High temperature corrosion and electrochemical behavior of INCONEL 625 weld overlay in PbSO4–Pb3O4–PbCl2–CdO–ZnO molten salt medium

2014 ◽  
Vol 85 ◽  
pp. 60-76 ◽  
Author(s):  
E. Mohammadi Zahrani ◽  
A.M. Alfantazi
CORROSION ◽  
2001 ◽  
Vol 57 (6) ◽  
pp. 489-496 ◽  
Author(s):  
M. Amaya ◽  
J. Porcayo-Calderon ◽  
L. Martinez

Abstract The performance of Fe-Si coatings and an iron aluminide (FeAl) intermetallic alloy (FeAl40at%+0.1at%B+10vol%Al2O3) in molten salts containing vanadium pentoxide (V2O5) and sodium sulfate (Na2SO4) is reported. Corrosion and fouling by ash deposits containing V2O5 and Na2SO4 are typical corrosion problems in fuel oil-fired electric power units. High-temperature corrosion tests were performed using both electrochemical polarization and immersion techniques. The temperature interval of this study was 600°C to 900°C, and the molten salts were 80wt%V2O5-20wt%Na2SO4. Curves of corrosion current density vs temperature obtained by the potentiodynamic studies are reported, as well as the weight loss vs temperature curves from molten salt immersion tests. Both Fe-Si coatings and FeAl40at%+0.1at%B+10vol%Al2O3 showed good behavior against molten salt corrosion. The final results show the potential of these coatings and alloys to solve the high-temperature corrosion in fuel oil-fired electric power units.


2016 ◽  
Vol 59 (3) ◽  
pp. 242-257 ◽  
Author(s):  
S.S. Sawant ◽  
B.D. Gajbhiye ◽  
S. Tyagi ◽  
C.S. Sona ◽  
R. Divya ◽  
...  

2013 ◽  
Vol 49 (4) ◽  
pp. 287-295 ◽  
Author(s):  
C. S. Sona ◽  
B. D. Gajbhiye ◽  
P. V. Hule ◽  
A. W. Patwardhan ◽  
C. S. Mathpati ◽  
...  

2017 ◽  
Vol 125 ◽  
pp. 184-193 ◽  
Author(s):  
Hanliang Zhu ◽  
Rohan Holmes ◽  
Tracey Hanley ◽  
Joel Davis ◽  
Ken Short ◽  
...  

1998 ◽  
Vol 552 ◽  
Author(s):  
M. Amaya ◽  
E. J. Lavernia ◽  
L. Martinez

ABSTRACTWe studied the high temperature corrosion of spray atomized and deposited FeAl40at% based intermetallic alloys immersed in a molten salt mixture of 80%V2O 5+20%Na2SO4 (wt%) over the temperature range of 600–900°C. Experiments were realized by the weight loss method and the potentiodynamic polarization electrochemical technique in three different samples: FeA140at%, FeA140+0.lat%B and FeA140+0.lat%B+10at%A12O3. Measurements of weight loss and corrosion current density as a function of the molten salts temperature were obtained and discussed in terms of the passive layer morphology and corrosion products formed during the tests. It was found that the iron aluminide doped with boron and reinforced with alumina particulate was more corrosion resistant in the test temperature range. The weight loss experiments revealed that at 700°C all alloys developed maximum corrosion rate. This behavior was related with the dissolution of protective oxide layer on metal base due the formation of vanadate phases which are highly corrosive at this temperature.


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