Mechanism for hydrogen evolution reaction on pipeline steel in near-neutral pH solution

2007 ◽  
Vol 9 (4) ◽  
pp. 558-562 ◽  
Author(s):  
Y.F. Cheng ◽  
L. Niu
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Pipeline Steel ◽  
Neutral Ph

scholarly journals A Supramolecular Porous Organic Cage Platform Promotes Electrochemical Hydrogen Evolution from Water Catalyzed by Cobalt Porphyrins

2021 ◽  
Author(s):  
Peter T. Smith ◽  
Bahiru Punja Benke ◽  
Lun An ◽  
Younghoon Kim ◽  
Kimoon Kim ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Supramolecular Structure ◽  
Fold Increase ◽  
Faradaic Efficiency ◽  
Tafel Slope ◽  
Neutral Ph ◽  
Catalyst Film ◽  
Electrochemically Active ◽  
Cobalt Porphyrins

We report a supramolecular porous organic cage platform composed of cobalt porphyrins for catalyzing the electrochemical hydrogen evolution reaction (HER) from water at neutral pH. Owing to its permanent porosity, the supramolecular structure yields a catalyst film with a 5-fold increase in the number of electrochemically active cobalt atoms and an improvement in Tafel slope from 170 mV/decade to 119 mV/decade compared to a planar cobalt porphyrin analog, reaching activities over 19,000 turnovers for HER over a 24-hour period with 100% Faradaic efficiency.

scholarly journals A Supramolecular Porous Organic Cage Platform Promotes Electrochemical Hydrogen Evolution from Water Catalyzed by Cobalt Porphyrins

2021 ◽  
Author(s):  
Peter T. Smith ◽  
Bahiru Punja Benke ◽  
Lun An ◽  
Younghoon Kim ◽  
Kimoon Kim ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Supramolecular Structure ◽  
Fold Increase ◽  
Faradaic Efficiency ◽  
Tafel Slope ◽  
Neutral Ph ◽  
Catalyst Film ◽  
Electrochemically Active ◽  
Cobalt Porphyrins

We report a supramolecular porous organic cage platform composed of cobalt porphyrins for catalyzing the electrochemical hydrogen evolution reaction (HER) from water at neutral pH. Owing to its permanent porosity, the supramolecular structure yields a catalyst film with a 5-fold increase in the number of electrochemically active cobalt atoms and an improvement in Tafel slope from 170 mV/decade to 119 mV/decade compared to a planar cobalt porphyrin analog, reaching activities over 19,000 turnovers for HER over a 24-hour period with 100% Faradaic efficiency.

Self-supported CoMoS4 nanosheet array as an efficient catalyst for hydrogen evolution reaction at neutral pH

Nano Research ◽  
2018 ◽  
Vol 11 (4) ◽  
pp. 2024-2033 ◽  
Author(s):  
Xiang Ren ◽  
Dan Wu ◽  
Ruixiang Ge ◽  
Xu Sun ◽  
Hongmin Ma ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Efficient Catalyst ◽  
Neutral Ph ◽  
Nanosheet Array

Nickel-Based Water-Soluble Metallopolymer for the Electrochemical Hydrogen Evolution Reaction in Neutral-pH Water

2021 ◽  
Vol 3 (10) ◽  
pp. 5051-5060
Author(s):  
Thongpon Meethong ◽  
Panittha Damsongsang ◽  
Kamonwad Ngamchuea ◽  
Kittipong Chainok ◽  
Somboon Sahasithiwat ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Water Soluble ◽  
Neutral Ph
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