Compatible ionic crosslinking composite membranes based on SPEEK and PBI for high temperature proton exchange membranes

2016 ◽  
Vol 41 (28) ◽  
pp. 12069-12081 ◽  
Author(s):  
Mingfeng Song ◽  
Xuewei Lu ◽  
Zhongfang Li ◽  
Guohong Liu ◽  
Xiaoyan Yin ◽  
...  
2006 ◽  
Vol 48 (3) ◽  
pp. 144-151 ◽  
Author(s):  
A. Yu. Leikin ◽  
E. G. Bulycheva ◽  
A. L. Rusanov ◽  
D. Yu. Likhachev

2014 ◽  
Vol 5 (17) ◽  
pp. 4939-4947 ◽  
Author(s):  
Na Zhang ◽  
Chengji Zhao ◽  
Wenjia Ma ◽  
Shuang Wang ◽  
Baolong Wang ◽  
...  

The phosphoric acid doped quaternary ammonium poly(ether ether ketone) membranes cross-linked with PBI showed improved performance.


RSC Advances ◽  
2016 ◽  
Vol 6 (66) ◽  
pp. 61029-61036 ◽  
Author(s):  
Jingshuai Yang ◽  
Chao Liu ◽  
Liping Gao ◽  
Jin Wang ◽  
Yixin Xu ◽  
...  

Phosphoric acid doped novel high temperature proton exchange membranes based on the imidazolium functionalized poly(epichlorohydrin) and porous polyetrafluoroethylene were fabricated and investigated.


Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4205
Author(s):  
Marwa H. Gouda ◽  
Noha A. Elessawy ◽  
Sami A. Al-Hussain ◽  
Arafat Toghan

The direct borohydride fuel cell (DBFC) is a low-temperature fuel cell that requires the development of affordable price and efficient proton exchange membranes for commercial purposes. In this context, super-acidic sulfated zirconia (SO4ZrO2) was embedded into a cheap and environmentally friendly binary polymer blend, developed from poly(vinyl alcohol) (PVA) and iota carrageenan (IC). The percentage of SO4ZrO2 ranged between 1 and 7.5 wt.% in the polymeric matrix. The study findings revealed that the composite membranes’ physicochemical features improved by adding increasing amounts of SO4ZrO2. In addition, there was a decrease in the permeability and swelling ratio of the borohydride membranes as the SO4ZrO2 weight% increased. Interestingly, the power density increased to 76 mW cm−2 at 150 mA cm−2, with 7.5 wt.% SO4ZrO2, which is very close to that of Nafion117 (91 mW cm−2). This apparent selectivity, combined with the low cost of the eco-friendly fabricated membranes, points out that DBFC has promising future applications.


2019 ◽  
Vol 487 ◽  
pp. 889-897 ◽  
Author(s):  
Fátima C. Teixeira ◽  
Ana I. de Sá ◽  
António P.S. Teixeira ◽  
C.M. Rangel

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