Nickel-palladium nanoparticle catalyzed hydrogen generation from hydrous hydrazine for chemical hydrogen storage

2011 ◽  
Vol 36 (18) ◽  
pp. 11794-11801 ◽  
Author(s):  
Sanjay Kumar Singh ◽  
Yasuo Iizuka ◽  
Qiang Xu
Author(s):  
Yu-Ping Qiu ◽  
Weizhen Wang ◽  
Mu-Hua Chen ◽  
Qing Shi ◽  
Zhiqing Yang ◽  
...  

On-demand hydrogen generation from catalytic decomposition of hydrazine monohydrate (N2H4·H2O) represents a promising chemical hydrogen storage technology for onboard and portable applications. But the performances of existing catalysts are still...


2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Zhang-Hui Lu ◽  
Qilu Yao ◽  
Zhujun Zhang ◽  
Yuwen Yang ◽  
Xiangshu Chen

Ammonia borane (denoted as AB, NH3BH3) and hydrazine borane (denoted as HB, N2H4BH3), having hydrogen content as high as 19.6 wt% and 15.4 wt%, respectively, have been considered as promising hydrogen storage materials. Particularly, the AB and HB hydrolytic dehydrogenation system can ideally release 7.8 wt% and 12.2 wt% hydrogen of the starting materials, respectively, showing their high potential for chemical hydrogen storage. A variety of nanocatalysts have been prepared for catalytic dehydrogenation from aqueous or methanolic solution of AB and HB. In this review, we survey the research progresses in nanocatalysts for hydrogen generation from the hydrolysis or methanolysis of NH3BH3and N2H4BH3.


2015 ◽  
Vol 8 (2) ◽  
pp. 478-512 ◽  
Author(s):  
Qi-Long Zhu ◽  
Qiang Xu

In this review, we survey the research progress in catalytic hydrogen generation from, and the regeneration of, diverse liquid-phase chemical hydrogen storage materials, including both organic and inorganic chemical hydrides.


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