A method combining FTIR-ATR and Raman spectroscopy to determine soil organic matter: Improvement of prediction accuracy using competitive adaptive reweighted sampling (CARS)

2021 ◽  
Vol 191 ◽  
pp. 106549
Author(s):  
Zhe Xing ◽  
Changwen Du ◽  
Yazhen Shen ◽  
Fei Ma ◽  
Jianmin Zhou
Sensors ◽  
2019 ◽  
Vol 19 (2) ◽  
pp. 263 ◽  
Author(s):  
Meihua Yang ◽  
Dongyun Xu ◽  
Songchao Chen ◽  
Hongyi Li ◽  
Zhou Shi

Soil organic matter (SOM) and pH are essential soil fertility indictors of paddy soil in the middle-lower Yangtze Plain. Rapid, non-destructive and accurate determination of SOM and pH is vital to preventing soil degradation caused by inappropriate land management practices. Visible-near infrared (vis-NIR) spectroscopy with multivariate calibration can be used to effectively estimate soil properties. In this study, 523 soil samples were collected from paddy fields in the Yangtze Plain, China. Four machine learning approaches—partial least squares regression (PLSR), least squares-support vector machines (LS-SVM), extreme learning machines (ELM) and the Cubist regression model (Cubist)—were used to compare the prediction accuracy based on vis-NIR full bands and bands reduced using the genetic algorithm (GA). The coefficient of determination (R2), root mean square error (RMSE), and ratio of performance to inter-quartile distance (RPIQ) were used to assess the prediction accuracy. The ELM with GA reduced bands was the best model for SOM (SOM: R2 = 0.81, RMSE = 5.17, RPIQ = 2.87) and pH (R2 = 0.76, RMSE = 0.43, RPIQ = 2.15). The performance of the LS-SVM for pH prediction did not differ significantly between the model with GA (R2 = 0.75, RMSE = 0.44, RPIQ = 2.08) and without GA (R2 = 0.74, RMSE = 0.45, RPIQ = 2.07). Although a slight increase was observed when ELM were used for prediction of SOM and pH using reduced bands (SOM: R2 = 0.81, RMSE = 5.17, RPIQ = 2.87; pH: R2 = 0.76, RMSE = 0.43, RPIQ = 2.15) compared with full bands (R2 = 0.81, RMSE = 5.18, RPIQ = 2.83; pH: R2 = 0.76, RMSE = 0.45, RPIQ = 2.07), the number of wavelengths was greatly reduced (SOM: 201 to 44; pH: 201 to 32). Thus, the ELM coupled with reduced bands by GA is recommended for prediction of properties of paddy soil (SOM and pH) in the middle-lower Yangtze Plain.


2022 ◽  
Author(s):  
Xumeng Zhang ◽  
Wuping Zhang ◽  
Mingjing Huang ◽  
Li Gao ◽  
Lei Qiao ◽  
...  

Abstract Dynamic changes in soil organic matter content affects the sustainable supply of soil water and fertilizer and impacts the stability of soil ecological function. Understanding the spatial distribution characteristics of soil organic matter will help deepen our understanding of the differences in soil organic matter content, soil formation law; such understanding would be useful for rational land use planning. Taking terrain data, meteorological data, and remote sensing data as auxiliary variables and the ordinary Kriging (OK) method as a control, this study compares the spatial prediction accuracies and mapping effects of various models (MLR, RK, GWR, GWRK, MGWR, and MGWRK) on soil organic matter. Our results show that the spatial distribution trend of soil organic matter predicted by each model is similar, but the prediction of composite models can reflect more mapping details than that of unitary models. The OK method can provide better support for spatial prediction when the sampling points are dense; however, the local models are superior in dealing with spatial non-stationarity. Notably, the MGWR model is superior to the GWR model, but the MGWRK model is inferior to the GWRK model. As a new method, the prediction accuracy of MGWRK reached 47.72% for the OK and RK methods and 40.08% for the GWRK method. The GWRK method achieved a better prediction accuracy. The influence mechanism of soil organic matter is complex, but the MGWR model more clearly reveals the complex nonlinear relationship between soil organic matter content and factors influencing it. This research can provide reference methods and mapping technical support to improve the spatial prediction accuracy of soil organic matter.


1962 ◽  
Vol 54 (5) ◽  
pp. 470-470
Author(s):  
T. M. McCalla

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