Electrochemical and electromechanical properties of high-performance fluoropolymer/ionic liquid (with wide electrochemical window of 6 V) gel hybrid actuators based on single-walled carbon nanotubes

2019 ◽  
Vol 95 ◽  
pp. 77-82
Author(s):  
Naohiro Terasawa
RSC Advances ◽  
2019 ◽  
Vol 9 (15) ◽  
pp. 8215-8221 ◽  
Author(s):  
Naohiro Terasawa ◽  
Kinji Asaka

This study describes new actuators with cellulose nanofibers, single-walled carbon nanotubes and ionic liquids (CNFs/SWCNTs/ILs) and examines the electrochemical and electromechanical properties of the CNF/SWCNT/IL gel hybrid actuators.


RSC Advances ◽  
2017 ◽  
Vol 7 (5) ◽  
pp. 2443-2449 ◽  
Author(s):  
Naohiro Terasawa

The electrochemical and electromechanical properties of actuators based on an ionic and non-ionic fluoropolymer gel, and an ionic liquid, fabricated using a single-walled carbon nanotube gel electrode.


2017 ◽  
Vol 199 ◽  
pp. 405-422 ◽  
Author(s):  
Hyacinthe Randriamahazaka ◽  
Kinji Asaka

We investigate the electromechanical properties of bucky-gel electrochemical actuators incorporating various amounts of single-walled carbon nanotubes and an ionic liquid electrolyte, 1-butyl-3-methylimidazolium tetrafluoroborate, that are able to convert electrochemical energy into mechanical energy. The interplay between mechanical and electrochemical effects is studied. The electromechanical responses are investigated by means of electrochemical impedance spectroscopy and bending displacement measurements. We develop a theoretical model that allows us to rationalize the electromechanical properties of the bucky-gel actuators. This model takes into account electrochemical stress due to the intercalation (de-intercalation) process, which generates the strain and bending of the actuators. We then analyze the relationship between the strain and the real part of the complex capacitance by introducing a strain–capacitance coefficient. This coefficient is related to the electrochemical stress and the amount of the ionic adsorption (desorption) at the double-layer. From a practical point of view, the determination of the strain–capacitance coefficient is helpful for characterizing and optimizing the performance of electrochemical actuators.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jae-Won Lee ◽  
Joon Young Cho ◽  
Mi Jeong Kim ◽  
Jung Hoon Kim ◽  
Jong Hwan Park ◽  
...  

AbstractSoft electronic devices that are bendable and stretchable require stretchable electric or electronic components. Nanostructured conducting materials or soft conducting polymers are one of the most promising fillers to achieve high performance and durability. Here, we report silver nanoparticles (AgNPs) embedded with single-walled carbon nanotubes (SWCNTs) synthesized in aqueous solutions at room temperature, using NaBH4 as a reducing agent in the presence of highly oxidized SWCNTs as efficient nucleation agents. Elastic composite films composed of the AgNPs-embedded SWCNTs, Ag flake, and polydimethylsiloxane are irradiated with radiation from a Xenon flash lamp within a time interval of one second for efficient sintering of conductive fillers. Under high irradiation energy, the stretchable electrodes are created with a maximum conductivity of 4,907 S cm−1 and a highly stretchable stability of over 10,000 cycles under a 20% strain. Moreover, under a low irradiation energy, strain sensors with a gauge factor of 76 under a 20% strain and 5.4 under a 5% strain are fabricated. For practical demonstration, the fabricated stretchable electrode and strain sensor are attached to a human finger for detecting the motions of the finger.


Author(s):  
Sujay Deshmukh ◽  
Zoubeida Ounaies

Efforts to enhance the electromechanical properties of Poly(vinylidene fluoride) (PVDF) and its copolymers have been directed at optimizing the molecular chemistry, stretching and poling parameters. This study investigates an alternative approach to enhancing the properties via adding nanoinclusions in PVDF. We investigate the enhanced electrostrictive response in PVDF by adding Single Walled Carbon Nanotubes (SWNTs). We also show the change in the non-polar morphology of “as-is” PVDF to the polar γ phase by adding SWNTs and eventually to the piezoelectric β phase by stretching the nanocomposites.


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