Heat transfer behavior of elemental sulfur for low temperature thermal energy storage applications

Author(s):  
K. Nithyanandam ◽  
A. Barde ◽  
R.E. Wirz
Author(s):  
Karthik Nithyanandam ◽  
Amey Barde ◽  
Louis Tse ◽  
Reza Baghaei Lakeh ◽  
Richard Wirz

Efficient and cost-effective thermal energy storage system plays an important role in energy conservation. Elemental sulfur, the thirteenth most abundant element on earth, is actively being researched as a potential thermal storage medium due to its high energy storage density and low cost. The present work investigates the heat transfer behavior of elemental sulfur at temperatures between 50 degree Celsius and 250 degree Celsius. A shell and tube heat exchanger configuration with sulfur stored inside the tubes and heat transfer fluid flowing over the tubes through the shell is considered. A detailed computational model solving for the conjugate heat transfer and solid-liquid phase change dynamics of the sulfur based thermal energy storage system is developed to elucidate the complex interplay between the governing heat transfer and fluid flow phenomena during charge and discharge operations. The developed numerical model is compared with experimental results and a systematic parametric analysis of the effects of various design parameters on the performance of the thermal storage system is reported.


2016 ◽  
Author(s):  
Mitchell Shinn ◽  
Karthik Nithyanandam ◽  
Amey Barde ◽  
Richard Wirz

Currently, concentrated solar power (CSP) plants utilize thermal energy storage (TES) in order to store excess energy so that it can later be dispatched during periods of intermittency or during times of high energy demand. Elemental sulfur is a promising candidate storage fluid for high temperature TES systems due to its high thermal mass, moderate vapor pressure, high thermal stability, and low cost. The objective of this paper is to investigate the behavior of encapsulated sulfur in a shell and tube configuration. An experimentally validated, transient, two-dimensional numerical model of the shell and tube TES system is presented. Initial results from both experimental and numerical analysis show high heat transfer performance of sulfur. The numerical model is then used to analyze the dynamic response of the elemental sulfur based TES system for multiple charging and discharging cycles. A sensitivity analysis is performed to analyze the effect of geometry (system length), cutoff temperature, and heat transfer fluid on the overall utilization of energy stored within this system. Overall, this paper demonstrates a systematic parametric study of a novel low cost, high performance TES system based on elemental sulfur as the storage fluid that can be utilized for different high temperature applications.


2017 ◽  
Vol 1 (8) ◽  
pp. 1820-1829 ◽  
Author(s):  
D. Dong ◽  
T. D. Humphries ◽  
D. A. Sheppard ◽  
B. Stansby ◽  
M. Paskevicius ◽  
...  

A prototype metal hydride reactor using supercritical water as a heat transfer fluid for thermal energy storage applications.


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