The Coles Hill Uranium Deposit, Virginia, USA: Geology, Geochemistry, Geochronology, and Genetic Model

The Coles Hill uranium deposit, with an indicated resource of about 130 Mlb of U3O8, is the largest unmined uranium deposit in the United States. The deposit is hosted in the Taconian (approx. 480–450 Ma) Martinsville igneous complex, which consists of the Ordovician Leatherwood Granite (granodiorite) and the Silurian Rich Acres Formation (diorite). The host rock was metamorphosed to orthogneiss during the Alleghanian orogeny (approx. 325–260 Ma), when it also underwent dextral strike-slip movement along the Brookneal shear zone. During the Triassic, extensional tectonics led to the development of the Dan River Basin that lies east of Coles Hill. The mineralized zone is hosted in brittle structures in the footwall of the Triassic Chatham fault that forms the western edge of the basin. Within brittle fracture zones, uranium silicate and uranium-bearing fluorapatite with traces of brannerite form veins and breccia-fill with chlorite, quartz, titanium oxide, pyrite, and calcite. Uranium silicates also coat and replace primary titanite, zircon, ilmenite, and sulfides. Sodium metasomatism preceded and accompanied uranium mineralization, pervasively altering host rock and forming albite from primary feldspar, depositing limpid albite rims on igneous feldspar, altering titanite to titanium oxide and calcite, and forming riebeckite. Various geothermometers indicate temperatures of less than ~200°C during mineralization. In situ U-Pb analyses of titanite, Ti-oxide, and apatite, along with Rb/Sr and U/Pb isotope systematics of whole-rock samples, resolve the timing of geologic processes affecting Coles Hill. The host Leatherwood Granite containing primary euhedral titanite is dated at 450 to 445 Ma, in agreement with previously obtained ages from zircon in the Martinsville igneous complex. A regional metamorphic event at 330 to 310 Ma formed anhedral titanite and some apatite, reequilibrated whole-rock Rb/Sr and U-Pb isotopes, and is interpreted to have coincided with movement along the Brookneal shear zone. During shearing and metamorphism, primary refractory uranium-bearing minerals including titanite, zircon, and uranothorite were recrystallized, and uranium was liberated and mixed locally with hematite, clay, and other fine-grained minerals. Uranium mineralization was accompanied by a metasomatic episode between 250 and 200 Ma that reset the Rb-Sr and U-Pb isotope systems and formed titanium oxide and apatite that are associated and, in places, intimately intergrown with uranium silicate dating mineralization. This event coincides with rifting that formed the Dan River Basin and was a precursor to the breakup of Pangea. The orientation of late-stage tectonic stylolites is compatible with their formation during Late Triassic to Early Jurassic basin inversion, postdating the main stage of uranium mineralization and effectively dating mineralization as Mesozoic. Based on the close spatial and temporal association of uranium with apatite, we propose that uranium was carried as a uranyl-phosphate complex. Uranium was locally reduced by coupled redox reactions with ferrous iron and sulfide minerals in the host rock, forming uranium silicates. The release of calcium during sodium metasomatic alteration of primary calcic feldspar and titanite in the host rock initiated successive reactions in which uranium and phosphate in mineralizing fluids combined with calcium to form U-enriched fluorapatite. Based on the deposit mineralogy, oxygen isotope geochemistry, and trace element characteristics of uranium silicate and gangue minerals, the primary mineralizing fluids likely included connate and/or meteoric water sourced from the adjacent Dan River Basin. High heat flow related to Mesozoic rifting may have driven these (P-Na-F-rich) fluids through local aquifers and into basin margin faults, transporting uranium from the basin or mobilizing uranium from previously formed U minerals in the Brookneal shear zone, or from U-enriched older basement rock.

The thermo-tectonic evolution of the Suckling-Dayman metamorphic core complex, southeastern Papua New Guinea

<p>The Suckling-Dayman metamorphic core complex (SDMCC) in the Woodlark Rift of southeastern Papua New Guinea is being exhumed along the Mai’iu Fault, an active low-angle normal fault dipping ~20-22° northwards at the surface. The spectacularly smooth topography of the Mai’iu Fault footwall clearly is expressive of geologically recent uplift. The precise timing and rates of the exhumation of this continental metamorphic core complex (MCC) have, however, never been studied in detail. This thesis provides the first systematic set of U-Pb, fission track (FT), (U-Th[-Sm])/He and ²⁶Al/¹⁰Be ages from metaigneous and metasedimentary rocks of the footwall of the SDMCC, clasts and a tephra deposit contained within syn-tectonic conglomerates (the Gwoira Conglomerate) in a rider block, and modern stream sediments in the footwall and hanging wall of the Mai’iu Fault. The ages are complemented by whole-rock compositional and thermobarometric data (Al-in-amphibole, Al-in-biotite, Raman spectroscopy of carbonaceous material). Based on these data, the timing of the onset of extension along the Mai’iu Fault, its long-term dip-slip rate and its initial dip were constrained. These data are presented in the context of the evolution of the SDMCC from the Cretaceous to the present. The dominant lithology of the SDMCC, the Goropu Metabasalt, formed in a marginal basin to the northeast of the Australian continent. Two zircon U-Pb ages of 103.0 ± 5.7 and 71.6 ± 3.3 Ma, indicative of maximum depositional ages, from metasedimentary intercalations (the Bonenau Schist) in the Goropu Metabasalt, suggest formation of the oceanic protolith in the Late Cretaceous. Between 60.4 ± 2.5 and 56.6 ± 2.3 Ma (zircon U-Pb), tholeiitic to mildly calc-alkaline gabbroic to tonalitic rocks of the Yau Igneous Complex intruded the Goropu Metabasalt. The age of the Yau Igneous Complex overlaps with the known timing of north-directed subduction of the oceanic lithosphere along the Owen Stanley Fault (OSF) beneath the Cape Vogel Arc and provides a minimum age for the oceanic protolith. A second phase of magmatism, consisting of peraluminous-metaluminous calc-alkaline (Suckling Granite) and high-K (Mai’iu Monzonite, Bonua Porphyry) granitoids and basaltic andesite dikes that were cut by the Mai’iu Fault, was associated with the tectonic inversion of the OSF. Zircons from these syn-extensional intrusions suggest crystallization between 3.8 ± 0.2 and 2.0 ± 0.1 Ma. The oldest age of this range is inferred to mark the time by which the OSF had been re-activated as an extensional structure, the Mai’iu Fault. Al-in-amphibole and -biotite thermobarometry suggests crystallization of the Suckling Granite and Mai’iu Monzonite in a relatively shallow crust (~2-8 km depth) at pressures of ~0.4-2.3 kbar. Inherited zircons in the Plio-Pleistocene granitoids indicate that the Goropu Metabasalt carapace of the SDMCC is underlain by Australian-derived Cretaceous crustal material that is inferred to be the continuation of the Kagi Metamorphics in the central Papuan Peninsula. Further constraints of the timing of unroofing of the SDMCC were determined from three quartz clasts in the Gwoira Conglomerate. ²⁶Al/¹⁰Be burial ages of these samples indicate deposition in the Pliocene between 4.6 ± 2.9 and 3.4 ± 2.1 Ma. A tephra in the upper section of the exposed conglomerates was dated employing U-Pb methods on zircon, combined with apatite, zircon and magnetite (U-Th[-Sm])/He chronometers, yielding a complex age spectrum. An eruption age of 0.6 ± 0.4 Ma was extrapolated for this tephra. FT and (U-Th[-Sm])/He low-temperature thermochronometry details a young (≤3 Ma) and rapid exhumation history. Based on the crystallization ages of the syn-extensional granitoids, the depositional age of the Gwoira Conglomerate, the extensional cooling recorded by low-temperature thermochronometry, and the backwards projection of the published Holocene dip-slip rate of the Mai’iu Fault, the timing of the onset of extension is estimated at ~4 Ma. A minimum dip-slip rate of 8.1 ± 1.3 km/myr has been calculated from the inverse slope of zircon (U-Th)/He (ZHe) ages with slip-parallel distance from Mai’iu Fault trace. This is slightly lower than the >12 km/myr required to restore the intrusion depths (2-8 km) of the syn-extensional granitoids, now exposed 20-25 km south of the Mai’iu Fault trace at elevations up to 3.4 km. Collectively, these constraints suggest that the Mai’iu Fault has moved at cm-per-year rates since ~3 Ma. Evidence for both a fossil zircon FT (ZFT) partial annealing zone (PAZ) and a ZHe partial retention zone (PRZ) on the footwall of the SDMCC is presented. Combining paleo-temperature estimates from the inferred bases of the zircon PAZ and PRZ, peak-metamorphic temperatures inferred from Raman spectroscopy of carbonaceous material (RSCM), and published peak-metamorphic temperature constraints on the extensional shear zone mylonites near the Mai’iu Fault trace, a minimum slip-parallel, down-dip paleo-temperature gradient of 9.7 ± 2.2°C/km has been estimated for the exhumed Mai’iu Fault plane. Assuming that the modern regional geothermal gradient in the Woodlark Rift is a maximum estimate of that which existed prior to extensional exhumation of the SDMCC, the paleo-temperature gradient was used to estimate an average initial dip of the Mai’iu Fault of ~44° for pre-extensional geothermal gradients ranging between 10 to 20°C/km. Presently dipping 20-22° at the surface, the constraints on the initial dip suggest that the Mai’iu Fault may have been back-rotated by >20° since the onset of extension, consistent with a rolling hinge-style evolution of this continental MCC.</p>

The thermo-tectonic evolution of the Suckling-Dayman metamorphic core complex, southeastern Papua New Guinea

<p>The Suckling-Dayman metamorphic core complex (SDMCC) in the Woodlark Rift of southeastern Papua New Guinea is being exhumed along the Mai’iu Fault, an active low-angle normal fault dipping ~20-22° northwards at the surface. The spectacularly smooth topography of the Mai’iu Fault footwall clearly is expressive of geologically recent uplift. The precise timing and rates of the exhumation of this continental metamorphic core complex (MCC) have, however, never been studied in detail. This thesis provides the first systematic set of U-Pb, fission track (FT), (U-Th[-Sm])/He and ²⁶Al/¹⁰Be ages from metaigneous and metasedimentary rocks of the footwall of the SDMCC, clasts and a tephra deposit contained within syn-tectonic conglomerates (the Gwoira Conglomerate) in a rider block, and modern stream sediments in the footwall and hanging wall of the Mai’iu Fault. The ages are complemented by whole-rock compositional and thermobarometric data (Al-in-amphibole, Al-in-biotite, Raman spectroscopy of carbonaceous material). Based on these data, the timing of the onset of extension along the Mai’iu Fault, its long-term dip-slip rate and its initial dip were constrained. These data are presented in the context of the evolution of the SDMCC from the Cretaceous to the present. The dominant lithology of the SDMCC, the Goropu Metabasalt, formed in a marginal basin to the northeast of the Australian continent. Two zircon U-Pb ages of 103.0 ± 5.7 and 71.6 ± 3.3 Ma, indicative of maximum depositional ages, from metasedimentary intercalations (the Bonenau Schist) in the Goropu Metabasalt, suggest formation of the oceanic protolith in the Late Cretaceous. Between 60.4 ± 2.5 and 56.6 ± 2.3 Ma (zircon U-Pb), tholeiitic to mildly calc-alkaline gabbroic to tonalitic rocks of the Yau Igneous Complex intruded the Goropu Metabasalt. The age of the Yau Igneous Complex overlaps with the known timing of north-directed subduction of the oceanic lithosphere along the Owen Stanley Fault (OSF) beneath the Cape Vogel Arc and provides a minimum age for the oceanic protolith. A second phase of magmatism, consisting of peraluminous-metaluminous calc-alkaline (Suckling Granite) and high-K (Mai’iu Monzonite, Bonua Porphyry) granitoids and basaltic andesite dikes that were cut by the Mai’iu Fault, was associated with the tectonic inversion of the OSF. Zircons from these syn-extensional intrusions suggest crystallization between 3.8 ± 0.2 and 2.0 ± 0.1 Ma. The oldest age of this range is inferred to mark the time by which the OSF had been re-activated as an extensional structure, the Mai’iu Fault. Al-in-amphibole and -biotite thermobarometry suggests crystallization of the Suckling Granite and Mai’iu Monzonite in a relatively shallow crust (~2-8 km depth) at pressures of ~0.4-2.3 kbar. Inherited zircons in the Plio-Pleistocene granitoids indicate that the Goropu Metabasalt carapace of the SDMCC is underlain by Australian-derived Cretaceous crustal material that is inferred to be the continuation of the Kagi Metamorphics in the central Papuan Peninsula. Further constraints of the timing of unroofing of the SDMCC were determined from three quartz clasts in the Gwoira Conglomerate. ²⁶Al/¹⁰Be burial ages of these samples indicate deposition in the Pliocene between 4.6 ± 2.9 and 3.4 ± 2.1 Ma. A tephra in the upper section of the exposed conglomerates was dated employing U-Pb methods on zircon, combined with apatite, zircon and magnetite (U-Th[-Sm])/He chronometers, yielding a complex age spectrum. An eruption age of 0.6 ± 0.4 Ma was extrapolated for this tephra. FT and (U-Th[-Sm])/He low-temperature thermochronometry details a young (≤3 Ma) and rapid exhumation history. Based on the crystallization ages of the syn-extensional granitoids, the depositional age of the Gwoira Conglomerate, the extensional cooling recorded by low-temperature thermochronometry, and the backwards projection of the published Holocene dip-slip rate of the Mai’iu Fault, the timing of the onset of extension is estimated at ~4 Ma. A minimum dip-slip rate of 8.1 ± 1.3 km/myr has been calculated from the inverse slope of zircon (U-Th)/He (ZHe) ages with slip-parallel distance from Mai’iu Fault trace. This is slightly lower than the >12 km/myr required to restore the intrusion depths (2-8 km) of the syn-extensional granitoids, now exposed 20-25 km south of the Mai’iu Fault trace at elevations up to 3.4 km. Collectively, these constraints suggest that the Mai’iu Fault has moved at cm-per-year rates since ~3 Ma. Evidence for both a fossil zircon FT (ZFT) partial annealing zone (PAZ) and a ZHe partial retention zone (PRZ) on the footwall of the SDMCC is presented. Combining paleo-temperature estimates from the inferred bases of the zircon PAZ and PRZ, peak-metamorphic temperatures inferred from Raman spectroscopy of carbonaceous material (RSCM), and published peak-metamorphic temperature constraints on the extensional shear zone mylonites near the Mai’iu Fault trace, a minimum slip-parallel, down-dip paleo-temperature gradient of 9.7 ± 2.2°C/km has been estimated for the exhumed Mai’iu Fault plane. Assuming that the modern regional geothermal gradient in the Woodlark Rift is a maximum estimate of that which existed prior to extensional exhumation of the SDMCC, the paleo-temperature gradient was used to estimate an average initial dip of the Mai’iu Fault of ~44° for pre-extensional geothermal gradients ranging between 10 to 20°C/km. Presently dipping 20-22° at the surface, the constraints on the initial dip suggest that the Mai’iu Fault may have been back-rotated by >20° since the onset of extension, consistent with a rolling hinge-style evolution of this continental MCC.</p>

Suitability of surficial media for Ni-Cu-PGE exploration in an established mining camp: a case study from the South Range of the Sudbury Igneous Complex, Canada

A geochemical study over the southwestern part of the South Range of the Sudbury Igneous Complex (SIC) was completed to assess the suitability of surficial media (humus, B-horizon soil and C-horizon soil) for delineating geochemical anomalies associated with Ni-Cu-PGE mineralization. Another objective was to test whether Na pyrophosphate can eliminate the effects of anthropogenic contamination in humus. Results of this study suggest that the natural geochemical signature of humus is strongly overprinted by anthropogenic contamination. Despite no indication of underlying or nearby mineralization, metal concentrations in humus samples by aqua regia collected downwind from smelting operations are higher compared to background, including up to 13 times higher for Pt, 12 times higher for Cu and 9 times higher for Ni. The high anthropogenic background masks the geogenic signal such that it is only apparent in humus samples collected in the vicinity of known Ni-Cu-PGE deposits. Results of this study also demonstrate that anthropogenically-derived atmospheric fallout also influences the upper B-horizon soil; however, lower B-horizon soil (at > 20 cm depth) and C-horizon soil (both developed in till) are not affected. Glacial dispersal from Ni-Cu-PGE mineralization is apparent in C-horizon till samples analyzed in this study. Compared to the background concentrations, the unaffected C-horizon till samples collected immediately down-ice of the low-sulfide, high precious metal (LSHPM) Vermilion Cu-Ni-PGE deposit are enriched over 20 times in Pt (203 ppb), Au (81 ppm) and Cu (963 ppm), and over 30 times in Ni (1283 ppm).Supplementary material:https://doi.org/10.6084/m9.figshare.c.5691080

The Petrogenesis of Mid-Cretaceous Continental Intraplate Volcanism in Marlborough, New Zealand, during the Break-up of Gondwana

<p>The Lookout Volcanics are the remnants of an extensive sheet of mid-Cretaceous (ca. 96 Ma) continental intraplate volcanic rocks erupted just prior to the rifting of New Zealand from Gondwana. Preserved in a fault angle depression bounded by the Awatere Fault located in Marlborough, South Island, New Zealand, the volcanic rocks cover an area of ca. 50 km2 with exposed thicknesses up to 1000 m. On the basis of stratigraphic evidence the dominantly terrestrial lavas flows are inferred to have erupted from dykes of a coeval radial dyke swarm. A detailed sampling of the lava flows of the Lookout Volcanics has been undertaken with a ca. 700 m composite stratigraphic section being constructed, largely based on a continuous sequence of lava flows outcropping in Middlehurst Stream. New Rb-Sr age constraints for the Lookout Volcanics (97.6 plus or minus 3.4 Ma) and Blue Mountain Igneous Complex (97.1 plus or minus 0.7 Ma) are consistent with previous radiometric dates of plutonic complexes in the Central Marlborough Igneous Complex, and suggest a rapid accumulation of volcanic material from ca. 98-96 Ma during the initial extension of proto-New Zealand. The predominantly mafic and alkaline samples include basalt, picrobasalt, basanite, trachybasalt and basaltic trachyandesite rock types. No samples represent primary magmas with all samples having undergone fractionation (or accumulation) of olivine plus clinopyroxene plus or minus plagioclase plus or minus Fe-Ti oxides. Initial Sr-Nd-Hf-Pb isotopic variations (87Sr/86Sr = 0.7030-0.7039; 143Nd/144Nd = 0.51272-0.51264; 176Hf/177Hf = 0.28283-0.28278; 206Pb/204Pb = 20.32-18.82) reflect mixing between melts of a HIMUlike mantle component with up to 25-30% of an Early Cretaceous upper crustal component. Oxygen isotope ratios determined by laser fluorination analysis from 6 lava flows yielded delta 18O = 4.7-5.0 per thousand for olivine, 4.8-5.4 per thousand in clinopyroxene cores, 3.9-5.5 per thousand in clinopyroxene rims. Average olivine (4.8 per thousand) and clinopyroxene core (5.1 per thousand) values are 0.4-0.5 per thousand lower than those of average mantle peridotite but comparable to those of HIMU OIB, and are consistent with New Zealand intraplate magmas being generated by a low delta 18O mantle. However, oxygen isotopic disequilibrium between clinopyroxene cores and rims (Delta 18O = -1.4 to +0.3) records the overprinting of this signature by crustal processes. Negative disequilibrium between clinopyroxene rims and cores in primitive samples suggests these phenocrysts grew in a shallow crustal magma chamber with an active meteoric water system. The effects of crustal assimilation can also be observed with clinopyroxene phenocrysts from the most evolved sample exhibiting coupled elevated delta 18O and 87Sr/86Sr. Variations in incompatible trace element ratios are consistent with the Lookout Volcanics being the small degree (2-5%) partial melts of an amphibole-bearing garnet pyroxenite. Furthermore, the elevated NiO contents of olivine phenocrysts are consistent with melting of a pyroxenitic mantle source. The presence of residual amphibole constrains melting to the hydrous subcontinental lithospheric mantle. The Lookout Volcanics and coeval plutonic complexes are the oldest occurrences of HIMU magmatism in Zealandia. This source was generated by small degree silicate melts from recycled oceanic lithosphere that metasomatised the base of the subcontinental lithospheric mantle beneath East Gondwana over 200 Ma ago.</p>

The Petrogenesis of Mid-Cretaceous Continental Intraplate Volcanism in Marlborough, New Zealand, during the Break-up of Gondwana

<p>The Lookout Volcanics are the remnants of an extensive sheet of mid-Cretaceous (ca. 96 Ma) continental intraplate volcanic rocks erupted just prior to the rifting of New Zealand from Gondwana. Preserved in a fault angle depression bounded by the Awatere Fault located in Marlborough, South Island, New Zealand, the volcanic rocks cover an area of ca. 50 km2 with exposed thicknesses up to 1000 m. On the basis of stratigraphic evidence the dominantly terrestrial lavas flows are inferred to have erupted from dykes of a coeval radial dyke swarm. A detailed sampling of the lava flows of the Lookout Volcanics has been undertaken with a ca. 700 m composite stratigraphic section being constructed, largely based on a continuous sequence of lava flows outcropping in Middlehurst Stream. New Rb-Sr age constraints for the Lookout Volcanics (97.6 plus or minus 3.4 Ma) and Blue Mountain Igneous Complex (97.1 plus or minus 0.7 Ma) are consistent with previous radiometric dates of plutonic complexes in the Central Marlborough Igneous Complex, and suggest a rapid accumulation of volcanic material from ca. 98-96 Ma during the initial extension of proto-New Zealand. The predominantly mafic and alkaline samples include basalt, picrobasalt, basanite, trachybasalt and basaltic trachyandesite rock types. No samples represent primary magmas with all samples having undergone fractionation (or accumulation) of olivine plus clinopyroxene plus or minus plagioclase plus or minus Fe-Ti oxides. Initial Sr-Nd-Hf-Pb isotopic variations (87Sr/86Sr = 0.7030-0.7039; 143Nd/144Nd = 0.51272-0.51264; 176Hf/177Hf = 0.28283-0.28278; 206Pb/204Pb = 20.32-18.82) reflect mixing between melts of a HIMUlike mantle component with up to 25-30% of an Early Cretaceous upper crustal component. Oxygen isotope ratios determined by laser fluorination analysis from 6 lava flows yielded delta 18O = 4.7-5.0 per thousand for olivine, 4.8-5.4 per thousand in clinopyroxene cores, 3.9-5.5 per thousand in clinopyroxene rims. Average olivine (4.8 per thousand) and clinopyroxene core (5.1 per thousand) values are 0.4-0.5 per thousand lower than those of average mantle peridotite but comparable to those of HIMU OIB, and are consistent with New Zealand intraplate magmas being generated by a low delta 18O mantle. However, oxygen isotopic disequilibrium between clinopyroxene cores and rims (Delta 18O = -1.4 to +0.3) records the overprinting of this signature by crustal processes. Negative disequilibrium between clinopyroxene rims and cores in primitive samples suggests these phenocrysts grew in a shallow crustal magma chamber with an active meteoric water system. The effects of crustal assimilation can also be observed with clinopyroxene phenocrysts from the most evolved sample exhibiting coupled elevated delta 18O and 87Sr/86Sr. Variations in incompatible trace element ratios are consistent with the Lookout Volcanics being the small degree (2-5%) partial melts of an amphibole-bearing garnet pyroxenite. Furthermore, the elevated NiO contents of olivine phenocrysts are consistent with melting of a pyroxenitic mantle source. The presence of residual amphibole constrains melting to the hydrous subcontinental lithospheric mantle. The Lookout Volcanics and coeval plutonic complexes are the oldest occurrences of HIMU magmatism in Zealandia. This source was generated by small degree silicate melts from recycled oceanic lithosphere that metasomatised the base of the subcontinental lithospheric mantle beneath East Gondwana over 200 Ma ago.</p>

Sulfide mineral chemistry and platinum-group minerals of the UG-2 chromitite in the northern limb of the Bushveld Igneous Complex, South Africa

ABSTRACT The UG-2 chromitite layer, with its elevated platinum-group element content, is a key marker horizon in the eastern and western limbs of the Bushveld Igneous Complex and the largest platinum-group element chromite-hosted resource of its kind in the world. In contrast, much less is known about its stratigraphic equivalent in the northern limb, the “UG-2 equivalent” (UG-2E) chromitite. Recent studies on chromite mineral chemistry show similarities between the UG-2 and sections of the UG-2E, but also that the UG-2E was partially contaminated by assimilation of local metasedimentary rocks. Here, we provide a detailed characterization of sulfide minerals and platinum-group minerals in a suite of samples from the UG-2E and compare the results with data obtained from a reference suite of samples from the UG-2. Results from petrographic observations, electron probe microanalysis, laser ablation-inductively coupled plasma-mass spectrometry, quantitative evaluation of materials by scanning electron microscopy, and δ34S isotopes show that: (1) sulfide minerals in the UG-2E and UG-2 consist mainly of pentlandite-chalcopyrite-pyrrhotite, but pyrrhotite is significantly more abundant in the UG-2E and almost absent in the UG-2; (2) iron contents in pentlandite from the UG-2E are significantly higher than in the UG-2; (3) platinum-group element contents within sulfide minerals are different between the two chromitites; (4) UG-2E platinum-group minerals are dominated by arsenides and bismuthotellurides, and by alloys and platinum-group element-sulfide minerals in the UG-2; (5) sulfide mineral chemistry and δ34S values indicate some crustal contamination of the UG-2E; and (6) sulfide mineral and secondary silicate mineral textures in both the UG-2E and UG-2 are indicative of minor, millimeter- to centimeter-scale, hydrothermal alteration. From our observations and results, we consider the UG-2E chromitite in the northern limb to be the equivalent to the UG-2 in the eastern and western limbs that has been contaminated by assimilation of Transvaal Supergroup footwall rocks during emplacement. The contamination resulted in UG-2E sulfide mineral elemental contents and platinum-group mineral types and abundances that are distinct from those of the UG-2 in the rest of the Bushveld.