scholarly journals Tracing the evolution of calc-alkaline magmas: In-situ Sm–Nd isotope studies of accessory minerals in the Bergell Igneous Complex, Italy

2009 ◽  
Vol 260 (1-2) ◽  
pp. 73-86 ◽  
Author(s):  
Courtney J. Gregory ◽  
Christopher R.M. McFarlane ◽  
Jörg Hermann ◽  
Daniela Rubatto
2020 ◽  
Author(s):  
Johannes Hammerli

<p>The long-lived radiogenic isotope systems Lu-Hf and Sm-Nd have been widely used by geochemists to study magma sources and crustal residential times of (igneous) rocks in order to understand how early crust formed and to model the production rate and volume of continental crust on global and regional-scales during the last ~4.4 Ga. However, while throughout most of Earth’s history Nd and Hf isotope signatures in terrestrial rocks are well correlated due to their very similar geochemical behavior, some of Earth’s oldest rocks show an apparent inconsistency in their Nd and Hf isotope signatures. While Hf isotopes in early Archean rocks are generally (near) chondritic, Nd isotope signatures can be distinctly super- or sub-chondritic. The super-chondritic Nd isotope values in Eoarchean samples would suggest that these rocks are derived from a mantle reservoir depleted by prior crust extraction. The chondritic Hf isotope values, on the other hand, support a mantle source from which no significant volume of crust had been extracted. While a range of different processes, some of them speculative, might explain this Hf-Nd isotope paradox, recent research [1, 2] has shown that relatively simple, post-magmatic, open-system processes can explain decoupling of the typically correlative Hf-Nd isotope signatures. This talk will focus on the importance of identifying Nd-bearing accessory minerals in (Archean) rocks to understand how the Sm-Nd isotope system is controlled and how in situ isotope and trace element analyses by LA-(MC)-ICP-MS in combination with detailed petrographic observations help to understand when and via which processes the two isotope systems become decoupled. Reconstructing the isotopic evolution of the different isotope systems since formation of the protoliths has important implications for our understanding of early crust formation and questions some of the proposed current models for early crust extraction from the mantle.</p><p> </p><p>[1] Hammerli et al. (2019) Chem. Geol 2; [2] Fisher et al. (2020) EPSL</p>


2020 ◽  
Vol 117 (35) ◽  
pp. 21125-21131 ◽  
Author(s):  
Jing-Liang Guo ◽  
Zaicong Wang ◽  
Wen Zhang ◽  
Frédéric Moynier ◽  
Dandan Cui ◽  
...  

Zircons widely occur in magmatic rocks and often display internal zonation finely recording the magmatic history. Here, we presented in situ high-precision (2SD <0.15‰ for δ94Zr) and high–spatial-resolution (20 µm) stable Zr isotope compositions of magmatic zircons in a suite of calc-alkaline plutonic rocks from the juvenile part of the Gangdese arc, southern Tibet. These zircon grains are internally zoned with Zr isotopically light cores and increasingly heavier rims. Our data suggest the preferential incorporation of lighter Zr isotopes in zircon from the melt, which would drive the residual melt to heavier values. The Rayleigh distillation model can well explain the observed internal zoning in single zircon grains, and the best-fit models gave average zircon–melt fractionation factors for each sample ranging from 0.99955 to 0.99988. The average fractionation factors are positively correlated with the median Ti-in-zircon temperatures, indicating a strong temperature dependence of Zr isotopic fractionation. The results demonstrate that in situ Zr isotope analyses would be another powerful contribution to the geochemical toolbox related to zircon. The findings of this study solve the fundamental issue on how zircon fractionates Zr isotopes in calc-alkaline magmas, the major type of magmas that led to forming continental crust over time. The results also show the great potential of stable Zr isotopes in tracing magmatic thermal and chemical evolution and thus possibly continental crustal differentiation.


1994 ◽  
Vol 151 (5) ◽  
pp. 815-823 ◽  
Author(s):  
S. J. MATTHEWS ◽  
A. P. JONES ◽  
A. D. BEARD

2021 ◽  
Author(s):  
◽  
Jürgen Österle

<p>The Suckling-Dayman metamorphic core complex (SDMCC) in the Woodlark Rift of southeastern Papua New Guinea is being exhumed along the Mai’iu Fault, an active low-angle normal fault dipping ~20-22° northwards at the surface. The spectacularly smooth topography of the Mai’iu Fault footwall clearly is expressive of geologically recent uplift. The precise timing and rates of the exhumation of this continental metamorphic core complex (MCC) have, however, never been studied in detail. This thesis provides the first systematic set of U-Pb, fission track (FT), (U-Th[-Sm])/He and ²⁶Al/¹⁰Be ages from metaigneous and metasedimentary rocks of the footwall of the SDMCC, clasts and a tephra deposit contained within syn-tectonic conglomerates (the Gwoira Conglomerate) in a rider block, and modern stream sediments in the footwall and hanging wall of the Mai’iu Fault. The ages are complemented by whole-rock compositional and thermobarometric data (Al-in-amphibole, Al-in-biotite, Raman spectroscopy of carbonaceous material). Based on these data, the timing of the onset of extension along the Mai’iu Fault, its long-term dip-slip rate and its initial dip were constrained. These data are presented in the context of the evolution of the SDMCC from the Cretaceous to the present.  The dominant lithology of the SDMCC, the Goropu Metabasalt, formed in a marginal basin to the northeast of the Australian continent. Two zircon U-Pb ages of 103.0 ± 5.7 and 71.6 ± 3.3 Ma, indicative of maximum depositional ages, from metasedimentary intercalations (the Bonenau Schist) in the Goropu Metabasalt, suggest formation of the oceanic protolith in the Late Cretaceous. Between 60.4 ± 2.5 and 56.6 ± 2.3 Ma (zircon U-Pb), tholeiitic to mildly calc-alkaline gabbroic to tonalitic rocks of the Yau Igneous Complex intruded the Goropu Metabasalt. The age of the Yau Igneous Complex overlaps with the known timing of north-directed subduction of the oceanic lithosphere along the Owen Stanley Fault (OSF) beneath the Cape Vogel Arc and provides a minimum age for the oceanic protolith.  A second phase of magmatism, consisting of peraluminous-metaluminous calc-alkaline (Suckling Granite) and high-K (Mai’iu Monzonite, Bonua Porphyry) granitoids and basaltic andesite dikes that were cut by the Mai’iu Fault, was associated with the tectonic inversion of the OSF. Zircons from these syn-extensional intrusions suggest crystallization between 3.8 ± 0.2 and 2.0 ± 0.1 Ma. The oldest age of this range is inferred to mark the time by which the OSF had been re-activated as an extensional structure, the Mai’iu Fault. Al-in-amphibole and -biotite thermobarometry suggests crystallization of the Suckling Granite and Mai’iu Monzonite in a relatively shallow crust (~2-8 km depth) at pressures of ~0.4-2.3 kbar. Inherited zircons in the Plio-Pleistocene granitoids indicate that the Goropu Metabasalt carapace of the SDMCC is underlain by Australian-derived Cretaceous crustal material that is inferred to be the continuation of the Kagi Metamorphics in the central Papuan Peninsula.  Further constraints of the timing of unroofing of the SDMCC were determined from three quartz clasts in the Gwoira Conglomerate. ²⁶Al/¹⁰Be burial ages of these samples indicate deposition in the Pliocene between 4.6 ± 2.9 and 3.4 ± 2.1 Ma. A tephra in the upper section of the exposed conglomerates was dated employing U-Pb methods on zircon, combined with apatite, zircon and magnetite (U-Th[-Sm])/He chronometers, yielding a complex age spectrum. An eruption age of 0.6 ± 0.4 Ma was extrapolated for this tephra. FT and (U-Th[-Sm])/He low-temperature thermochronometry details a young (≤3 Ma) and rapid exhumation history. Based on the crystallization ages of the syn-extensional granitoids, the depositional age of the Gwoira Conglomerate, the extensional cooling recorded by low-temperature thermochronometry, and the backwards projection of the published Holocene dip-slip rate of the Mai’iu Fault, the timing of the onset of extension is estimated at ~4 Ma.  A minimum dip-slip rate of 8.1 ± 1.3 km/myr has been calculated from the inverse slope of zircon (U-Th)/He (ZHe) ages with slip-parallel distance from Mai’iu Fault trace. This is slightly lower than the >12 km/myr required to restore the intrusion depths (2-8 km) of the syn-extensional granitoids, now exposed 20-25 km south of the Mai’iu Fault trace at elevations up to 3.4 km. Collectively, these constraints suggest that the Mai’iu Fault has moved at cm-per-year rates since ~3 Ma.  Evidence for both a fossil zircon FT (ZFT) partial annealing zone (PAZ) and a ZHe partial retention zone (PRZ) on the footwall of the SDMCC is presented. Combining paleo-temperature estimates from the inferred bases of the zircon PAZ and PRZ, peak-metamorphic temperatures inferred from Raman spectroscopy of carbonaceous material (RSCM), and published peak-metamorphic temperature constraints on the extensional shear zone mylonites near the Mai’iu Fault trace, a minimum slip-parallel, down-dip paleo-temperature gradient of 9.7 ± 2.2°C/km has been estimated for the exhumed Mai’iu Fault plane. Assuming that the modern regional geothermal gradient in the Woodlark Rift is a maximum estimate of that which existed prior to extensional exhumation of the SDMCC, the paleo-temperature gradient was used to estimate an average initial dip of the Mai’iu Fault of ~44° for pre-extensional geothermal gradients ranging between 10 to 20°C/km. Presently dipping 20-22° at the surface, the constraints on the initial dip suggest that the Mai’iu Fault may have been back-rotated by >20° since the onset of extension, consistent with a rolling hinge-style evolution of this continental MCC.</p>


2021 ◽  
Author(s):  
◽  
Jürgen Österle

<p>The Suckling-Dayman metamorphic core complex (SDMCC) in the Woodlark Rift of southeastern Papua New Guinea is being exhumed along the Mai’iu Fault, an active low-angle normal fault dipping ~20-22° northwards at the surface. The spectacularly smooth topography of the Mai’iu Fault footwall clearly is expressive of geologically recent uplift. The precise timing and rates of the exhumation of this continental metamorphic core complex (MCC) have, however, never been studied in detail. This thesis provides the first systematic set of U-Pb, fission track (FT), (U-Th[-Sm])/He and ²⁶Al/¹⁰Be ages from metaigneous and metasedimentary rocks of the footwall of the SDMCC, clasts and a tephra deposit contained within syn-tectonic conglomerates (the Gwoira Conglomerate) in a rider block, and modern stream sediments in the footwall and hanging wall of the Mai’iu Fault. The ages are complemented by whole-rock compositional and thermobarometric data (Al-in-amphibole, Al-in-biotite, Raman spectroscopy of carbonaceous material). Based on these data, the timing of the onset of extension along the Mai’iu Fault, its long-term dip-slip rate and its initial dip were constrained. These data are presented in the context of the evolution of the SDMCC from the Cretaceous to the present.  The dominant lithology of the SDMCC, the Goropu Metabasalt, formed in a marginal basin to the northeast of the Australian continent. Two zircon U-Pb ages of 103.0 ± 5.7 and 71.6 ± 3.3 Ma, indicative of maximum depositional ages, from metasedimentary intercalations (the Bonenau Schist) in the Goropu Metabasalt, suggest formation of the oceanic protolith in the Late Cretaceous. Between 60.4 ± 2.5 and 56.6 ± 2.3 Ma (zircon U-Pb), tholeiitic to mildly calc-alkaline gabbroic to tonalitic rocks of the Yau Igneous Complex intruded the Goropu Metabasalt. The age of the Yau Igneous Complex overlaps with the known timing of north-directed subduction of the oceanic lithosphere along the Owen Stanley Fault (OSF) beneath the Cape Vogel Arc and provides a minimum age for the oceanic protolith.  A second phase of magmatism, consisting of peraluminous-metaluminous calc-alkaline (Suckling Granite) and high-K (Mai’iu Monzonite, Bonua Porphyry) granitoids and basaltic andesite dikes that were cut by the Mai’iu Fault, was associated with the tectonic inversion of the OSF. Zircons from these syn-extensional intrusions suggest crystallization between 3.8 ± 0.2 and 2.0 ± 0.1 Ma. The oldest age of this range is inferred to mark the time by which the OSF had been re-activated as an extensional structure, the Mai’iu Fault. Al-in-amphibole and -biotite thermobarometry suggests crystallization of the Suckling Granite and Mai’iu Monzonite in a relatively shallow crust (~2-8 km depth) at pressures of ~0.4-2.3 kbar. Inherited zircons in the Plio-Pleistocene granitoids indicate that the Goropu Metabasalt carapace of the SDMCC is underlain by Australian-derived Cretaceous crustal material that is inferred to be the continuation of the Kagi Metamorphics in the central Papuan Peninsula.  Further constraints of the timing of unroofing of the SDMCC were determined from three quartz clasts in the Gwoira Conglomerate. ²⁶Al/¹⁰Be burial ages of these samples indicate deposition in the Pliocene between 4.6 ± 2.9 and 3.4 ± 2.1 Ma. A tephra in the upper section of the exposed conglomerates was dated employing U-Pb methods on zircon, combined with apatite, zircon and magnetite (U-Th[-Sm])/He chronometers, yielding a complex age spectrum. An eruption age of 0.6 ± 0.4 Ma was extrapolated for this tephra. FT and (U-Th[-Sm])/He low-temperature thermochronometry details a young (≤3 Ma) and rapid exhumation history. Based on the crystallization ages of the syn-extensional granitoids, the depositional age of the Gwoira Conglomerate, the extensional cooling recorded by low-temperature thermochronometry, and the backwards projection of the published Holocene dip-slip rate of the Mai’iu Fault, the timing of the onset of extension is estimated at ~4 Ma.  A minimum dip-slip rate of 8.1 ± 1.3 km/myr has been calculated from the inverse slope of zircon (U-Th)/He (ZHe) ages with slip-parallel distance from Mai’iu Fault trace. This is slightly lower than the >12 km/myr required to restore the intrusion depths (2-8 km) of the syn-extensional granitoids, now exposed 20-25 km south of the Mai’iu Fault trace at elevations up to 3.4 km. Collectively, these constraints suggest that the Mai’iu Fault has moved at cm-per-year rates since ~3 Ma.  Evidence for both a fossil zircon FT (ZFT) partial annealing zone (PAZ) and a ZHe partial retention zone (PRZ) on the footwall of the SDMCC is presented. Combining paleo-temperature estimates from the inferred bases of the zircon PAZ and PRZ, peak-metamorphic temperatures inferred from Raman spectroscopy of carbonaceous material (RSCM), and published peak-metamorphic temperature constraints on the extensional shear zone mylonites near the Mai’iu Fault trace, a minimum slip-parallel, down-dip paleo-temperature gradient of 9.7 ± 2.2°C/km has been estimated for the exhumed Mai’iu Fault plane. Assuming that the modern regional geothermal gradient in the Woodlark Rift is a maximum estimate of that which existed prior to extensional exhumation of the SDMCC, the paleo-temperature gradient was used to estimate an average initial dip of the Mai’iu Fault of ~44° for pre-extensional geothermal gradients ranging between 10 to 20°C/km. Presently dipping 20-22° at the surface, the constraints on the initial dip suggest that the Mai’iu Fault may have been back-rotated by >20° since the onset of extension, consistent with a rolling hinge-style evolution of this continental MCC.</p>


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