Abstract
Suspended particulate matter (SPM) is a major contamination source in urban rivers. In this work, the Beiyun River, northern China, was used as a case study to determine the characteristics of heavy metal spatial distribution in SPM, and to evaluate the potential ecological risks and identify heavy metal sources. The concentration of seven heavy metals and associated indicators (TC, TN, TP, and OM) were measured at 12 sites and analyzed by Pearson correlation (PC) and principal component analyses (PCA). The average concentrations of Cr, Ni, Cu, Zn, As, Cd, and Pb were 70.72, 27.88, 31.35, 115.70, 27.77, 0.23, and 29.62 mg/kg, respectively, and significant spatial differences occurred between some elements. Igeo values indicated the ranking of heavy metal pollution in SPM as As > Cd > Zn > Cu > Pb > Cr > Ni. The Eir analysis demonstrated that the order of potential ecological risk of the seven metals was Cd > As > Cu > Pb > Ni > Cr > Zn. RI (potential ecological risk index) results confirmed high potential ecological risk in objective area. Of the measured heavy metals, Cd represented the highest pollution risk. Significant positive correlations were found between TC, TN, TP, and Cu. Three element pairs, Zn-Cd, Cr-Cu, and Cr-Ni, had strong correlations. Zn, Cu, and Ni were mainly introduced by human activities, and Cr was mainly from natural processes. This information on the concentration, risk, and sources of SPM in Beiyun River provides an important reference for reducing heavy metal pollution in SPM of a typical river in the Haihe River Basin.
Heavy Metals in Suspended Particulate Matter of the Zhujiang River, Southwest China: Contents, Sources, and Health Risks
