Kinetic and Thermodynamic Properties of Samarium Chlorides Dissolved in Alkali Chloride Melts Obtained by Electrochemical Transient Techniques

2020 ◽  
Vol 98 (10) ◽  
pp. 341-354
Author(s):  
Sergey Kuznetsov ◽  
Yuri Stulov ◽  
Marcelle Gaune-Escard
Keyword(s):  
Thermodynamic Properties ◽  
Alkali Chloride ◽  
Transient Techniques ◽  
Chloride Melts

Thermodynamic Properties of Zinc Chloride in Alkali Chloride Melts by Electromotive Force Measurements

1973 ◽  
Vol 51 (18) ◽  
pp. 3114-3122 ◽  
Author(s):  
Ron J. Robertson ◽  
Alfred S. Kucharski
Keyword(s):  
Thermodynamic Properties ◽  
Electromotive Force ◽  
Metal Salt ◽  
Alkali Metal Salt ◽  
Free Energies ◽  
Force Measurements ◽  
Acid Base ◽  
Alkali Chloride ◽  
Chloride Melts ◽  
Electromotive Force Measurements

Electromotive force measurements on the ZnCl2–ACl systems where A = K, Rb, and Cs were made using cells of the type[Formula: see text]in the temperature range 450° to 800 °C. The partial molar free energies, enthalpies, and excess entropies have been determined from the temperature dependence of the emf results. These thermodynamic properties exhibit increasing negative departure from ideality as the basicity of the alkali metal salt increases. The results are interpreted in terms of an acid–base reaction and are discussed in relation to current models.

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