Phase transitions and NH3 motions in [Zn(NH3)4](ClO4)2 studied by incoherent neutron scattering and 1H NMR methods

2007 ◽  
Vol 335 (2-3) ◽  
pp. 187-193 ◽  
Author(s):  
Anna Migdał-Mikuli ◽  
Krystyna Hołderna-Natkaniec ◽  
Edward Mikuli ◽  
Łukasz Hetmańczyk ◽  
Ireneusz Natkaniec
2001 ◽  
Vol 56 (3-4) ◽  
pp. 244-248 ◽  
Author(s):  
E. Mikuli ◽  
A. Migdał-Mikuli ◽  
I. Natkaniec ◽  
B. Grad

Abstract Inelastic incoherent neutron scattering (IINS) spectra and neutron powder diffraction (NPD) patterns, registered for [Co(H2O)6](ClO4)2 at 18 -270 K and for [Mn(H2O)6](BF4)2 at 18 -230 K, provided evidence that these crystals possess three solid phases in these ranges of temperatures. In both compounds the phase transition occurring at TC3 is connected with a change of the crystal structure, and that occurring at TC2 with a change in the rate of the reorientational motions of H2O ligands.


1992 ◽  
Vol 180-181 ◽  
pp. 342-344 ◽  
Author(s):  
J. Etrillard ◽  
B. Toudic ◽  
H. Cailleau ◽  
M.H. Lemée-Cailleau ◽  
G. Coddens ◽  
...  

1991 ◽  
Vol 113 (11) ◽  
pp. 4158-4160 ◽  
Author(s):  
Roderick D. Cannon ◽  
Upali A. Jayasooriya ◽  
Samuel K. Arap Koske ◽  
Ross P. White ◽  
Jeffrey H. Williams

1972 ◽  
Vol 56 (7) ◽  
pp. 3217-3225 ◽  
Author(s):  
H. J. Prask ◽  
S. F. Trevino ◽  
J. D. Gault ◽  
K. W. Logan

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