Gold and silver accessory minerals in ultramafites of the Kyzyr-Burlyuksky ultramafic massif (Western Sayan)

The study focuses on gold and silver accessory minerals (native silver, cuprous gold, luanheite (Ag3Hg), unspecified mineral phase (Cu,Ag,Hg), first diagnosed in dunites and apodunite serpentinites of the Kyzyr-Burlyuksky ultramafic massif, which is part of the Kurtushibin ophiolite belt of Western Sayan. The revealed ore minerals are mainly observed in the form of single hypidiomorphic, irregular microscopic precipitates (0.5– 3.0 μm) mainly inside magnetite, much less often in grains of avaruite. Typomorphic and chemical features of ore minerals, their natural setting in rock-forming silicate matrix are characterized. Formation and concentration of these accessory minerals is associated with superimposed low-temperature transformation (hydration) processes affecting original ultramafic rocks. At the same time, the presence of luanheite and an unnamed phase (Cu,Ag,Hg), along with the previously identified potarite (PdHg), is probably evidence of low-temperature conditions of mineral formation during the manifestation of epigenetic processes of serpentinization (lowgrade metamorphism) due to solutions enriched in mercury. The source of such solutions could be gabbro intrusions that penetrated later into the main ultramafic body.

Rock-Forming (Biotite and Plagioclase) and Accessory (Zircon) Minerals Geochemistry as an Indicator of the Metal Fertility of Magmas by the Example of Au-Cu-Fe-Skarn Deposits in Eastern Transbaikalia

Many gold and gold-bearing complex deposits related to the Late Jurassic and Early Cretaceous magmatism are known in Eastern Transbaikalia. The largest deposits are the Lugokan, the Kultuma and the Bystrinsky. These deposits are in a paragenetic relationship with the Late Jurassic magmatic rocks of the Shakhtama complex. According to the available data, the total resources of gold in these three deposits are estimated to be approximately 443 tons: the Lugokan, Au~53 tons, Cu~302 thousand tons; the Kultuma, Au~121 tons, Cu~587 thousand tons, Fe~33 mln t; the Bystrinsky, Au~269 tons, Cu~2070 thousand tons, Fe~67 mln t. One of the main aims of this work was to reveal the criteria of fertility for the classical porphyry type, based on the specific geochemical features of rock-forming and accessory minerals. A comparison of the obtained results with other data on the large porphyry and skarn deposits of the world showed that the magmatic rocks of the Bystrinsky massif, specifically porphyry species dated 159.6–158.6 Ma, are potentially ore-bearing for the porphyry type mineralization. The magmatic rocks that widely occur at the Lugokan and Kultuma deposits are most close to the Fe-skarn deposits. The best indicators of the magma fertility for the porphyry rocks are Ce/Ce*, Eu/Eu*, Yb/Dy, (Ce/Nd)/Y in zircons. Thus, magmatic rocks characterized by Ce/Ce* > 100, Eu/Eu* > 0.4, Yb/Dy > 5.0 and (Ce/Nd)/Y > 0.01 may be classified as high fertile for the classical porphyry mineralization in Eastern Transbaikalia. The plagioclase and biotite chemistry data also showed that the magmatic rocks that occurred at the Bystrinsky deposit are the most fertile for the porphyry type mineralization. The magmatic rocks classified as ore-bearing porphyry type have Al* > 1 in plagioclase, high values of IV(F) and IV(F/Cl) and low ratios of X(F)/X(OH) in biotites. The assessment of the metal fertility of magmatic rocks is most effective in combination with data on both the composition of rock-forming and accessory minerals. The obtained data may be used to develop the methods of prediction and search for gold, copper and iron mineralization.

The spatial association of accessory minerals with biotite in granitic rocks from the South Mountain Batholith, Nova Scotia, Canada

We use mineral liberation analysis (MLA) to quantify the spatial association of 15,118 grains of accessory apatite, monazite, xenotime, and zircon with essential biotite, and clustered with themselves, in a peraluminous biotite granodiorite from the South Mountain Batholith in Nova Scotia (Canada). A random distribution of accessory minerals demands that the proportion of accessory minerals in contact with biotite is identical to the proportion of biotite in the rock, and the binary touching factor (percentage of accessory mineral touching biotite divided by modal proportion of biotite) would be ~1.00. Instead, the mean binary touching factors for the four accessory minerals in relation to biotite are: apatite (5.06 for 11,168 grains), monazite (4.68 for 857 grains), xenotime (4.36 for 217 grains), and zircon (5.05 for 2876 grains). Shared perimeter factors give similar values. Accessory mineral grains that straddle biotite grain boundaries are larger than completely locked, or completely liberated, accessory grains. Only apatite-monazite clusters are significantly more abundant than expected for random distribution. The high, and statistically significant, binary touching factors and shared perimeter factors suggest a strong physical or chemical control on their spatial association. We evaluate random collisions in magma (synneusis), heterogeneous nucleation processes, induced nucleation in passively enriched boundary layers, and induced nucleation in actively enriched boundary layers to explain the significant touching factors. All processes operate during the crystallization history of the magma, but induced nucleation in passively and actively enriched boundary layers are most likely to explain the strong spatial association of phosphate accessories and zircon with biotite. In addition, at least some of the apatite and zircon may also enter the granitic magma as inclusions in grains of Ostwald-ripened xenocrystic biotite.

Zirconium-bearing accessory minerals in UK Paleogene granites: textural, compositional, and paragenetic relationships

The mineral occurrences, parageneses, textures, and compositions of Zr-bearing accessory minerals in a suite of UK Paleogene granites from Scotland and Northern Ireland are described. Baddeleyite, zirconolite, and zircon, in that sequence, formed in hornblende + biotite granites (type 1) and hedenbergite–fayalite granites (type 2). The peralkaline microgranite (type 3) of Ailsa Craig contains zircon, dalyite, a eudialyte-group mineral, a fibrous phase which is possibly lemoynite, and Zr-bearing aegirine. Hydrothermal zircon is also present in all three granite types and documents the transition from a silicate-melt environment to an incompatible element-rich aqueous-dominated fluid. No textures indicative of inherited zircon were observed. The minerals crystallized in stages from magmatic through late-magmatic to hydrothermal. The zirconolite and eudialyte-group mineral are notably Y+REE-rich (REE signifies rare earth element). The crystallization sequence of the minerals may have been related to the activities of Si and Ca, to melt peralkalinity, and to local disequilibrium.

Pre-Pegmatite Stage in Peralkaline Magmatic Process: Insights from Poikilitic Syenites from the Lovozero Massif, Kola Peninsula, Russia

The Lovozero peralkaline massif (Kola Peninsula, Russia) is widely known for its unique mineral diversity, and most of the rare metal minerals are found in pegmatites, which are spatially associated with poikilitic rocks (approximately 5% of the massif volume). In order to determine the reasons for this relationship, we have investigated petrography and the chemical composition of poikilitic rocks as well as the chemical composition of the rock-forming and accessory minerals in these rocks. The differentiation of magmatic melt during the formation of the rocks of the Lovozero massif followed the path: lujavrite → foyaite → urtite (magmatic stage) → pegmatite (hydrothermal stage). Yet, for peralkaline systems, the transition between magmatic melt and hydrothermal solution is gradual. In the case of the initially high content of volatiles in the melt, the differentiation path was probably as follows: lujavrite → foyaite (magmatic stage) → urtitization of foyaite → pegmatite (hydrothermal stage). Poikilitic rocks were formed at the stage of urtitization, and we called them pre-pegmatites. Indeed, the poikilitic rocks have a metasomatic texture and, in terms of chemical composition, correspond to magmatic urtite. The reason for the abundance of rare metal minerals in pegmatites associated with poikilitic rocks is that almost only one nepheline is deposited during urtitization, whereas during the magmatic crystallization of urtite, rare elements form accessory minerals in the rock and are less concentrated in the residual solution.

Leka Ophiolite Complex as analogy to the serpentinization-carbonation system on Mars.

<p>Serpentinization and carbonation have affected ultramafic rocks on Noachian Mars in several places called here serpentinization-carbonation systems (SCS). Among the most prominent SCS revealing mineral assemblages characteristic of serpentinization/carbonation is the Nili Fossae region [1]. Jezero crater – the target of the Mars 2020 rover –hosted a paleolake which constitutes a sink for sediments from Nili Fossae [1]. Thanks to the near infrared spectrometer onboard Mars2020 [2], the mission has the potential to offer ground truth measurement for other putative serpentinization/carbonation system documented on Mars. Several important aspects that may be addressed are: Do carbonates result from primary alteration of olivine-rich lithologies or are they derived by reprocessing of previous alteration minerals [3]? What is the composition? and nature of the protolith, which appear to be constituted of considerable amounts of olivine [4]? To reveal critical information regarding the conditions of serpentinization/carbonation, accessory minerals need detailed studies [1; 5]. In case of Jezero Crater, and serpentinization on Mars in general, the main alteration minerals are identified, but little is known about the accessory minerals.</p> <p>The Nili Fossae-Jezero system has potential analogues in terrestrial serpentinized and carbonated rocks, such as the Leka Ophiolite Complex, Norway (PTAL collection, https://www.ptal.eu). Here, distinct mineral assemblages record different stages of hydration and carbonation of ultramafic rocks [6].</p> <p>We perform petrological and mineralogical analyses on thin sections to characterize the major and trace minerals and combine with Near Infrared (NIR) spectroscopy measurements. A set of spectral parameters are defined and compare to spectral parameters previously used on CRISM and OMEGA data [1, 4, 7, 8]. We study the significance of the mineralogical assemblages including nature of accessory minerals. Effect of the presence of accessory minerals on the NIR signal is investigated and their potential incidence on the amount of H<sub>2</sub>/CH<sub>4</sub> production in mafic or ultramafic system is discussed [5].</p> <p>We started to apply the newly defined spectral parameters on several SCS on Mars. Results confirm local carbonation of earlier serpentinized rocks and suggest that different protoliths could have led to diversity of mineralogical associations in SCS on Mars. Multiple detection of brucite are also suggested for the first time on Mars. Altogether our results help to better describe key geochemical conditions of the SCS on Mars for habitability potential of the martian crust and Mars’s evolution.</p> <p><strong> </strong></p> <p>References:</p> <ul> <li>Brown, A. J., et al. <em>EPSL</em>1-2 (2010): 174-182.</li> <li>Wiens, R.C., et al.  <em>Space Sci Rev</em><strong>217, </strong>4 (2021).</li> <li>Horgan, B., et al. <em>Second International Mars Sample Return</em>. Vol. 2071. 2018.</li> <li>Ody, A., et al. <em>JGR: Planets</em>2 (2013): 234-262.</li> <li>Klein, F., et al. <em>Lithos</em>178 (2013): 55-69.</li> <li>Bjerga, A., et al. <em>Lithos</em>227 (2015): 21-36.</li> <li>Viviano-Beck et al, <em>JGR: Planets 11</em>8.9 (2013)</li> <li>Viviano-Beck et al, <em>JGR: Planets 119.6</em> (2014)</li> </ul>

Geochemistry evolution of Schists of northwest Obudu area southeastern Nigeria

Geochemistry of schists of Obudu area was carried out using ICP-MS and ICP-ES techniques in order to determine the geochemical evolution of the area. 40 samples were analyzed for their major, trace and REE composition. Field mapping revealed that gneisses, amphibolites and schists comprising migmatitic schists (MS), quartz-mica schists (QMS), garnet-mica schists (GMS), and hornblende biotite schists (HBS), intruded by granites, granodiorites, quartzofeldspathic rocks and dolerites occur in the area. Structural studies revealed that the schists trend approximately NE–SW (5 – 30o ) indicating the Pan-African event. Modal analysis revealed that the schists have average concentration of quartz (15vol.%), plagioclase (An45-19 vol.%), biotite (15vol.%), garnet (9.0vol.%) and muscovite (6vol.%), the remaining consists of accessory minerals. Geochemistry showed that all the schists have molecular Al2O3 > CaO+K2O+Na2O, indicating they are peraluminous metasedimentary pelites. Trace and REE element results show that all the analyzed schist samples are depleted in Hg, Ag, Be, Bi, and Sb below < 1.0ppm, but relatively enriched in Ba, Sr and Zr with average concentration of 996, 675.73, 243.13 ppm respective. The HREE are depleted with ΣHREE < 10.2, but the LREE are relatively enriched with ΣLREE > 289.54. The ΣLREE/ΣHREE ratio ranges from 9.17 to 33.4, with a large positive delta V at Eu. These findings indicate that the schists of Northwest Obudu area are highly fractionated and had attained at least the uppermost amphibolite metamorphic grade. The schists had contributed to the development of the Pan-African continent.