Insertion reaction of carbon monoxide into metal-carbon bonds. Synthesis and structural characterization of cobalt(II) and nickel(II) acyl complexes with tri(tertiary arsines and phosphines)

1978 ◽  
Vol 17 (3) ◽  
pp. 718-725 ◽  
Author(s):  
P. Stoppioni ◽  
P. Dapporto ◽  
L. Sacconi
Keyword(s):  
Carbon Monoxide ◽  
Structural Characterization ◽  
Insertion Reaction ◽  
Acyl Complexes ◽  
Carbon Bonds ◽  
Tertiary Arsines

Spectroscopic, Redox, and Structural Characterization of the Ni-Labile and Nonlabile Forms of the Acetyl-CoA Synthase Active Site of Carbon Monoxide Dehydrogenase

1998 ◽  
Vol 120 (30) ◽  
pp. 7502-7510 ◽  
Author(s):  
William K. Russell ◽  
Christina M. V. Stålhandske ◽  
Jinqiang Xia ◽  
Robert A. Scott ◽  
Paul A. Lindahl
Keyword(s):  
Carbon Monoxide ◽  
Structural Characterization ◽  
Active Site ◽  
Carbon Monoxide Dehydrogenase ◽  
Acetyl Coa

Synthesis, structural characterization, and reactivity of Cp*Ru(N-phosphinoamidinate) complexes

2014 ◽  
Vol 92 (3) ◽  
pp. 194-200 ◽  
Author(s):  
Colin M. Kelly ◽  
Adam J. Ruddy ◽  
Craig A. Wheaton ◽  
Orson L. Sydora ◽  
Brooke L. Small ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Structural Characterization ◽  
Ammonia Borane ◽  
The Stability

We report herein on the synthesis and spectroscopic/crystallographic characterization of the first isolable, formally 16-electron Cp*Ru(κ2-P∼N) species, which are supported by N-phosphinoamidinate ligands. Despite the stability of such complexes, they have been shown to readily coordinate two-electron (L) donors including carbon monoxide and 2,6-xylylisocyanide, affording crystallographically characterized 18-electron Cp*Ru(L)(κ2-P∼N) adducts. Preliminary reactivity studies confirm that such complexes are capable of extruding hydrogen from ammonia borane.

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