Corrigendum to: Synthesis, spectroscopic characterization, X-ray crystal structure and magnetic properties of oxalato-bridged copper(II) dinuclear complexes with di-2-pyridylamine [Inorganica Chimica Acta 353 (2003) 119–128]

New nickel-deficient stannides Eu2Ni2−xSn5 were synthesized by induction melting of the elements in sealed tantalum tubes. The solid solution was studied by X-ray powder diffraction and two crystal structures were refined on the basis of X-ray diffractometer data: Cmcm, a = 466.03(4), b = 3843.1(8), c = 462.92(9) pm, wR2 = 0.0469, 692 F2 values, 39 variables for Eu2Ni1.49(1)Sn5 and a = 466.11(9), b = 3820.1(8), c = 462.51(9) pm, wR2 = 0.0358, 695 F2 values, 39 variables for Eu2Ni1.35(1)Sn5. This new structure type can be considered as an intergrowth structure of CaBe2Ge2- and CrB-related slabs. The striking structural motifs are nickel-centered square pyramids which are condensed via common corners and edges. The layers of condensed NiSn5 units are separated by the europium atoms. The Ni1 sites within the CaBe2Ge2 slabs show significant defects which leads to split positions for one tin site. Eu2Ni1.50Sn5 shows Curie-Weiss behavior and an experimental magnetic moment of 7.74(1) μB / Eu atom, indicating stable divalent europium, as is also evident from 151Eu Mössbauer spectra. Antiferromagnetic ordering is detected at 3.5 K.

Download Full-text

Darstellung, Reaktionen und spektroskopische Charakterisierung von [Os2X8]2-, X = Cl, Br, I, und Kristallstruktur von (PPN)2[Os2I8] · 2 CH2Cl2 / Preparation, Reactions and Spectroscopic Characterization of [Os2X8]2-, X = Cl, Br, I, and Crystal Structure of (PPN)2[Os2I8] · 2 CH2Cl2

Zeitschrift für Naturforschung B ◽

10.1515/znb-1990-1011 ◽

1990 ◽

Vol 45 (10) ◽

pp. 1416-1424 ◽

Cited By ~ 8

Author(s):

W. Preetz ◽

P. Hollmann ◽

G. Thiele ◽

H. Hillebrecht

Keyword(s):

Crystal Structure ◽

Structure Determination ◽

Triple Bond ◽

Room Temperature ◽

Spectroscopic Characterization ◽

Spectroscopic Constants ◽

Monoclinic System ◽

X Ray ◽

Fine Structures

The triply bonded octahalogenodiosmate(III) anions [Os2X8]2-, previously known with X = Cl, Br, have now been extended to include the iodide with two staggered OsI4 units. This compound was prepared by treating [Os2Cl8]2- with Nal at room temperature in acetone solution. The structure determination by X-ray diffractometry on single crystals of (PPN)2[Os2I8] · 2 CH2Cl2, reveals crystallization in the monoclinic system, space group P21/c with Z = 4. The Os-Os triple bond is with 2.212(1) Å the longest within the three octahalogenodiosmates(III). The Raman spectra show ν(OsOs) at 285, [Os2Cl8]2-; at 287, [Os2Br8]2- and for the iodo compound at 270.1 cm-1 with up to three overtones. The spectroscopic constants are calculated to be ω1 = 270.9 cm-1; X11 = -0.50 cm-1. The 10 Κ UV-VIS spectra of solid [(n-C4H9)4N]2[Os2X8] exhibit δ-π* transitions with maxima at 723, 690 and 643 nm, superimposed by vibrational fine structures with long progressions of 195, 211 and 183 cm-1 for X = Cl, Br, I, respectively. Oxidation of [Os2X8]2-, X = Cl, Br with the corresponding halogen leads to the cleavage of the Os-Os bond, and the dekahalogenodiosmates(IV), [Os2X10]2-, are formed

Download Full-text

Magnetic and Structural Properties of Ferrimagnetic Bioceramics

Materials Science Forum ◽

10.4028/www.scientific.net/msf.473-474.117 ◽

2005 ◽

Vol 473-474 ◽

pp. 117-122 ◽

Cited By ~ 1

Author(s):

A.C. Kis ◽

Th. Leventouri ◽

J.R. Thompson

Keyword(s):

Crystal Structure ◽

Heat Treatment ◽

Magnetic Properties ◽

Calcium Phosphate ◽

Powder Diffraction ◽

Magnetic Measurements ◽

Treatment Temperature ◽

Monoclinic Crystal ◽

X Ray ◽

Phase Development

Structure and magnetic properties of ferrimagnetic bioceramics in the system {0.45(CaO, P2O5) ySiO2 xFe2O3 0.03Na2O}, x=0.05, 0.10, 0.15, 0.20, were studied by x-ray powder diffraction and magnetic measurements. Magnetite and calcium phosphate, crystallizing in the hexagonal and monoclinic crystal systems, are the major phases in the compounds. Phase development, crystal structure, and magnetic properties of the composites are determined by the specific starting composition of oxides and the heat-treatment temperature.

Download Full-text