Review of Recent Developments of Glass Transition in PVC Nanocomposites

This review addresses the impact of different nanoadditives on the glass transition temperature (Tg) of polyvinyl chloride (PVC), which is a widely used industrial polymer. The relatively high Tg limits its temperature-dependent applications. The objective of the review is to present the state-of-the-art knowledge on the influence of nanofillers of various origins and dimensions on the Tg of the PVC. The Tg variations induced by added nanofillers can be probed mostly by such experimental techniques as thermomechanical analysis (TMA), dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), and dielectric thermal analysis (DETA). The increase in Tg is commonly associated with the use of mineral and carbonaceous nanofillers. In this case, a rise in the concentration of nanoadditives leads to an increase in the Tg due to a restraint of the PVC macromolecular chain’s mobility. The lowering of Tg may be attributed to the well-known plasticizing effect, which is a consequence of the incorporation of oligomeric silsesquioxanes to the polymeric matrix. It has been well established that the variation in the Tg value depends also on the chemical modification of nanofillers and their incorporation into the PVC matrix. This review may be an inspiration for further investigation of nanofillers’ effect on the PVC glass transition temperature.

Experimental approach to modeling of the plasticizing operation in the hot plate welding process

The paper discusses the topic of butt welding of polyurethane drive belts by the hot plate method in the context of modeling the process of this technological operation. Based on the analysis of the butt welding process, a series of studies of the thermomechanical properties of the material from which the belt is made has been planned. The results will be used for mathematical modeling of the welding process, and in particular its most important phase: the plasticizing operation. On this basis, the study of the compression of cylindrical specimens taken from the belt has been performed at two different speeds. Their result is the relationship between the compressive stress σc and the modulus of longitudinal elasticity Ec at compression and: deformation εc, temperature value T, as well as the compressive velocity vc. In the next step, dynamic viscosity η of the belt material was determined based on the results of dynamic thermomechanical analysis. The research work culminated in the attempts to plasticize the material on a hot plate, in conditions similar to the process of industrial welding. These studies were performed at different speeds vpl, resulting in the correlation between the force required for plasticizing Fpl and the value of the speed of the belt end vpl relative to the hot plate heated to a temperature Tp. The obtained results will be used to formulate a mathematical model of plasticizing the material, based on the selected mechanical deformation models.

Design and Development of a Micro-LDH Apparatus to Determine Formability of Sheet Metal Under Hot Stamping Conditions Using Gleeble

In the last few years, demand for hot stamped components has increased in the automotive industry. Determination of formability under hot stamping is challenging due to elevated temperature, fast cooling and high punch velocity. Although there was various strive for formability determination but had limitations with experiments like non-uniform heating of specimen, non-uniform strain and temperature distribution. Therefore, in this work, an experimental apparatus was developed to determine formability at room temperature, high temperature, hot stamping conditions, and any complex process cycle involving heating and cooling. New specimen was designed to produce different strain paths, uniform and homogenous temperature distribution with the help of FEM software using thermomechanical and thermoelectrical simulation. A micro hemispherical dome based experimental apparatus was designed using Solidworks. The designed apparatus was used in conjunction with the thermo-mechanical simulator (Gleeble-3800). Thermomechanical analysis was done in PAM STAMP software to optimize specimen size and shape to get uniform strain distribution and different strain paths. A thermoelectric FEM model was developed using Abaqus 6.14 to optimize the temperature distribution in the specimen. The developed model enables choosing the appropriate polarity of the electrical cable connection to achieve uniform temperature distribution in the specimen. Strain path and temperature profiles for experiment and simulation were compared. Further, a forming limit curve was developed using the designed apparatus to verify the feasibility of the apparatus. For feasibility test of apparatus, hot stamping process was selected. This new design apparatus can be used for a range of temperatures up to 1000 °C, hot stamping conditions, and for different materials (aluminium, magnesium alloys, different grade of steel, etc.). It concludes that the connection of different polarities of electrical cable was critical for homogenous and uniform temperature distribution in specimens.