Influence of rare-earth doping on the structural and dielectric properties of orthoferrite La0.50R0.50FeO3 ceramics synthesized under high pressure

2020 ◽  
Vol 842 ◽  
pp. 155859 ◽  
Author(s):  
I.I. Makoed ◽  
N.A. Liedienov ◽  
A.V. Pashchenko ◽  
G.G. Levchenko ◽  
D.D. Tatarchuk ◽  
...  
Keyword(s):  
High Pressure ◽  
Rare Earth ◽  
Dielectric Properties ◽  
Rare Earth Doping

Effects of Rare-Earth Doping on Dielectric Properties of CaCu3Ti4O12Ceramics

2013 ◽  
Vol 452 (1) ◽  
pp. 35-42
Author(s):  
J. Li ◽  
H. Lu ◽  
C. Lu ◽  
C. Huang ◽  
B. Fu ◽  
...  
Keyword(s):  
Rare Earth ◽  
Dielectric Properties ◽  
Rare Earth Doping

scholarly journals High Pressure X-ray Diffraction as a Tool for Designing Doped Ceria Thin Films Electrolytes

Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 724
Author(s):  
Sara Massardo ◽  
Alessandro Cingolani ◽  
Cristina Artini
Keyword(s):  
Thin Films ◽  
High Pressure ◽  
Rare Earth ◽  
Ionic Conductivity ◽  
Bulk Material ◽  
Threshold Temperature ◽  
Doped Ceria ◽  
X Ray Diffraction ◽  
X Ray ◽  
Rare Earth Doped

Rare earth-doped ceria thin films are currently thoroughly studied to be used in miniaturized solid oxide cells, memristive devices and gas sensors. The employment in such different application fields derives from the most remarkable property of this material, namely ionic conductivity, occurring through the mobility of oxygen ions above a certain threshold temperature. This feature is in turn limited by the association of defects, which hinders the movement of ions through the lattice. In addition to these issues, ionic conductivity in thin films is dominated by the presence of the film/substrate interface, where a strain can arise as a consequence of lattice mismatch. A tensile strain, in particular, when not released through the occurrence of dislocations, enhances ionic conduction through the reduction of activation energy. Within this complex framework, high pressure X-ray diffraction investigations performed on the bulk material are of great help in estimating the bulk modulus of the material, and hence its compressibility, namely its tolerance toward the application of a compressive/tensile stress. In this review, an overview is given about the correlation between structure and transport properties in rare earth-doped ceria films, and the role of high pressure X-ray diffraction studies in the selection of the most proper compositions for the design of thin films.

scholarly journals High-pressure synthesis of REB5O8(OH)2 (RE = Ho, Er, Tm)

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Michael Zoller ◽  
Hubert Huppertz
Keyword(s):  
High Pressure ◽  
Rare Earth ◽  
Ir Spectroscopy ◽  
Earth Metal ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
X Ray ◽  
Structure Solution ◽  
Pressure Synthesis ◽  
The Rare Earth

AbstractThe rare earth oxoborates REB5O8(OH)2 (RE = Ho, Er, Tm) were synthesized in a Walker-type multianvil apparatus at a pressure of 2.5 GPa and a temperature of 673 K. Single-crystal X-ray diffraction data provided the basis for the structure solution and refinement. The compounds crystallize in the monoclinic space group C2 (no. 5) and are composed of a layer-like structure containing dreier and sechser rings of corner sharing [BO4]5− tetrahedra. The rare earth metal cations are coordinated between two adjacent sechser rings. Further characterization was performed utilizing IR spectroscopy.

High Pressure effects on electrical resistivity and dielectric properties of nanocrystalline SnO2

2005 ◽  
Vol 66 (10) ◽  
pp. 1621-1627 ◽  
Author(s):  
P. Thangadurai ◽  
A. Chandra Bose ◽  
S. Ramasamy ◽  
R. Kesavamoorthy ◽  
T.R. Ravindran
Keyword(s):  
High Pressure ◽  
Electrical Resistivity ◽  
Dielectric Properties ◽  
Pressure Effects ◽  
High Pressure Effects

High-Pressure Study of the Anomalous Rare-Earth TernariesEu1.2Mo6S8andEu1.2Mo6Se8

1981 ◽  
Vol 46 (4) ◽  
pp. 276-279 ◽  
Author(s):  
C. W. Chu ◽  
S. Z. Huang ◽  
C. H. Lin ◽  
R. L. Meng ◽  
M. K. Wu ◽  
...  
Keyword(s):  
High Pressure ◽  
Rare Earth ◽  
High Pressure Study

High-pressure Syntheses and Characterization of the Rare-earth Fluoride Borates RE2(BO3)F3 (RE=Tb, Dy, Ho)

2013 ◽  
Vol 68 (11) ◽  
pp. 1198-1206 ◽  
Author(s):  
Ernst Hinteregger ◽  
Michael Enders ◽  
Almut Pitscheider ◽  
Klaus Wurst ◽  
Gunter Heymann ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Rare Earth ◽  
Monoclinic Space Group ◽  
Rare Earth Fluoride ◽  
Earth Fluoride ◽  
Structure Determinations ◽  
New Compounds ◽  
Rare Earth Fluorides

The new rare-earth fluoride borates RE2(BO3)F3 (RE=Tb, Dy, Ho) were synthesized under highpressure/ high-temperature conditions of 1:5 GPa=1200 °C for Tb2(BO3)F3 and 3:0 GPa=900 °C for Dy2(BO3)F3 and Ho2(BO3)F3 in a Walker-type multianvil apparatus from the corresponding rareearth sesquioxides, rare-earth fluorides, and boron oxide. The single-crystal structure determinations revealed that the new compounds are isotypic to the known rare-earth fluoride borate Gd2(BO3)F3. The new rare-earth fluoride borates crystallize in the monoclinic space group P21/c (Z = 8) with the lattice parameters a=16:296(3), b=6:197(2), c=8:338(2) Å , b =93:58(3)° for Tb2(BO3)F3, a= 16:225(3), b = 6:160(2), c = 8:307(2) Å , b = 93:64(3)° for Dy2(BO3)F3, and a = 16:189(3), b = 6:124(2), c = 8:282(2) Å , β= 93:69(3)° for Ho2(BO3)F3. The four crystallographically different rare-earth cations (CN=9) are surrounded by oxygen and fluoride anions. All boron atoms form isolated trigonal-planar [BO3]3- groups. The six crystallographically different fluoride anions are in a nearly planar coordination by three rare-earth cations.

Sign in / Sign up

Export Citation Format

Share Document