Facile Synthesis and Electrochemical Performance of Carbon-Coated V2O5 Cathode Materials Using Carboxylic Acids as Carbon Source

2014 ◽  
Vol 139 ◽  
pp. 408-414 ◽  
Author(s):  
Jihyun Shin ◽  
Taegyeong Kim ◽  
Jiwoon Je ◽  
Tae-Soo You ◽  
Jongsik Kim
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xing Shen ◽  
Quan Zhou ◽  
Miao Han ◽  
Xingguo Qi ◽  
Bo Li ◽  
...  

AbstractNa-ion batteries have been considered promising candidates for stationary energy storage. However, their wide application is hindered by issues such as high cost and insufficient electrochemical performance, particularly for cathode materials. Here, we report a solvent-free mechanochemical protocol for the in-situ fabrication of sodium vanadium fluorophosphates. Benefiting from the nano-crystallization features and extra Na-storage sites achieved in the synthesis process, the as-prepared carbon-coated Na3(VOPO4)2F nanocomposite exhibits capacity of 142 mAh g−1 at 0.1C, higher than its theoretical capacity (130 mAh g−1). Moreover, a scaled synthesis with 2 kg of product was conducted and 26650-prototype cells were demonstrated to proof the electrochemical performance. We expect our findings to mark an important step in the industrial application of sodium vanadium fluorophosphates for Na-ion batteries.


Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1672
Author(s):  
Shih-Chieh Hsu ◽  
Tzu-Ten Huang ◽  
Yen-Ju Wu ◽  
Cheng-Zhang Lu ◽  
Huei Chu Weng ◽  
...  

Carbon-coated Li4Ti5O12 (LTO) has been prepared using polyimide (PI) as a carbon source via the thermal imidization of polyamic acid (PAA) followed by a carbonization process. In this study, the PI with different structures based on pyromellitic dianhydride (PMDA), 4,4′-oxydianiline (ODA), and p-phenylenediamine (p-PDA) moieties have been synthesized. The effect of the PI structure on the electrochemical performance of the carbon-coated LTO has been investigated. The results indicate that the molecular arrangement of PI can be improved when the rigid p-PDA units are introduced into the PI backbone. The carbons derived from the p-PDA-based PI show a more regular graphite structure with fewer defects and higher conductivity. As a result, the carbon-coated LTO exhibits a better rate performance with a discharge capacity of 137.5 mAh/g at 20 C, which is almost 1.5 times larger than that of bare LTO (94.4 mAh/g).


2020 ◽  
Vol 29 (4) ◽  
pp. 2542-2550
Author(s):  
Mohamad Izha Ishak ◽  
Mohd Sobri Idris ◽  
Rozana A. M. Osman ◽  
S. M. Hasanaly ◽  
A. H. Hashim ◽  
...  

2016 ◽  
Vol 16 (3) ◽  
pp. 226-230 ◽  
Author(s):  
Mansoo Choi ◽  
In-Ho Jo ◽  
Sang-Hun Lee ◽  
Yang-Il Jung ◽  
Jei-Kwon Moon ◽  
...  

2009 ◽  
Vol 117 (1371) ◽  
pp. 1225-1228 ◽  
Author(s):  
Yuta MIZUNO ◽  
Masashi KOTOBUKI ◽  
Hirokazu MUNAKATA ◽  
Kiyoshi KANAMURA

2011 ◽  
Vol 56 (5) ◽  
pp. 2269-2275 ◽  
Author(s):  
Y.Q. Qiao ◽  
X.L. Wang ◽  
J.Y. Xiang ◽  
D. Zhang ◽  
W.L. Liu ◽  
...  

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