scholarly journals Control structure design for the ammonia synthesis process

2008 ◽  
Vol 32 (12) ◽  
pp. 2920-2932 ◽  
Author(s):  
Antonio Araújo ◽  
Sigurd Skogestad
2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>


2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>


2021 ◽  
Vol 420 ◽  
pp. 129893
Author(s):  
Zijian Liu ◽  
Wende Tian ◽  
Zhe Cui ◽  
Honglong Wei ◽  
Chuankun Li

2013 ◽  
Vol 1 (4) ◽  
pp. 233-244 ◽  
Author(s):  
Marc-Oliver Schach ◽  
Rüdiger Schneider ◽  
Henning Schramm ◽  
Jens-Uwe Repke

2005 ◽  
Vol 83 (2) ◽  
pp. 153-159 ◽  
Author(s):  
W.-H. Tsai ◽  
H.-P. Huang ◽  
C.-C. Yu

Author(s):  
Mehdi Panahi ◽  
Mehdi Karimi ◽  
Sigurd Skogestad ◽  
Magne Hillestad ◽  
Hallvard F. Svendsen

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