CO2 electrolysis – Gas impurities and electrode overpotential causing detrimental carbon deposition

2021 ◽  
Vol 506 ◽  
pp. 230108
Author(s):  
A. Hauch ◽  
M.L. Traulsen ◽  
R. Küngas ◽  
T.L. Skafte
2018 ◽  
Vol 373 ◽  
pp. 54-60 ◽  
Author(s):  
Theis Løye Skafte ◽  
Peter Blennow ◽  
Johan Hjelm ◽  
Christopher Graves

2014 ◽  
Vol 16 (26) ◽  
pp. 13063-13068 ◽  
Author(s):  
V. Duboviks ◽  
R. C. Maher ◽  
M. Kishimoto ◽  
L. F. Cohen ◽  
N. P. Brandon ◽  
...  

In situ and ex situ Raman analyses of porous Ni/CGO electrodes reveal differences in the amount, location and type of carbon formed during CO/CO2 electrolysis. The majority of the carbon forms in the region of the anode, which lies in the range of ca. 4 micrometers from the electrode–electrolyte interface.


2019 ◽  
Vol 7 (25) ◽  
pp. 15233-15243 ◽  
Author(s):  
Jiayue Wang ◽  
Sean R. Bishop ◽  
Lixin Sun ◽  
Qiyang Lu ◽  
Gulin Vardar ◽  
...  

Suppressing Ce3+–Ce3+ pair formation avoids carbon deposition on CeO2-based electrode during CO2 electrolysis, found by in operando X-ray photoelectron spectroscopy.


2015 ◽  
Vol 68 (1) ◽  
pp. 3429-3437 ◽  
Author(s):  
T. L. Skafte ◽  
C. Graves ◽  
P. Blennow ◽  
J. Hjelm

Author(s):  
Gyeung Ho Kim ◽  
Mehmet Sarikaya ◽  
D. L. Milius ◽  
I. A. Aksay

Cermets are designed to optimize the mechanical properties of ceramics (hard and strong component) and metals (ductile and tough component) into one system. However, the processing of such systems is a problem in obtaining fully dense composite without deleterious reaction products. In the lightweight (2.65 g/cc) B4C-Al cermet, many of the processing problems have been circumvented. It is now possible to process fully dense B4C-Al cermet with tailored microstructures and achieve unique combination of mechanical properties (fracture strength of over 600 MPa and fracture toughness of 12 MPa-m1/2). In this paper, microstructure and fractography of B4C-Al cermets, tested under dynamic and static loading conditions, are described.The cermet is prepared by infiltration of Al at 1150°C into partially sintered B4C compact under vacuum to full density. Fracture surface replicas were prepared by using cellulose acetate and thin-film carbon deposition. Samples were observed with a Philips 3000 at 100 kV.


Tellus B ◽  
2011 ◽  
Vol 63 (3) ◽  
Author(s):  
Borgar Aamaas ◽  
Carl Egede Bøggild ◽  
Frode Stordal ◽  
Terje Berntsen ◽  
Kim Holmén ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document