Optoelectronic, luminescence, and nonlinear properties of a non-centrosymmetric Cd(II)-based complex

Author(s):  
Rawia Msalmi ◽  
Khouloud Dammak ◽  
Slim Elleuch ◽  
Besma Hamdi ◽  
Anowar Tozri ◽  
...  
Keyword(s):  
2020 ◽  
Author(s):  
Zeyu Liu ◽  
Shugui Hua ◽  
Tian Lu ◽  
Ziqi Tian

Inspired by a previous experimental study on the first-order hyperpolarizabilities of 1,3-thiazolium-5-thiolates mesoionic compounds using Hyper-Rayleigh scattering technique, we theoretically investigated the UV-Vis absorption spectra and every order polarizabilities of these mesoionic molecules. Based on the fact that the photophysical and nonlinear properties observed in the experiment can be perfectly replicated, our theoretical calculations explored the essential characteristics of the optical properties of the mesoionic compounds with different electron-donating groups at the level of electronic structures through various wave function analysis methods. The influence of the electron-donating ability of the donor on the optical properties of the molecules and the contribution of the mesoionic ring moiety to their optical nonlinearity are clarified, which have not been reported by any research so far. This work will help people understand the nature of optical properties of mesoionic-based molecules and provide guidance for the rational design of molecules with excellent photoelectric performance in the future.


2020 ◽  
Vol 7 (1) ◽  
pp. 48-55 ◽  
Author(s):  
Bolat Duissenbekov ◽  
Abduhalyk Tokmuratov ◽  
Nurlan Zhangabay ◽  
Zhenis Orazbayev ◽  
Baisbay Yerimbetov ◽  
...  

AbstractThe study solves a system of finite difference equations for flexible shallow concrete shells while taking into account the nonlinear deformations. All stiffness properties of the shell are taken as variables, i.e., stiffness surface and through-thickness stiffness. Differential equations under consideration were evaluated in the form of algebraic equations with the finite element method. For a reinforced shell, a system of 98 equations on a 8×8 grid was established, which was next solved with the approximation method from the nonlinear plasticity theory. A test case involved computing a 1×1 shallow shell taking into account the nonlinear properties of concrete. With nonlinear equations for the concrete creep taken as constitutive, equations for the quasi-static shell motion under constant load were derived. The resultant equations were written in a differential form and the problem of solving these differential equations was then reduced to the solving of the Cauchy problem. The numerical solution to this problem allows describing the stress-strain state of the shell at each point of the shell grid within a specified time interval.


2021 ◽  
Vol 328 ◽  
pp. 115391
Author(s):  
Vinícius Castro Ferreira ◽  
Letícia Zanchet ◽  
Wesley Formentin Monteiro ◽  
Letícia Guerreiro da Trindade ◽  
Michèle Oberson de Souza ◽  
...  

Photonics ◽  
2021 ◽  
Vol 8 (4) ◽  
pp. 121
Author(s):  
Ekaterina Ponkratova ◽  
Eduard Ageev ◽  
Filipp Komissarenko ◽  
Sergei Koromyslov ◽  
Dmitry Kudryashov ◽  
...  

Fabrication of hybrid micro- and nanostructures with a strong nonlinear response is challenging and represents a great interest due to a wide range of photonic applications. Usually, such structures are produced by quite complicated and time-consuming techniques. This work demonstrates laser-induced hybrid metal-dielectric structures with strong nonlinear properties obtained by a single-step fabrication process. We determine the influence of several incident femtosecond pulses on the Au/Si bi-layer film on produced structure morphology. The created hybrid systems represent isolated nanoparticles with a height of 250–500 nm exceeding the total thickness of the Au-Si bi-layer. It is shown that fabricated hybrid nanostructures demonstrate enhancement of the SHG signal (up to two orders of magnitude) compared to the initial planar sample and a broadband photoluminescence signal (more than 200 nm in width) in the visible spectral region. We establish the correlation between nonlinear signal and phase composition provided by Raman scattering measurements. Such laser-induced structures have significant potential in optical sensing applications and can be used as components for different nanophotonic devices.


2012 ◽  
Vol 397 ◽  
pp. 012044 ◽  
Author(s):  
Waldemar Głaz ◽  
Tadeusz Bancewicz ◽  
George Maroulis ◽  
Anastasios Haskopoulos ◽  
Jean-Luc Godet

2014 ◽  
Vol 69 ◽  
pp. 156-174 ◽  
Author(s):  
F. Wang ◽  
O. Sigmund ◽  
J.S. Jensen
Keyword(s):  

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