Thermogravimetric analysis and the optimisation of bio-oil yield from fixed-bed pyrolysis of rice husk using response surface methodology (RSM)

2011 ◽  
Vol 33 (2) ◽  
pp. 481-487 ◽  
Author(s):  
Khairuddin Md Isa ◽  
Suhardy Daud ◽  
Nasrul Hamidin ◽  
Khudzir Ismail ◽  
Saiful Azhar Saad ◽  
...  
REAKTOR ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 1-9
Author(s):  
Tutuk Djoko Kusworo ◽  
Bayu Aji Pratama ◽  
Dhea Putri Safira

The need for fuel oil continues to increase in line with the increasing number of human populations and the growth rate of dependence on fuel oil. Bio-oil is a condensed-liquid mixture that results from the thermal derivation of biomass containing hemicellulose, lignin, and cellulose. This research developed an optimization of the operation condition of bio-oil from empty palm fruit bunches (OPEFB) using a modified pyrolysis reactor. The temperature and mass of empty palm fruit bunches were the two parameters considered in this study. Optimization was carried out on process parameters using the surface response methodology (RSM) and variance analysis (ANOVA). The significance of the different parameters and the effect of the relationship between parameters on the bio-oil yield is determined using a full factorial central composite design. The optimal operation condition of pyrolysis was found to be 570.71 oC, and the mass of empty palm fruit bunch 420.71 gr. Predictions from the optimum variable of operating conditions produce a bio-oil yield of 5.58%. The actual bio-oil yield on the optimum condition that was be validated is 5.6 %. The chemical composition of bio-oil obtained was evaluated by GCMS to ensure its characterization as a fuel.Keywords: Empty palm fruit bunches, Bio-oil, Pyrolysis, Response Surface Methodology, Optimization


2018 ◽  
Vol 3 (5) ◽  
pp. 266-278 ◽  
Author(s):  
Rey P. Gumaling ◽  
Jay R E. Agusan ◽  
Neil Ven Cent R. Ellacer ◽  
Gretel Mary T. Abi Abi ◽  
Jasmin Roxatte P. Pajaron ◽  
...  

2019 ◽  
Vol 37 (9) ◽  
pp. 925-933 ◽  
Author(s):  
Derya Yeşim Hopa ◽  
Oğuzhan Alagöz ◽  
Nazan Yılmaz ◽  
Meltem Dilek ◽  
Gamze Arabacı ◽  
...  

In the present study, pyrolysis and co-pyrolysis of sugarcane bagasse, poppy capsule pulp, and rice husk were conducted in a fixed bed reactor at 550⁰C in nitrogen atmosphere. The moisture (5%–8%), ash (4%–17%), volatile matter (60%–76%), and fixed carbon analyses (11%–24%) of the utilized biomass were conducted. The decomposition behavior of biomasses due to the heat effect was investigated by thermogravimetric analysis/differential thermal analysis . In the pyrolysis of biomasses separately, the highest bio-oil yield was obtained with sugarcane bagasse (27.4%). In the co-pyrolysis of the binary blends of biomass, the highest bio-oil yield was obtained with the rice husk and sugarcane bagasse blends. While the mean bio-oil yield obtained with the separate pyrolysis of these two biomasses was 23.9%, it was observed that the bio-oil yield obtained with the co-pyrolysis of biomass blends was 28.4%. This suggested a synergistic interaction between the two biomasses during pyrolysis. It was observed that as the total ash content in the biomasses used in the pyrolysis increased, the bio-oil yield decreased, and the solid product content increased. Characterization studies of bio-oils were conducted by Fourier-transform infrared spectroscopy, gas chromatography–mass spectrometry (GC-MS), and hydrogen-1 nuclear magnetic resonance analyses. Results of these studies revealed that, all bio-oils were mainly composed of aliphatic and oxygenated compounds. The calorific values of bio-oils were determined by calorimeter bomb. Based on the GC-MS, the bio-oils with high fatty acid and its ester content also had high calorific values. The highest calorific value was 29.68 MJ kg-1, and this was obtained by pyrolysis of poppy capsule and sugarcane bagasse blend.


2020 ◽  
Vol 849 ◽  
pp. 47-52
Author(s):  
Siti Jamilatun ◽  
Aster Rahayu ◽  
Yano Surya Pradana ◽  
Budhijanto ◽  
Rochmadi ◽  
...  

Nowadays, energy consumption has increased as a population increases with socio-economic developments and improved living standards. Therefore, it is necessary to find a replacement for fossil energy with renewable energy sources, and the potential to develop is biofuels. Bio-oil, water phase, gas, and char products will be produced by utilizing Spirulina platensis (SPR) microalgae extraction residue as pyrolysis raw material. The purpose of this study is to characterize pyrolysis products and bio-oil analysis with GC-MS. Quality fuel is good if O/C is low, H/C is high, HHV is high, and oxygenate compounds are low, but aliphatic and aromatic are high. Pyrolysis was carried out at a temperature of 300-600°C with a feed of 50 grams in atmospheric conditions with a heating rate of 5-35°C/min, the equipment used was a fixed-bed reactor. The higher the pyrolysis temperature, the higher the bio-oil yield will be to an optimum temperature, then lower. The optimum temperature of pyrolysis is 550°C with a bio-oil yield of 23.99 wt%. The higher the pyrolysis temperature, the higher the H/C, the lower O/C. The optimum condition was reached at a temperature of 500°C with the values of H/C, and O/C is 1.17 and 0.47. With an increase in temperature of 300-600°C, HHV increased from 11.64 MJ/kg to 20.63 MJ/kg, the oxygenate compound decreased from 85.26 to 37.55 wt%. Aliphatics and aromatics increased, respectively, from 5.76 to 36.72 wt% and 1.67 to 6.67 wt%.


2018 ◽  
Vol 11 (23) ◽  
pp. 1121-1133
Author(s):  
Candelaria Tejada-Tovar ◽  
Angel Villabona ◽  
Angelica Cabarcas ◽  
Cristian Benitez ◽  
Diofanor Acevedo

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