scholarly journals Study of Cr2O3 nanoparticles supported on carbonaceous materials as catalysts for O2 reduction reaction

Author(s):  
Paloma Almodóvar ◽  
Florencio Santos ◽  
Joaquín Gonzalez ◽  
Julio Ramírez-Castellanos ◽  
José María González-Calbet ◽  
...  
Author(s):  
Shrish Nath Upadhyay ◽  
Srimanta Pakhira

The O2 reduction reaction (ORR) is one promising reaction in clean energy conversion systems such as fuel cells, metal-air batteries, electrochemical reactions, etc. Pt shows excellent electrocatalytic activities for ORR,...


2018 ◽  
Vol 6 (34) ◽  
pp. 16699-16709 ◽  
Author(s):  
D. Garcés ◽  
H. Wang ◽  
S. A. Barnett ◽  
A. G. Leyva ◽  
F. R. Napolitano ◽  
...  

The mechanism controlling the electrode polarization resistance response was studied for new LT-SOFC cathodes with La0.5−xPrxBa0.5CoO3−δ (0 ≤ x ≤ 0.5) compositions.


2017 ◽  
Vol 205 ◽  
pp. 637-653 ◽  
Author(s):  
Luigi Osmieri ◽  
Ricardo Escudero-Cid ◽  
Marco Armandi ◽  
Alessandro H.A. Monteverde Videla ◽  
José Luís García Fierro ◽  
...  

2015 ◽  
Vol 51 (60) ◽  
pp. 12052-12055 ◽  
Author(s):  
Jing-Fang Huang ◽  
Wen-Yu Chen

Combination of the “nano-size” effect and Cl− complexation ability causes massive electrodissolution of Pt under acidic conditions to promote the regeneration of Pt–organic composites and to significantly improve the catalytic performance of the O2 reduction reaction.


2020 ◽  
Vol 20 (5) ◽  
pp. 2736-2745 ◽  
Author(s):  
Haohua Kuang ◽  
Yi Cheng ◽  
Cheng Qiang Cui ◽  
San Ping Jiang

Carbon nanotubes (CNTs) are one of the most common catalysts supports for the development of electrocatalysts for O2 reduction reaction (ORR) of electrochemical devices such as polymer electrolyte membrane fuel cells (PEMFCs) and metal-air batteries due to their high electrical conductivity and high stability. In addition to the electrical conductivity and stability, the number of inner tubes or walls also influence the electrocatalytic activity of the supported catalysts. Here we study the electrocatalytic activity of Pt nanoparticles (NPs) supported on CNTs (Pt/CNTs) as a function of number of walls towards ORR in both alkaline and acid solutions. The results indicate that the mechanism of ORR on Pt/CNTs does not change with the number of walls of CNTs support but the number of walls of CNTs supports has a significant effect on the electrocatalytic activity of supported Pt NPs. Pt NPs supported on double-walled CNTs (DWCNTs) exhibit a much better activity for ORR, as compared with that supported on single-walled and multi-walled CNTs (SWCNTs and MWCNTs). The high electrocatalytic activity of DWCNTs-supported Pt NPs is contributed to the fast electron transfer between the outer wall and inner tubes of DWCNTs for ORR through electron tunnelling process under the electrochemical polarization driving force.


2013 ◽  
Vol 52 (17) ◽  
pp. 9897-9907 ◽  
Author(s):  
Sudipta Chatterjee ◽  
Kushal Sengupta ◽  
Subhra Samanta ◽  
Pradip Kumar Das ◽  
Abhishek Dey

2015 ◽  
Vol 51 (49) ◽  
pp. 10010-10013 ◽  
Author(s):  
Sk Amanullah ◽  
Pradip Kumar Das ◽  
Subhra Samanta ◽  
Abhishek Dey

A porphyrin ligand with two β-pyrrolic electron withdrawing ester groups is synthesized and its Co complex is crystallographically characterized.


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