Experimental comparison of Oxygen Consumption Calorimetry and Sensible Enthalpy Rise Approach for determining the heat release rate of large-scale lithium-ion battery fires

2021 ◽  
Vol 126 ◽  
pp. 103447
Author(s):  
Sascha Voigt ◽  
Felix Sträubig ◽  
Stephan Palis ◽  
Arno Kwade ◽  
Christian Knaust
Author(s):  
Jiann C. Yang

The derivations of the formulas for heat release rate calculations are revisited based on the oxygen consumption principle. A systematic, structured, and pedagogical approach to formulate the problem and derive the generalized formulas with fewer assumptions is used. The operation of oxygen consumption calorimetry is treated as a chemical flow process, the problem is formulated in matrix notation, and the associated material balances using the tie component concept commonly used in chemical engineering practices are solved. The derivation procedure described is intuitive and easy to follow. Inclusion of other chemical species in the measurements and calculations can be easily implemented using the generalized framework developed here.


1984 ◽  
Vol 2 (5) ◽  
pp. 380-395 ◽  
Author(s):  
W.J. Parker

The calculation of heat release rate by oxygen consumption is based on the assumption that all materials release approximately the same amount of heat per unit mass of oxygen consumed. This technique is now being employed to determine the heat release rate of materials in various heat release rate cal orimeters. Other uses include the heat release rate of assemblies in the fire en durance furnaces and the total heat release rate in room fire tests. These dif ferent applications lead to different experimental procedures which require dif ferent formulas. The experimental choices or constraints include open or closed systems, paramagnetic or high temperature oxygen analyzers, CO2 analyzers or CO2 traps, and the use of a gas burner whose heat release rate must be deducted from the total. Various assumptions about CO levels in the exhaust duct and vitiation and humidity in the incoming air are made. General formulas for the heat release rate by oxygen consumption are developed in this paper from which the formulas for specific applications can easily be derived.


Author(s):  
Alexander J. De Rosa ◽  
Janith Samarasinghe ◽  
Stephen J. Peluso ◽  
Bryan D. Quay ◽  
Domenic A. Santavicca

Fluctuations in the heat release rate that occur during unstable combustion in lean premixed gas turbine combustors can be attributed to velocity and equivalence ratio fluctuations. For a fully premixed flame, velocity fluctuations affect the heat release rate primarily by inducing changes in the flame area. In this paper, a technique to analyze changes in flame area using chemiluminescence-based flame images is presented. The technique decomposes the flame area into separate components which characterize the relative contributions of area fluctuations in the large scale structure and the small scale wrinkling of the flame. The fluctuation in the wrinkled area of the flame which forms the flame brush is seen to dominate its response in the majority of cases tested. Analysis of the flame area associated with the large scale structure of the flame resolves convective perturbations that move along the mean flame position. Results are presented that demonstrate the application of this technique to both single-nozzle and multi-nozzle flames.


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