Infilling of highly ion-conducting gel polymer electrolytes into electrodes with high mass loading for high-performance energy storage

2020 ◽  
Vol 87 ◽  
pp. 173-179 ◽  
Author(s):  
Eunseok Song ◽  
Joobee Shin ◽  
Soo-Hyoung Lee ◽  
Sung-Kon Kim
Keyword(s):  
Energy Storage ◽  
Polymer Electrolytes ◽  
High Performance ◽  
High Mass ◽  
Gel Polymer Electrolytes ◽  
Mass Loading ◽  
Ion Conducting

Ultrathin paper-like boron-doped carbon nanosheet electrodes combined with boron-enriched gel polymer electrolytes for high-performance energy storage

2016 ◽  
Vol 4 (40) ◽  
pp. 15589-15596 ◽  
Author(s):  
Chuanlin Cai ◽  
Ping Yuan ◽  
Jiayong Tang ◽  
Yanhui Guo ◽  
Xiaohua Ma
Keyword(s):  
Energy Storage ◽  
Polymer Electrolytes ◽  
High Performance ◽  
Electrochemical Performances ◽  
Gel Polymer Electrolytes ◽  
The Novel ◽  
Boron Doped ◽  
Doped Graphene ◽  
Graphene Paper ◽  
Novel Design

The novel design of B-doped graphene paper electrodes combined with B-enriched gel polymer electrolytes endows symmetric SCs with outstanding electrochemical performances.

scholarly journals Self-shutdown function induced by sandwich-like gel polymer electrolytes for high safety lithium metal batteries

RSC Advances ◽  
2021 ◽  
Vol 11 (23) ◽  
pp. 14036-14046
Author(s):  
Binxuan Xie ◽  
Shimou Chen ◽  
Yong Chen ◽  
Lili Liu
Keyword(s):  
Polymer Electrolytes ◽  
High Performance ◽  
Gel Polymer Electrolytes ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Safety Features

The SGPE can achieve high performance and high safety features simultaneously.

scholarly journals Inorganic Fillers in Composite Gel Polymer Electrolytes for High-Performance Lithium and Non-Lithium Polymer Batteries

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 614
Author(s):  
Vo Pham Hoang Huy ◽  
Seongjoon So ◽  
Jaehyun Hur
Keyword(s):  
Polymer Electrolytes ◽  
High Performance ◽  
Gel Polymer Electrolyte ◽  
Inorganic Filler ◽  
Gel Polymer Electrolytes ◽  
Lithium Polymer Batteries ◽  
Conductivity Enhancement ◽  
Composite Gel ◽  
Inorganic Fillers ◽  
Historical Developments

Among the various types of polymer electrolytes, gel polymer electrolytes have been considered as promising electrolytes for high-performance lithium and non-lithium batteries. The introduction of inorganic fillers into the polymer-salt system of gel polymer electrolytes has emerged as an effective strategy to achieve high ionic conductivity and excellent interfacial contact with the electrode. In this review, the detailed roles of inorganic fillers in composite gel polymer electrolytes are presented based on their physical and electrochemical properties in lithium and non-lithium polymer batteries. First, we summarize the historical developments of gel polymer electrolytes. Then, a list of detailed fillers applied in gel polymer electrolytes is presented. Possible mechanisms of conductivity enhancement by the addition of inorganic fillers are discussed for each inorganic filler. Subsequently, inorganic filler/polymer composite electrolytes studied for use in various battery systems, including Li-, Na-, Mg-, and Zn-ion batteries, are discussed. Finally, the future perspectives and requirements of the current composite gel polymer electrolyte technologies are highlighted.

Direct growth of nickel terephthalate on Ni foam with large mass-loading for high-performance supercapacitors

2017 ◽  
Vol 5 (36) ◽  
pp. 19323-19332 ◽  
Author(s):  
Qiulin Chen ◽  
Shuijin Lei ◽  
Peiqin Deng ◽  
Xiuling Ou ◽  
Lianfu Chen ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Large Mass ◽  
High Mass ◽  
Mass Loading ◽  
Ni Foam ◽  
Direct Growth

Nickel terephthalate is grown on Ni foam with high mass-loading and its electrochemical performance can be greatly enhanced by polyaniline electrodeposition.

scholarly journals Atomic Modulation of 3D Conductive Frameworks Boost Performance of MnO2 for Coaxial Fiber-Shaped Supercapacitors

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Xiaona Wang ◽  
Zhenyu Zhou ◽  
Zhijian Sun ◽  
Jinho Hah ◽  
Yagang Yao ◽  
...  
Keyword(s):  
Energy Density ◽  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
Superior Performance ◽  
High Mass ◽  
Mass Loading ◽  
Energy Storage Devices ◽  
Free Standing ◽  
Cell Potential

Abstract Coaxial fiber-shaped supercapacitors are a promising class of energy storage devices requiring high performance for flexible and miniature electronic devices. Yet, they are still struggling from inferior energy density, which comes from the limited choices in materials and structure used. Here, Zn-doped CuO nanowires were designed as 3D framework for aligned distributing high mass loading of MnO2 nanosheets. Zn could be introduced into the CuO crystal lattice to tune the covalency character and thus improve charge transport. The Zn–CuO@MnO2 as positive electrode obtained superior performance without sacrificing its areal and gravimetric capacitances with the increasing of mass loading of MnO2 due to 3D Zn–CuO framework enabling efficient electron transport. A novel category of free-standing asymmetric coaxial fiber-shaped supercapacitor based on Zn0.11CuO@MnO2 core electrode possesses superior specific capacitance and enhanced cell potential window. This asymmetric coaxial structure provides superior performance including higher capacity and better stability under deformation because of sufficient contact between the electrodes and electrolyte. Based on these advantages, the as-prepared asymmetric coaxial fiber-shaped supercapacitor exhibits a high specific capacitance of 296.6 mF cm−2 and energy density of 133.47 μWh cm−2. In addition, its capacitance retention reaches 76.57% after bending 10,000 times, which demonstrates as-prepared device’s excellent flexibility and long-term cycling stability.

scholarly journals Hierarchical Carbon Microtube@Nanotube Core–Shell Structure for High-Performance Oxygen Electrocatalysis and Zn–Air Battery

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Wenfu Xie ◽  
Jianming Li ◽  
Yuke Song ◽  
Shijin Li ◽  
Jianbo Li ◽  
...  
Keyword(s):  
Energy Density ◽  
Power Density ◽  
High Power ◽  
High Performance ◽  
Rational Design ◽  
Specific Capacity ◽  
High Mass ◽  
Core Shell ◽  
High Power Density ◽  
Mass Loading

AbstractZinc–air batteries (ZABs) hold tremendous promise for clean and efficient energy storage with the merits of high theoretical energy density and environmental friendliness. However, the performance of practical ZABs is still unsatisfactory because of the inevitably decreased activity of electrocatalysts when assembly into a thick electrode with high mass loading. Herein, we report a hierarchical electrocatalyst based on carbon microtube@nanotube core–shell nanostructure (CMT@CNT), which demonstrates superior electrocatalytic activity for oxygen reduction reaction and oxygen evolution reaction with a small potential gap of 0.678 V. Remarkably, when being employed as air–cathode in ZAB, the CMT@CNT presents an excellent performance with a high power density (160.6 mW cm−2), specific capacity (781.7 mAhg Zn −1 ) as well as long cycle stability (117 h, 351 cycles). Moreover, the ZAB performance of CMT@CNT is maintained well even under high mass loading (3 mg cm−2, three times as much as traditional usage), which could afford high power density and energy density for advanced electronic equipment. We believe that this work is promising for the rational design of hierarchical structured electrocatalysts for advanced metal-air batteries.

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