The adsorption and corrosion inhibition of some cationic gemini surfactants on carbon steel surface in hydrochloric acid

2005 ◽  
Vol 47 (1) ◽  
pp. 273-278 ◽  
Author(s):  
Ling-Guang Qiu ◽  
An-Jian Xie ◽  
Yu-Hua Shen
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Corrosion Inhibition ◽  
Steel Surface ◽  
Gemini Surfactants ◽  
Carbon Steel Surface ◽  
Cationic Gemini Surfactants

scholarly journals Experimental Theoretical Studies on Extract of Date Palm Seed as a Green Anti-Corrosion Agent in Hydrochloric Acid Solution

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3535
Author(s):  
Naba Jasim Mohammed ◽  
Norinsan Kamil Othman ◽  
Mohamad Fariz Mohamad Taib ◽  
Mohd Hazrie Samat ◽  
Solhan Yahya
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Active Sites ◽  
Immersion Time ◽  
Steel Surface ◽  
Date Palm ◽  
Inhibition Efficiency ◽  
Experimental Results ◽  
Plant Materials ◽  
Carbon Steel Surface

Extracts from plant materials have great potential as alternatives to inorganic corrosion inhibitors, which typically have harmful consequences. Experimental and theoretical methodologies studied the effectiveness of agricultural waste, namely, date palm seed extract as a green anti-corrosive agent in 0.5 M hydrochloric acid. Experimental results showed that immersion time and temperature are closely related to the effectivity of date palm seed as a corrosion inhibitor. The inhibition efficiency reduced from 95% to 91% at 1400 ppm when the immersion time was increased from 72 h to 168 h. The experimental results also indicated that the inhibition efficiency decreased as the temperature increased. The presence of a protective layer of organic matter was corroborated by scanning electron microscopy. The adsorption studies indicated that date palm seed obeyed Langmuir adsorption isotherm on the carbon steel surface, and Gibbs free energy values were in the range of −33.45 to −38.41 kJ·mol−1. These results suggested that the date palm seed molecules interacted with the carbon steel surface through mixture adsorption. Theoretical calculations using density functional theory showed that the capability to donate and accept electrons between the alloy surface and the date palm seed inhibitor molecules is critical for adsorption effectiveness. The HOMO and LUMO result indicated that the carboxyl (COOH) group and C=C bond were the most active sites for the electron donation-acceptance type of interaction and most auxiliary to the adsorption process over the Fe surface.

Adsorption Behavior and Corrosion Inhibition of S-Benzyl o-Phenylenedioxydithiophosphate for Carbon Steel in Hydrochloric Acid Solution

2014 ◽  
Vol 937 ◽  
pp. 109-112
Author(s):  
Xiu Lan Zhang ◽  
Xiao Lin ◽  
Bin Xie ◽  
Li Ke Zou ◽  
Sha Sha Zhu ◽  
...  
Keyword(s):  
Weight Loss ◽  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Hydrochloric Acid Concentration ◽  
Carbon Steel Surface ◽  
Effects Of Temperature ◽  
Mixed Type Inhibitor

The corrosion inhibition of S-benzyl o-phenylenedioxydithiophosphate (BPOTP), for carbon steel in hydrochloric acid solution was studied by electrochemical measurements and weight loss measurements. Polarization curves indicate BPOTP is a mixed-type inhibitor, and the effects of temperature, hydrochloric acid concentration and immersion time were also studied. The studies of weight loss measurement show that the inhibition efficiency was up to 92.82 % at the BPOTP concentration of 40 mg·L-1 in 1.0 M hydrochloric acid solution at 30°C. The adsorption of BPOTP on carbon steel surface obeys the Langmuir isotherm.

INHIBITION EFFECT OF DODECYLAMINE ON CARBON STEEL CORROSION IN HYDROCHLORIC ACID SOLUTION

2012 ◽  
Vol 19 (06) ◽  
pp. 1250060
Author(s):  
ZHENYU CHEN ◽  
LING HUANG ◽  
YUBING QIU ◽  
XINGPENG GUO
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Hydrochloric Acid Solution ◽  
Steel Surface ◽  
Steel Corrosion ◽  
Inhibition Mechanism ◽  
Polar Group ◽  
Exponential Factor ◽  
Carbon Steel Surface

Dodecylamine spontaneously adsorbs on carbon steel via its polar group (-NH2) in hydrochloric acid solution. Furthermore, it forms a monolayer film on carbon steel surface. The inhibition mechanism of dodecylamine for carbon steel is geometric blocking effect. The adsorption of dodecylamine on carbon steel surface follows Arrhenius equation. The adsorption slightly increases activated energy, but greatly reduces pre-exponential factor value. Atomic force microscopy force curves indicate that at the area without adsorbed dodecylamine, no obvious adhere force occurs. At the area with adsorbed dodecylamine, however, an average 1.3 nN adhere force is observed.

Corrosion protection of mild steel in Hydrochloric acid solutions using expired Hydrocortisone sodium succinate drug

2021 ◽  
pp. 874-881
Author(s):  
Kareima A. Abdelghani ◽  
Nisrin, F. Kirallah ◽  
Saleh M. Bofarwa ◽  
A A Idress
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Adsorption Isotherm ◽  
Mild Steel ◽  
Mass Loss ◽  
Steel Surface ◽  
Sodium Succinate ◽  
Acid Solutions ◽  
Carbon Steel Surface ◽  
Hydrochloric Acid Solutions

The erosion hindrance of carbon steel in 1M HCl in nearness and nonappearance of terminated Hydrocortisone Sodium Succinate has been examined utilizing mass-loss. Comes about gotten appeared that the restraint productivity expanded with the increment of the concentration of the utilized medicate and diminished with the increment of temperature. The adsorption of this sedate on carbon steel surface takes after Langmuir’s adsorption isotherm. A few thermodynamic parameters were calculated. The motor parameters of erosion of carbon steel in HCl arrangement have been examined. Keywords: Corrosion inhibition; Carbon steel; Hydrocortisone

Study of the corrosion products formed on carbon steel surface in hydrochloric acid solution

2012 ◽  
Vol 110 (1) ◽  
pp. 145-152 ◽  
Author(s):  
Adriana Samide ◽  
Bogdan Tutunaru ◽  
Aurelian Dobritescu ◽  
Catalin Negrila
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Hydrochloric Acid Solution ◽  
Steel Surface ◽  
Corrosion Products ◽  
Carbon Steel Surface

Adsorption Behavior and Corrosion Inhibition of S-benzyl-O,O'-dibenzyldithiophosphate for Carbon Steel in Hydrochloric Acid Solution

2013 ◽  
Vol 781-784 ◽  
pp. 295-298
Author(s):  
Yan Lu ◽  
Sha Sha Zhu ◽  
Bin Xie ◽  
Chuan Lai ◽  
Qin Huan Yang ◽  
...  
Keyword(s):  
Weight Loss ◽  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Hydrochloric Acid Concentration ◽  
Carbon Steel Surface ◽  
Effects Of Temperature ◽  
Mixed Type Inhibitor

The corrosion inhibition of S-benzyl-O,O'-dibenzyldithiophosphate (BBP) for carbon steel in hydrochloric acid solution was studied by electrochemical measurements and weight loss measurements. Polarization curves indicate BBP is a mixed-type inhibitor, and the effects of temperature, hydrochloric acid concentration and immersion time were also studied. The studies of weight loss measurement show that the inhibition efficiency was up to 97.39 % at the BBP concentration of 60 mg·L-1 in 1.0 M hydrochloric acid solution at 30°C. The adsorption of BBP on carbon steel surface obeys the Langmuir isotherm.

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