Kinetics of electrode processes and thermodynamic properties of europium chlorides dissolved in alkali chloride melts

2006 ◽  
Vol 595 (1) ◽  
pp. 11-22 ◽  
Author(s):  
S.A. Kuznetsov ◽  
M. Gaune-Escard
Keyword(s):  
Thermodynamic Properties ◽  
Alkali Chloride ◽  
Electrode Processes ◽  
Chloride Melts ◽  
Kinetics Of

Kinetics of aluminium deposition from aluminium chloride—alkali chloride melts

1982 ◽  
Vol 27 (11) ◽  
pp. 1595-1598 ◽  
Author(s):  
R. Ødegard ◽  
A. Bjørgum ◽  
Å. Sterten ◽  
J. Thonstad ◽  
R. Tunold
Keyword(s):  
Aluminium Chloride ◽  
Alkali Chloride ◽  
Chloride Melts ◽  
Kinetics Of

Kinetics of Reaction of Oxygen with Uranium(IV) Chloride in Alkali Chloride Melts

2020 ◽  
Vol MA2020-02 (59) ◽  
pp. 2942-2942
Author(s):  
Vladimir A. Volkovich ◽  
Alexander B. Ivanov ◽  
Alexander A. Ryzhov ◽  
Dmitry Maltsev ◽  
Trevor R. Griffiths
Keyword(s):  
Alkali Chloride ◽  
Chloride Melts ◽  
Kinetics Of Reaction ◽  
Kinetics Of

scholarly journals Speciation of Rhenium in Chloride Melts: Spectroscopic and Electrochemical Study

2008 ◽  
Vol 63 (5-6) ◽  
pp. 371-376 ◽  
Author(s):  
Danil A. Danilov ◽  
Vladimir A. Volkovich ◽  
Boris D. Vasin ◽  
Denis E. Aleksandrov ◽  
Ilya B. Polovov ◽  
...  
Keyword(s):  
Molten Salts ◽  
Diffuse Reflectance ◽  
Diffuse Reflectance Spectroscopy ◽  
Oxidation States ◽  
Alkali Chloride ◽  
Chloride Melts ◽  
Current Densities ◽  
Alkali Chlorides ◽  
First Time ◽  
Kinetics Of

Speciation of rhenium in high-temperature alkali chloride-based melts was studied using electronic absorption and IR spectroscopy of molten salts and diffuse reflectance spectroscopy of quenched melts. Rhenium was added to the melts by anodic dissolution of the metal (at anodic current densities of 0.005 - 0.05 A/cm2), by reacting Re and ReO2 with Cl2 and HCl, and by dissolving K2[ReCl6]. The melts included 3LiCl-2KCl and NaCl-2CsCl eutectics, an NaCl-KCl equimolar mixture, and pure NaCl, KCl and CsCl between 450 and 850 ◦C. Rhenium was present in the melts as Re(IV) hexachloro-ions, [ReCl6]2−; no evidence of species containing rhenium in oxidation states below four was obtained. The kinetics of [ReCl6]2− disproportionation in molten alkali chlorides were investigated, and the IR spectra of [ReO4]− ions in molten CsCl-CsI and CsI were measured for the first time.

Kinetics of Reaction of Oxygen with Uranium(IV) Chloride in Alkali Chloride Melts

2020 ◽  
Vol 98 (10) ◽  
pp. 365-372
Author(s):  
Vladimir A. Volkovich ◽  
Alexander B. Ivanov ◽  
Alexander A. Ryzhov ◽  
Dmitry S. Maltsev ◽  
Trevor R. Griffiths
Keyword(s):  
Alkali Chloride ◽  
Chloride Melts ◽  
Kinetics Of Reaction ◽  
Kinetics Of
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