scholarly journals Creation of Lunar and Hermean analogue mineral powder samples for solar wind irradiation experiments and mid-infrared spectra analysis

Icarus ◽  
2021 ◽  
Vol 365 ◽  
pp. 114492
Author(s):  
Noah Jäggi ◽  
André Galli ◽  
Peter Wurz ◽  
Herbert Biber ◽  
Paul Stefan Szabo ◽  
...  
2020 ◽  
Author(s):  
Noah Jäggi ◽  
Paul Stefan Szabo ◽  
Herbert Biber ◽  
Klaus Mezger ◽  
Friedrich Aumayr ◽  
...  

2020 ◽  
Author(s):  
Noah Jäggi ◽  
André Galli ◽  
Peter Wurz ◽  
Herbert Biber ◽  
Paul S. Szabo ◽  
...  

<p>The surfaces of Mercury and Moon are thought to be similar in terms of being rocky, regolith covered planetary bodies, dominated by pyroxene and plagioclase (Taylor et al. 1991, McCoy et al. 2018). Contrary to the Moon, Mercury possesses a global dipole magnetic field, resulting in a highly dynamic magnetosphere that varies surface exposure to solar wind ions and energetic electrons (Winslow et al. 2017, Gershman et al. 2015). The energy of these particles is thereby transferred and material is sputtered from the surface (Sigmund 2012), providing the main contributions to the exospheres of the Moon and Mercury. Parametrizing the underlying sputtering processes is of great interest for successfully linking exosphere observations with surface compositions (e.g. Wurz et al. 2010, Merkel et al. 2018).</p><p>The understanding of sputtering from the kinetic energy transfer is sufficient to predict sputter yields of singly charged impinging ions on conducting surfaces (e.g., Stadlmayr et al. 2018). Hijazi et al. (2017) and Szabo et al. (2018) have also made advancements on potential sputtering, investigating the interaction of multiply charged ions with glassy thin films. We expand on their studies and use mineral powder pellets as analogues for sputtering experiments relevant to the surfaces of the Moon and Mercury. The powder pellets include plagioclase, pyroxene, and wollastonite. The latter is a pyroxene-like Ca-rich mineral with Fe contents below detection limits, which allows investigating the effect on reflectivity during sputtering of Fe-free minerals. With these analogues, we strive to supply infrared spectra with a focus on the robust mid infrared (MIR) range for Mercury and sputter yields for both the Moon and Mercury. </p><p>First results of irradiated mineral pellets include MIR spectra of the minerals before and after irradiation as well as sputtering yields and visual alteration effects. So far, no relevant changes in the MIR spectra were observed nor any visual alteration of wollastonite. The first irradiation with 4 keV <sup>4</sup>He<sup>+</sup> reached a fluence of about 29 E+20 ions per m<sup>2</sup> at an angle of 30°. Presumably, the lack of visual alteration is due to the absence of Fe in wollastonite. Further results are expected to bring clarity in the reaction of pellets to irradiation and if their sputtering characteristics differ from those of glassy thin films.</p><p>Gershman, D. J., et al. (2015). J. Geophys. Res.-Space, 120(10).</p><p>Hiesinger, H., & Helbert, J. (2010). Planet. Space Sci., 58(1–2).</p><p>Hijazi, H., et al. (2017). J. Geophys. Res.-Planet, 122(7).</p><p>McCoy, T. J., et al. (2018). Mercury: The View after MESSENGER.</p><p>Sigmund, P. (2012). Thin Solid Films, 520(19).</p><p>Stadlmayr, R., et al. (2018). Nucl. Instrum. Meth. B, 430.</p><p>Szabo, P. S., et al. (2018). Icarus, 314.</p><p>Taylor, G. J., et al. (1991). Lunar sourcebook-A user’s guide to the moon.</p><p>Winslow, R. M., et al. (2017). J. Geophys. Res.-Space, 122(5).</p><p> </p>


1993 ◽  
Vol 1 (2) ◽  
pp. 99-108 ◽  
Author(s):  
P. Robert ◽  
M.F. Devaux ◽  
A. Qannari ◽  
M. Safar

Multivariate data treatments were applied to mid and near infrared spectra of glucose, fructose and sucrose solutions in order to specify near infrared frequencies that characterise each carbohydrate. As a first step, the mid and near infrared regions were separately studied by performing Principal Component Analyses. While glucose, fructose and sucrose could be clearly identified on the similarity maps derived from the mid infrared spectra, only the total sugar content of the solutions was observed when using the near infrared region. Characteristic wavelengths of the total sugar content were found at 2118, 2270 and 2324 nm. In a second step, the mid and near infrared regions were jointly studied by a Canonical Correlation Analysis. As the assignments of frequencies are generally well known in the mid infrared region, it should be useful to study the relationships between the two infrared regions. Thus, the canonical patterns obtained from the near infrared spectra revealed wavelengths that characterised each carbohydrate. The OH and CH combination bands were observed at: 2088 and 2332 nm for glucose, 2134 and 2252 nm for fructose, 2058 and 2278 nm for sucrose. Although a precise assignment of the near infrared bands to chemical groups within the molecules was not possible, the present work showed that near infrared spectra of carbohydrates presented specific features.


1994 ◽  
Vol 31 (7) ◽  
pp. 205
Author(s):  
Stephen P. Gurden ◽  
Richard G. Brereton ◽  
John A. Groves

Geoderma ◽  
2015 ◽  
Vol 247-248 ◽  
pp. 65-72 ◽  
Author(s):  
Mohsen Forouzangohar ◽  
Jeffrey A. Baldock ◽  
Ronald J. Smernik ◽  
Bruce Hawke ◽  
Lauren T. Bennett

2019 ◽  
Vol 102 (12) ◽  
pp. 11751-11765 ◽  
Author(s):  
T.M. Denninger ◽  
F. Dohme-Meier ◽  
L. Eggerschwiler ◽  
A. Vanlierde ◽  
F. Grandl ◽  
...  

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