Cellulose derivatives crosslinked by citric acid on electrode surface as a heavy metal absorption/sensing matrix

Author(s):  
Jitka Sotolářová ◽  
Štěpán Vinter ◽  
Jaroslav Filip
2013 ◽  
Vol 726-731 ◽  
pp. 4464-4467
Author(s):  
Wei Wei ◽  
Xue Jin Zhou ◽  
Yun Tao Gao

Taking plateau red soil as research object, using the ultrasonic-assisted organic acid extraction the heavy metal zinc in it, and analyze the form of zinc. Results showed that the extraction rate can reach 68%, with the increase of time, the extraction effect of zinc is obviously enhanced in this method. Ultrasonic-assisted citric acid extraction soil can increase the extraction rate of exchangeable, bound to carbonates and bound to iron and manganese oxides relatively.


Sensors ◽  
2005 ◽  
Vol 5 (1) ◽  
pp. 70-84 ◽  
Author(s):  
Vojtech Adam ◽  
Josef Zehnalek ◽  
Jitka Petrlova ◽  
David Potesil ◽  
Bernd Sures ◽  
...  

Author(s):  
Zhihong Guo ◽  
Shuqin Zhang ◽  
Dajun Ren ◽  
Xiaoqing Zhang ◽  
Shuang Liu ◽  
...  

2020 ◽  
Vol 2020 ◽  
pp. 1-13
Author(s):  
Silvie Durpekova ◽  
Kateryna Filatova ◽  
Jaroslav Cisar ◽  
Alena Ronzova ◽  
Erika Kutalkova ◽  
...  

This study details the design and characterization of a new, biodegradable, and renewable whey/cellulose-based hydrogel (i.e., agricultural hydrogel). This was formulated from cellulose derivatives (carboxymethylcellulose (CMC) and hydroxyethylcellulose (HEC)) and acid whey cross-linked with citric acid, with the aim to obtain an agricultural product with a high swelling capacity to uphold the quality of soil and conserve water resources. With regard to the swelling behaviour of the prepared hydrogels, the authors initially assessed the swelling ratio and capacity for water uptake. Evaluating the chemical structure of the hydrogel and its thermal and viscoelastic properties involved performing Fourier transform infrared spectroscopy, differential scanning colorimetry, thermal gravimetric analysis, and rheological measurement of the hydrogel films. According to preliminary results, sufficient swelling capacity and stiffness were observed in a hydrogel prepared with 3% CMC and HEC, cross-linked with 5% citric acid. Moreover, the kinetics of water uptake revealed a promising capacity that was sustainable after 5 drying and swelling cycles. The results confirmed that the stability of the hydrogel was enhanced by the presence of the citric acid. As a consequence, it is necessary to utilize an appropriate cross-linking concentration and abide by certain conditions to ensure the swelling properties of the prepared hydrogel are sufficient. Further investigation of the topic, especially in relation to applications in soil, could confirm if the whey-cellulose-based hydrogel is actually suitable for agricultural use, thereby contributing to the advancement of sustainable arable farming.


2015 ◽  
Vol 9 (7) ◽  
pp. 37
Author(s):  
Judy R. B. Witono ◽  
Henrietta Henrietta ◽  
Y. I. P Arry Miryanti

The technology development in many industries nowadays, such as electronic industry produces heavy metal wastes which may pollute our environment. The use of adsorbent as a heavy metal removal from soil and water is one of the efficient process which can be considered to be used. In addition the release of the adsorbate becomes an important way as well because usually those heavy metals still have a high value. The objective of this research is to develop adsorbent based on cassava starch. So, the release process will become easier and will not produce another waste. The adsorbent was produced through the grafting of acrylic acid onto cassava starch by using Fenton initiator. To construct a stable 3-D network, the crosslinker (CL) N,N’- methylenebisacrylamide was added. The variable observed were the amount of CL added (0.5%; 1.5%; 2.5% and 3.5%) and the treatment of generating more pores on starch copolymer. The treatments on starch copolymer observed were single freezing, second freezing, and citric acid modification and carbonization methods. Analysis performed on the adsorbent was % add-on, water absorption and metal adsorption (especially Cu2+ ion) capacity. The result showed that the used of 2.5% CL produced the highest add-on (47.66 %), the highest water absorption capacity and the highest metal adsorption capacity (0.29g Cu2+/g adsorbent) The citric acid modification also produced the highest pores on the adsorbent.


1977 ◽  
Vol 106 (4) ◽  
pp. 261-273 ◽  
Author(s):  
EDWARD L BAKER ◽  
CARL G HAYES ◽  
PHILIP J. LANDRIGAN ◽  
JAN L. HANDKE ◽  
RONALD T. LEGER ◽  
...  

2020 ◽  
Vol 242 ◽  
pp. 116822 ◽  
Author(s):  
Degang Ma ◽  
Meizhong Su ◽  
Jingjing Qian ◽  
Qian Wang ◽  
Fanyi Meng ◽  
...  

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