Silver/poly(N-vinyl-2-pyrrolidone) (Ag/PVP) nanocomposites were obtained by
electrochemical reduction of Ag+ ions at a constant voltage, by the in situ
synthesis of silver nanoparticles inside poly(N-vinyl-2-pyrrolidone) matrix,
previously crosslinked by ?-irradiation. Optimal values of synthesis
parameters were investigated: the composition of the solution for swelling of
PVP hydrogel, implementation time and applied voltage. Ag/PVP nanocomposites
were characterized by UV-visible spectroscopy, and IR spectroscopy.
UV-visible spectroscopy results shown that the reduction of silver ions was
more efficient when the more conductive solution for swelling of PVP hydrogel
was used, i.e. the solution containing 3.9 mM AgNO3 with 0.1 M KNO3. Also, it
was shown that the concentration of the reduced silver increases with the
increase in implementation time and applied voltage, up to the values of 4
min, and 200 V, respectively. The Ag nanoparticle size was estimated to be 25
nm, by comparison of the experimental results of UV-vis spectroscopy with the
theoretical predictions obtained by the calculations in ?MiePlot v.3.4?
computer program, having the algorithm based on Mie scattering from a sphere.
The results of FTIR spectroscopy have shown that Ag nanoparticles are mainly
bonded to PVP by coordination bondages between Ag nanoparticles and N from
the pyrrolidone ring of PVP.