Thermodynamic properties of the Lu2O3–ZrO2 solid solutions by Knudsen effusion mass spectrometry at high temperature

2014 ◽  
Vol 72 ◽  
pp. 85-88 ◽  
Author(s):  
Sergey I. Lopatin ◽  
Sergey M. Shugurov
2017 ◽  
Vol 31 (23) ◽  
pp. 2021-2029 ◽  
Author(s):  
S.M. Shugurov ◽  
O.Yu. Kurapova ◽  
S.I. Lopatin ◽  
V.G. Konakov ◽  
E.A. Vasil'eva

2007 ◽  
Vol 62 (5-6) ◽  
pp. 270-274 ◽  
Author(s):  
Iwona Rutkowska ◽  
Jan Kapała

The Gibbs energies of formation of the pseudobinary compounds Rb3GdCl6(s) and RbGd2Cl7(s) from the constituent metal halides, determined by Knudsen effusion mass spectrometry, were compared with the thermodynamic properties of the solid and liquid phases of the RbCl-GdCl3 system, obtained by different methods. The compatibility of the results obtained in this work for pseudobinary compounds with literature data was assessed by an optimization procedure using the CALPHAD method. The liquid phase in the RbCl-GdCl3 system was described by the associate model. The phase diagram, thermodynamic functions of mixing of the system studied, and the Gibbs energies of formation of the pseudobinary compounds: Rb2GdCl5(s), Rb3GdCl6(s), and RbGd2Cl7(s) resulted from this optimization procedure.


2020 ◽  
Vol 34 (8) ◽  
Author(s):  
Ksenia A. Emelyanova ◽  
Sergey M. Shugurov ◽  
Andrej I. Panin ◽  
Sergey I. Lopatin ◽  
Maria A. Panaeva

Calphad ◽  
2019 ◽  
Vol 64 ◽  
pp. 347-353
Author(s):  
V.V. Trinadh ◽  
P. Manikandan ◽  
Ashish Jain ◽  
T.S. Lakshmi Narasimhan ◽  
K. Ananthasivan

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