Heat release during thermally-induced failure of a lithium ion battery: Impact of cathode composition

2016 ◽  
Vol 85 ◽  
pp. 10-22 ◽  
Author(s):  
Xuan Liu ◽  
Zhibo Wu ◽  
Stanislav I. Stoliarov ◽  
Matthew Denlinger ◽  
Alvaro Masias ◽  
...  
2018 ◽  
Vol 165 (11) ◽  
pp. A2909-A2918 ◽  
Author(s):  
Xuan Liu ◽  
Zhibo Wu ◽  
Stanislav I. Stoliarov ◽  
Matthew Denlinger ◽  
Alvaro Masias ◽  
...  

2015 ◽  
Vol 280 ◽  
pp. 516-525 ◽  
Author(s):  
Xuan Liu ◽  
Stanislav I. Stoliarov ◽  
Matthew Denlinger ◽  
Alvaro Masias ◽  
Kent Snyder

Author(s):  
Jun Guo ◽  
Haibin Wang ◽  
Yuanhua He

Abstract The fire hazard of lithium-ion batteries (LIBs) poses a serious threat to their transportation and use. The purpose of this study is to investigate the efficiency of low-pressure twin-fluid water mist (TFWM) on suppressing lithium-ion battery fires. Experiments were executed to research the effect of working pressures and release stages on extinguishing the fire. Aqueous vermiculite dispersion (AVD), a commercial agent that was specifically designed to extinguish battery fires, was chosen to compare with the fire suppression performance of TFWM under the same conditions. The results indicate that the type 21,700 LIB fires could be controlled by applying the water mist within 10 s. The cooling ability at various working pressures (0.4, 0.8, 1.0, and 1.2 MPa) demonstrated an increase in inhibitory effects as the working pressure increased, and the optimal pressure was 1.2 MPa. The results further show that the extinguishing ability of the TFWM was better than the AVD agent. When the water mist was applied at the optimal working pressure, the surface temperature, flame temperature and concentration of CO reduced more significantly, compared with the AVD agent. Therefore, the TFWM shows considerable merit as a candidate to fight LIB fires.


2019 ◽  
Vol 37 (1) ◽  
pp. 81-95 ◽  
Author(s):  
Zhi Wang ◽  
Xiaoyao Ning ◽  
Kang Zhu ◽  
Jianyao Hu ◽  
Han Yang ◽  
...  

A series of experiments were conducted to study the thermal failure hazard of large-format commercial lithium-ion batteries with typical states of charge in a calorimeter apparatus. The results indicate that the thermal failure penetration of the lithium-ion battery with 70% state of charge is faster than the lithium-ion battery with 50% state of charge. Two typical thermal failure modes, “Gas-driven mode” and “Flame-driven mode,” were also observed, corresponding to lithium-ion battery with 70% state of charge and 50% state of charge, respectively. Significant heat release, accompanied by large amount of carbon dioxide (CO2) release, took place for lithium-ion battery with 50% state of charge. Inversely, lithium-ion battery with 70% state of charge presented a lower heat release while more carbon monoxide (CO) generation and obvious mass loss trend. This study may serve as a reference for safe storage, application, and transportation in lithium-ion batteries.


2019 ◽  
Vol 199 ◽  
pp. 111969 ◽  
Author(s):  
Tong Liu ◽  
Yangpeng Liu ◽  
Xishi Wang ◽  
Xiangxiao Kong ◽  
Guochun Li

Author(s):  
Xiantao Chen ◽  
Xu Zhang ◽  
Haibin Wang ◽  
Jingyun Jia ◽  
Song Xie ◽  
...  

Abstract The thermal runaway hazards pose serious threat to the application and transport of lithium-ion battery on the aircraft. Hence the researches of thermal safety in flight condition are necessary. In this study, the tests were conducted in a dynamic pressure chamber to study the effects of ambient pressure and heating power on the thermal runaway characteristics. The results show that the fierce behaviors of jet fire, deflagration and explosion only were observed in high ambient pressure with high heating power. The open time of safety valve is advanced as pressure from 95 kPa to 20 kPa. The parameters of heat release rate (HRR), total heat release (THR), cell surface temperature, peak concentration of CO2 and mass loss decrease as the descend of external pressure or heating power. The peak values of hydrocarbon (CHx) and CO increase with the descent of pressure, but decrease as the reduction of heating power. The effects of ambient pressure on the thermal runaway (TR) fire behaviors mainly attribute to the low oxygen density. The time of heating and smoking may account for the difference of TR behaviors with various heating power. It is revealed that the fire risk and the hazards of toxic/flammable gas emissions are tightly relative to the TR behaviors. Those results provide valuable proposals and inspiration for the safety warning and hazard reduction under low pressure.


2021 ◽  
Vol 35 (3) ◽  
pp. 1-6
Author(s):  
Soo-Gyeong Park ◽  
Sin-Woo Kim ◽  
Eui-Ju Lee

The lithium-ion battery is the most popular type of secondary battery because of its high energy density. It has been widely used in mobile power and energy storage systems. However, several accidents can occur in systems using lithium-ion batteries, and most of the reported losses have resulted from battery fires and explosions. In this study, a cone calorimeter experiment was performed to investigate the fire characteristics of lithium-ion batteries and assess their heat release rate (HRR), which is the most representative property for fire events. Fires involving cylindrical standard batteries consist of two combustion stages. The first burning stage is due to the package material and intercalated lithium of the battery, and the second stage is attributed to the thermal runaway reactions of the electrolyte. The second combustion stage has a greater peak HRR than the first stage and is accompanied by a violent explosion. In a comparison of the HRRs with the oxygen consumption rate, the HRRs measured on the basis of the mass loss rate show higher maximum values and extremely narrow heat release times.


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