured by the ability of binary gas separation. Commercial polyetherimide (PEI-Ultem® 1000) polymer was used as the polymer matrix. The solution casting method was utilized to obtain dense MMMs. In the SEM images of ZIF-12 particles, the particles with a rhombic dodecahedron structure were identified. From SEM images, it was observed that the distribution of ZIF-12 particles in the MMMs was homogeneous and no agglomeration was present. Gas permeability experiments of MMMs were measured for H2, CO2, and CH4 gases at steady state, at 4 bar and 35 °C by constant volume-variable pressure method. PEI/ZIF-12-30 wt% MMM exhibited high permeability and ideal selectivity values for H2/CH4 and CO2/CH4 were P H 2 / CH 4 = 331.41 ${P}_{{\text{H}}_{2}/{\text{CH}}_{4}}=331.41$ and P CO 2 / CH 4 = 53.75 ${P}_{{\text{CO}}_{2}/{\text{CH}}_{4}}=53.75$ gas pair.


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