A combined theoretical-experimental study of interactions between vanadium ions and Nafion membrane in all-vanadium redox flow batteries

2018 ◽  
Vol 373 ◽  
pp. 150-160 ◽  
Author(s):  
Nadia N. Intan ◽  
Konstantin Klyukin ◽  
Tawanda J. Zimudzi ◽  
Michael A. Hickner ◽  
Vitaly Alexandrov
2005 ◽  
Vol 109 (43) ◽  
pp. 20310-20314 ◽  
Author(s):  
Xuanli Luo ◽  
Zhengzhong Lu ◽  
Jingyu Xi ◽  
Zenghua Wu ◽  
Wentao Zhu ◽  
...  

2017 ◽  
Vol 7 (3) ◽  
pp. 139 ◽  
Author(s):  
Hao Peng ◽  
Zuohua Liu ◽  
Changyuan Tao

<p><span lang="EN-GB">Periodic electrochemical oscillation of the anolyte was reported for the first time in a simulated charging process of the vanadium redox flow batteries. The electrochemical oscillation could be explained in terms of the competition between the growth and the chemical dissolution of V<sub>2</sub>O<sub>5</sub> film. Also, the oscillation phenomenon was possible to regular extra power consumption. The results of this paper might enable new methods to improve the charge efficiency and energy saving for vanadium redox flow batteries.</span></p>


RSC Advances ◽  
2016 ◽  
Vol 6 (5) ◽  
pp. 3756-3763 ◽  
Author(s):  
Lihong Yu ◽  
Feng Lin ◽  
Ling Xu ◽  
Jingyu Xi

GO nanosheets in Nafion effectively block the crossover of vanadium ions while hydrogen bonds between GO and Nafion increase the mechanical stability, significantly improving the efficiency and cyclability in a rNafion/GO membrane based VRFB.


2019 ◽  
Vol 43 (28) ◽  
pp. 11374-11381 ◽  
Author(s):  
Xiao-Bing Yang ◽  
Lei Zhao ◽  
Kokswee Goh ◽  
Xu-Lei Sui ◽  
Ling-Hui Meng ◽  
...  

The polar clusters of Nafion are blocked by the incorporation of the nanohybrid, which contributes to suppress vanadium ions crossover.


RSC Advances ◽  
2015 ◽  
Vol 5 (89) ◽  
pp. 72805-72815 ◽  
Author(s):  
The Nam Long Doan ◽  
Tuan K. A. Hoang ◽  
P. Chen

A key component for all-vanadium redox flow batteries is the membrane separator, which separates the positive and negative half-cells and prevents the cross-mixing of vanadium ions, while providing required ionic conductivity.


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