Investigation of Anionic Group Effects on the Shale Inhibition Performance of Fatty Acid-based Ionic Liquids and their Inhibition Mechanism

Author(s):  
Han Jia ◽  
Shaoyan Wang ◽  
Zhe Wang ◽  
Qiang Wang ◽  
Haidong Jia ◽  
...  
Coatings ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 21
Author(s):  
Javier Faes ◽  
Rubén González ◽  
Antolin Hernández Battez ◽  
David Blanco ◽  
Alfonso Fernández-González ◽  
...  

This research deals with the tribological behavior and corrosion performance of three novel fatty acid anion-based ionic liquids (FAILs): methyltrioctylammonium hexanoate ([N8,8,8,1][C6:0]), methyltrioctylammonium octadecanoate ([N8,8,8,1][C18:0]) and methyltrioctylammonium octadec-9-enoate ([N8,8,8,1][C18:1]), employed for the first time as neat lubricant with five different material pairs: steel–steel, steel–aluminum alloy, steel–bronze, steel–cast iron and steel–tungsten carbide. These novel substances were previously obtained from fatty acids via metathesis reactions, identified structurally via NMR (nuclear magnetic resonance) and FTIR (Fourier-transform infrared spectroscopy) techniques, and then characterized from a physicochemical (density, water solubility, viscosity, viscosity index and refractive index) and environmental (bacterial toxicity and biodegradability) points of view. The corrosion behavior of the three FAILs was studied by exposure at room temperature, while friction and wear tests were performed with a reciprocating ball-on-disc configuration. The main results and conclusions obtained were: (1) Corrosion in the presence of the three FAILs is observed only on the bronze surface; (2) All FAILs presented similar tribological behavior as lubricants for each tested material pair; (3) XPS (X-ray photoelectron spectroscopy) analysis indicated that the surface behavior of the three FAILs in each material pair was similar, with low chemical interaction with the surfaces.


2016 ◽  
Vol 19 (3) ◽  
pp. 511-517 ◽  
Author(s):  
Xiao-Sheng Lin ◽  
Yong Zou ◽  
Kai-Hua Zhao ◽  
Tao-Xiang Yang ◽  
Peter Halling ◽  
...  

2017 ◽  
Vol 410 (19) ◽  
pp. 4633-4643 ◽  
Author(s):  
Mohsen Talebi ◽  
Rahul A. Patil ◽  
Leonard M. Sidisky ◽  
Alain Berthod ◽  
Daniel W. Armstrong

2020 ◽  
Vol 305 ◽  
pp. 112827 ◽  
Author(s):  
M. Sernaglia ◽  
D. Blanco ◽  
A. Hernández Battez ◽  
J.L. Viesca ◽  
R. González ◽  
...  

2018 ◽  
Vol 410 (19) ◽  
pp. 4763-4764
Author(s):  
Mohsen Talebi ◽  
Rahul A. Patil ◽  
Leonard M. Sidisky ◽  
Alain Berthod ◽  
Daniel W. Armstrong

2021 ◽  
Author(s):  
Rizwan Ahmed Khan ◽  
Mobeen Murtaza ◽  
Hafiz Mudaser Ahmad ◽  
Abdulazeez Abdulraheem ◽  
Muhammad Shahzad Kamal ◽  
...  

Abstract In the last decade, hydrophilic Ionic liquids have been emerged as an additive in drilling fluids for clay swelling inhibition. However, the application of hydrophobic Ionic liquids as a clay swelling inhibitor have not been investigated. In this study, the combination of hydrophobic Ionic liquids and Gemini surfactant were studied to evaluate the inhibition performance. The novel combination of hydrophobic ionic liquid (Trihexyltetradecyl phosphonium bis(2,4,4-trimethyl pentyl) phosphinate) and cationic gemini surfactant (GB) was prepared by mixing various concentrations of both chemicals and then preparing water based drilling fluid using other drilling fluid additives such as rheological modifier, filtration control agent, and pH control agent. The wettability of sodium bentonite was determined by contact angle with different concentrations of combined solution. Some other experiments such as linear swelling, capillary suction test (CST) and bentonite swell index were performed to study the inhibition performance of ionic liquid. Different concentrations of novel combined ionic liquid and gemini surfactant were used to prepare the drilling fluids ranging from (0.1 to 0.5 wt.%), and their performances were compared with the base drilling fluid. The wettability results showed that novel drilling fluid having 0.1% Tpb-P - 0.5% GB wt.% concentration has a maximum contact angle indicating the highly hydrophobic surface. The linear swelling was evaluated over the time of 24 hours, and least swelling of bentonite was noticed with 0.1% Tpb-P - 0.5% GB wt.% combined solution compared to linear swelling in deionized water. Furthermore, the results of CST also suggested the improved performance of novel solution at 0.1% Tpb-P - 0.1% GB concentration. The novel combination The novel combination of hydrophobic ionic liquids and gemini surfactant has been used to formulate the drilling fluid for high temperature applications to modify the wettability and hydration properties of clay. The use of novel combined ionic liquid and gemini surfactant improves the borehole stability by adjusting the clay surface and resulted in upgraded wellbore stability.


2020 ◽  
Vol 158 ◽  
pp. 106581
Author(s):  
Qianwen Chen ◽  
Shuainan Ni ◽  
Guanghua Ai ◽  
Tao Zhang ◽  
Xiaoqi Sun

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