Analysis of liquid water transport in cathode catalyst layer of PEM fuel cells

2010 ◽  
Vol 35 (6) ◽  
pp. 2403-2416 ◽  
Author(s):  
Prodip K. Das ◽  
Xianguo Li ◽  
Zhong-Sheng Liu
Author(s):  
Prodip K. Das ◽  
Xianguo Li ◽  
Zhong-Sheng Liu

The performance of a polymer electrolyte membrane (PEM) fuel cell is significantly affected by liquid water generated at the cathode catalyst layer (CCL). Conversely, the ionic conductivity of PEM is directly proportional to its water content; it must have sufficient water. Therefore, it is essential to maintain a delicate water balance, which seems difficult without properly understanding liquid water transport from the CCL. In the present study, a one-dimensional analytical solution of liquid water transport across the CCL is derived from the fundamental transport equations. The effect of CCL wettability on liquid water transport and the effect of liquid water “flooding” on reactant transport have been investigated. It has been observed that hydrophilic characteristic of a CCL plays significant role on the liquid water transport. The liquid water saturation in a hydrophilic CCL can be reduced by increasing the surface wettability or lowering contact angle. Based on a dimensionless time constants analysis, it has been shown that liquid water production from the phase change process is negligible compared to water production from the electrochemical process.


Author(s):  
Luis Breziner ◽  
Peter Strahs ◽  
Parsaoran Hutapea

The objective of this research is to analyze the effects of vibration on the performance of hydrogen PEM fuel cells. It has been reported that if the liquid water transport across the gas diffusion layer (GDL) changes, so does the overall cell performance. Since many fuel cells operate under a vibrating environment –as in the case of automotive applications, this may influence the liquid water concentration across the GDL at different current densities, affecting the overall fuel cell performance. The problem was developed in two main steps. First, the basis for an analytical model was established using current models for water transport in porous media. Then, a series of experiments were carried, monitoring the performance of the fuel cell for different parameters of oscillation. For sinusoidal vibration at 10, 20 and 50Hz (2 g of magnitude), a decrease in the fuel cell performance by 2.2%, 1.1% and 1.3% was recorded when compared to operation at no vibration respectively. For 5 g of magnitude, the fuel cell reported a drop of 5.8% at 50 Hz, whereas at 20 Hz the performance increased by 1.3%. Although more extensive experimentation is needed to identify a relationship between magnitude and frequency of vibration affecting the performance of the fuel cell as well as a throughout examination of the liquid water formation in the cathode, this study shows that sinusoidal vibration, overall, affects the performance of PEM fuel cells.


RSC Advances ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 2216-2226
Author(s):  
Yunqi Li ◽  
Xiran Chen ◽  
Yuwei Liu ◽  
Danping Xiong ◽  
Jing Li ◽  
...  

An analytical modeling framework coupling carbon corrosion and an agglomerate model is established to predict the performance degradation of the cathode catalyst layer (cCL) during startup–shutdown cycles.


2019 ◽  
Vol 12 (1) ◽  
pp. 67-79 ◽  
Author(s):  
Jay B. Benziger ◽  
Tamara Whitaker ◽  
Erin Kimball ◽  
Ioannis G. Kevrekidis

2011 ◽  
Vol 52 (10) ◽  
pp. 1954-1959
Author(s):  
S. Ahadian ◽  
N. Khajeh-Hosseini-Dalasm ◽  
K. Fushinobu ◽  
K. Okazaki ◽  
Y. Kawazoe

2004 ◽  
Vol 50 (2-3) ◽  
pp. 725-730 ◽  
Author(s):  
Qianpu Wang ◽  
Datong Song ◽  
Titichai Navessin ◽  
Steven Holdcroft ◽  
Zhongsheng Liu

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