Application of a boron doped diamond (BDD) electrode as an anode for the electrolytic reduction of UO2 in Li2O–LiCl–KCl molten salt

2013 ◽  
Vol 432 (1-3) ◽  
pp. 175-181 ◽  
Author(s):  
Wooshin Park ◽  
Jong-Kook Kim ◽  
Jin-Mok Hur ◽  
Eun-Young Choi ◽  
Hun Suk Im ◽  
...  
Keyword(s):  
Molten Salt ◽  
Electrolytic Reduction ◽  
Boron Doped Diamond ◽  
Bdd Electrode ◽  
Boron Doped

DICLOFENAC REMOVAL FROM AQUEOUS SOLUTIONS BY ELECTROOXIDATION AT BORON-DOPED DIAMOND (BDD) ELECTRODE

2015 ◽  
Vol 14 (6) ◽  
pp. 1339-1345
Author(s):  
Monica Ihos ◽  
Florica Manea ◽  
Maria Jitaru ◽  
Corneliu Bogatu ◽  
Rodica Pode
Keyword(s):  
Aqueous Solutions ◽  
Boron Doped Diamond ◽  
Bdd Electrode ◽  
Boron Doped

scholarly journals Study of the Electrochemical Deposition of Cu/Sn Alloy Nanoparticles on Boron Doped Diamond Films for Electrocatalytic Nitrate Reduction

2013 ◽  
Vol 1511 ◽  
Author(s):  
Jorge T. Matsushima ◽  
Andrea B. Couto ◽  
Neidenei G. Ferreira ◽  
Mauricio R. Baldan
Keyword(s):  
Electrochemical Deposition ◽  
Sem Analysis ◽  
Homogeneous Distribution ◽  
Alloy Nanoparticles ◽  
Electrocatalytic Reduction ◽  
Boron Doped Diamond ◽  
Buffer Solution ◽  
Bdd Electrode ◽  
Boron Doped ◽  
Dissolution Peak

ABSTRACTThis paper presents the study of the electrochemical deposition of Cu/Sn alloy nanoparticles on Boron Doped Diamond (BDD) films in order to improve their electrocatalytic activity and selectivity for application in nitrate electrochemical reduction. Cyclic voltammetry measurements evidenced the formation of Cu/Sn alloy electrodeposited on BDD electrode. The electrodeposited Cu/Sn can be better visualized by analyzing the dissolution process. By studying the dissolution peak separately, the dissolution peak of the Sn was obtained at a more positive potential, when compared with the dissolution peak of Cu. From the scanning electronic microscopy (SEM) analysis, the homogeneous distribution of the Cu/Sn alloys particles on BDD surface with grain size in nanometric scale was verified. From X-ray diffraction analysis, two Cu/Sn alloy phases (Cu41Sn11 and Cu10Sn3) were identified for the electrodeposits obtained at -0.5V and charge of 0.26 C. The electrocatalytic reduction of nitrate in 0.1 M Britton-Robinson (BR) buffer solution with pH 9 was analyzed. The BDD electrode modified with Cu/Sn alloy nanoparticles proved to potentiate the electrocatalytic reduction of nitrate.

Voltammetric determination of antifungal agents in pharmaceuticals and cosmetics using boron-doped diamond electrodes

2014 ◽  
Vol 6 (19) ◽  
pp. 7912-7922 ◽  
Author(s):  
Katarzyna Mielech-Łukasiewicz ◽  
Katarzyna Rogińska
Keyword(s):  
Antifungal Agents ◽  
Voltammetric Determination ◽  
Diamond Electrodes ◽  
Boron Doped Diamond ◽  
Ciclopirox Olamine ◽  
Bdd Electrode ◽  
Boron Doped

This paper presents attractive methods for the determination of ketoconazole and ciclopirox olamine. The recommended procedures are based on oxidation of the said compounds on the BDD electrode. The properties of this electrode and the usage of the SWV technique facilitated the development of sensitive and accuracy procedures intended to determine the selected antifungal agents.

scholarly journals Sensitive Voltammetric Detection of Chloroquine Drug by Applying a Boron-Doped Diamond Electrode

2020 ◽  
Vol 6 (4) ◽  
pp. 75
Author(s):  
Geiser Gabriel Oliveira ◽  
Déborah Christine Azzi ◽  
Tiago Almeida Silva ◽  
Paulo Roberto de Oliveira ◽  
Orlando Fatibello-Filho ◽  
...  
Keyword(s):  
Square Wave Voltammetry ◽  
Limit Of Detection ◽  
Boron Doped Diamond ◽  
Bdd Electrode ◽  
Diamond Electrode ◽  
Boron Doped ◽  
Wave Voltammetry ◽  
Boron Doped Diamond Electrode ◽  
Analytical Curve ◽  
Voltammetric Detection

In this research, a boron-doped diamond (BDD) electrode has been explored to detect the chloroquine drug. The electrochemical performance of BDD electrode towards the irreversible anodic response of chloroquine was investigated by subjecting this electrode to the cathodic (−0.5 A cm−2 by 180 s, generating a predominantly hydrogen-terminated surface) and anodic (+0.5 A cm−2 by 30 s, oxygen-terminated surface) pretreatments. The cathodically pretreated BDD electrode ensured a better-defined anodic peak and higher current intensity. Thus, by applying the cathodically pretreated BDD electrode and square-wave voltammetry (SWV), the analytical curve was linear from 0.01 to 0.25 µmol L−1 (correlation coefficient of 0.994), with sensitivity and limit of detection of 12.2 µA L µmol−1 and 2.0 nmol−1, respectively. This nanomolar limit of detection is the lowest recorded so far with modified and unmodified electrodes.

scholarly journals Anodic Stripping Voltammetry of Se4+on Gold-Modified Boron-Doped Diamond Electrodes

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Stéphane Fierro ◽  
Takeshi Watanabe ◽  
Kazumi Akai ◽  
Mikito Yamanuki ◽  
Yasuaki Einaga
Keyword(s):  
Gold Nanoparticles ◽  
Anodic Stripping Voltammetry ◽  
Selenium Concentration ◽  
Stripping Voltammetry ◽  
Boron Doped Diamond ◽  
Bdd Electrode ◽  
Boron Doped ◽  
Calibration Curves ◽  
Anodic Stripping ◽  
Clear Peak

Electrochemical detection of Se4+has been performed by anodic stripping voltammetry on a boron-doped diamond (BDD) electrode modified with gold nanoparticles deposited through chronocoulometry. This method is based on the affinity between the gold nanoparticles and Se0, while the BDD electrode is presented as an ideal material for metal modification due to its unique properties. The resulting anodic stripping voltammograms exhibited a clear peak at 0.9 V versus AgCl related to Se4+, and highly accurate (r2=0.99) calibration curves could be obtained for a selenium concentration range between 10 and 100 μg/L. The influence of Se deposition time and other metals dissolved in solution (Cu, Cd, Pb, Cr, and B) has been investigated as well, and it was found that the Se4+calibration curves remained unaltered. For all the experiments performed, a detection limit around 10 μg/L was achieved. The high accuracy and reproducibility of the results as well as the excellent stability of the electrode material proves the excellent capabilities of this system for selenium detection.

Mineralization of bisphenol A (BPA) by anodic oxidation with boron-doped diamond (BDD) electrode

2008 ◽  
Vol 154 (1-3) ◽  
pp. 213-220 ◽  
Author(s):  
M. Murugananthan ◽  
S. Yoshihara ◽  
T. Rakuma ◽  
T. Shirakashi
Keyword(s):  
Bisphenol A ◽  
Anodic Oxidation ◽  
Boron Doped Diamond ◽  
Bdd Electrode ◽  
Boron Doped

Application of TiO2 Modified Boron Doped Diamond (BDD) Electrode for As(III) Determination in Natural Waters

2019 ◽  
Vol 19 (32) ◽  
pp. 87-93 ◽  
Author(s):  
Roumen Zlatev ◽  
Margarita Stoytcheva ◽  
Jean-Pierre Magnin ◽  
Benjamin Valdez ◽  
Mafalda Argüelles ◽  
...  
Keyword(s):  
Natural Waters ◽  
Boron Doped Diamond ◽  
Bdd Electrode ◽  
Boron Doped

scholarly journals Highly sensitive detection of influenza virus by boron-doped diamond electrode terminated with sialic acid-mimic peptide

2016 ◽  
Vol 113 (32) ◽  
pp. 8981-8984 ◽  
Author(s):  
Teruhiko Matsubara ◽  
Michiko Ujie ◽  
Takashi Yamamoto ◽  
Miku Akahori ◽  
Yasuaki Einaga ◽  
...  
Keyword(s):  
Influenza Virus ◽  
Sialic Acid ◽  
Early Phase ◽  
Influenza A ◽  
Electrochemical Impedance ◽  
Electrochemical Characteristics ◽  
Boron Doped Diamond ◽  
Bdd Electrode ◽  
Boron Doped ◽  
Mimic Peptide

The progression of influenza varies according to age and the presence of an underlying disease; appropriate treatment is therefore required to prevent severe disease. Anti-influenza therapy, such as with neuraminidase inhibitors, is effective, but diagnosis at an early phase of infection before viral propagation is critical. Here, we show that several dozen plaque-forming units (pfu) of influenza virus (IFV) can be detected using a boron-doped diamond (BDD) electrode terminated with a sialic acid-mimic peptide. The peptide was used instead of the sialyloligosaccharide receptor, which is the common receptor of influenza A and B viruses required during the early phase of infection, to capture IFV particles. The peptide, which was previously identified by phage-display technology, was immobilized by click chemistry on the BDD electrode, which has excellent electrochemical characteristics such as low background current and weak adsorption of biomolecules. Electrochemical impedance spectroscopy revealed that H1N1 and H3N2 IFVs were detectable in the range of 20–500 pfu by using the peptide-terminated BDD electrode. Our results demonstrate that the BDD device integrated with the receptor-mimic peptide has high sensitivity for detection of a low number of virus particles in the early phase of infection.

Sign in / Sign up

Export Citation Format

Share Document