Enhancement of proton conductivity of chitosan membrane enabled by sulfonated graphene oxide under both hydrated and anhydrous conditions

2014 ◽  
Vol 269 ◽  
pp. 898-911 ◽  
Author(s):  
Yahua Liu ◽  
Jingtao Wang ◽  
Haoqin Zhang ◽  
Chuanming Ma ◽  
Jindun Liu ◽  
...  
2016 ◽  
Vol 52 (10) ◽  
pp. 2173-2176 ◽  
Author(s):  
Guangwei He ◽  
Xueyi He ◽  
Xinglin Wang ◽  
Chaoyi Chang ◽  
Jing Zhao ◽  
...  

Coating an ultrathin graphene oxide film onto a Nafion membrane confers a distinct anti-tradeoff behavior: 93% decrease of methanol permeability while retaining the high proton conductivity.


2020 ◽  
Vol 3 (1) ◽  
pp. 1-5
Author(s):  
Herry Purnama ◽  
Indra Viki Hartoko ◽  
Muhammad Mujiburohman ◽  
Nur Hidayati

Direct Methanol Fuel Cell (DMFC) can operate at low temperatures, but efficiency and performance are greatly influenced by the material. On the other hand, sulfonated ketone polyether ethers (sPEEK) which have high thermal resistance, ductile, chemical resistance and high mechanical properties, can be combined with chitosan which has good proton conductivity properties. The sPEEK-Chitosan membrane is known to have good mechanical and thermal resistance, but its conductivity is low. The addition of graphene oxide as a filler material can increase the proton conductivity due to its properties. This research was conducted with a completely randomized design of 1 factor to investigate the characteristics of the sPEEK-Chitosan composite membrane as the dependent variable and the addition of graphene oxide solution to the variables 0, 1, 3, 6, and 9% w/w as independent variables. The test results show that the water uptake is in the range of 8.82-33.34%, the swelling degree is in the range of 5.55-20.75%, and the ion exchange capacity is 0.1875-0.2714 meq/g. With this good character, the sPEEK-chitosan membrane with the addition of graphene oxide is a promising candidate for DMFC applications.


Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1375 ◽  
Author(s):  
Dong Chan Seo ◽  
Ikseong Jeon ◽  
Eun Suk Jeong ◽  
Jae Young Jho

To improve both the mechanical and chemical durability of Nafion membranes for polymer electrolyte membrane fuel-cells (PEMFCs), Nafion composite membranes containing sulfonated graphene oxide (SGO) and cerium oxide (CeO2; ceria) were prepared by solution casting. The structure and chemical composition of SGO were investigated by FT-IR and XPS. The effect of the sulfonation, addition of SGO and ceria on the mechanical properties, proton conductivity, and chemical stability were evaluated. The addition of SGO gave rise to an increase in the number of sulfonic acid groups in Nafion, resulting in a higher tensile strength and proton conductivity compared to that of graphene oxide (GO). Although the addition of ceria was found to decrease the tensile strength and proton conductivity, Nafion/SGO/ceria composite membranes exhibited a higher tensile strength and proton conductivity than recast Nafion. Measurement of the weight loss and SEM observations of the composite membranes after immersing in Fenton’s reagent indicate an excellent radical scavenging ability of ceria under radical degradation conditions.


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