A single layered organic-inorganic hybrid compound [(FBMA)2PbBr4] with reversible phase transition and intense fluorescent property

Organic-inorganic hybrid metal halides with dielectric properties have attracted widespread attention due to their applications in the field of optoelectronics. Here, we successfully synthesized a novel dielectric material (C8H18BrN)2SnBr6 (1),...

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Two bilayer organic-inorganic hybrid perovskite compounds exhibiting reversible phase transition and dielectric anomalies

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2019.121104 ◽

2020 ◽

Vol 282 ◽

pp. 121104 ◽

Cited By ~ 1

Author(s):

Jiang ZhenTao ◽

Hao Yanhuan ◽

Wang Hui ◽

Zhang Xiuxiu ◽

Yao Jiaojiao ◽

...

Keyword(s):

Phase Transition ◽

Inorganic Hybrid ◽

Hybrid Perovskite ◽

Reversible Phase Transition ◽

Reversible Phase

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Tin based organic–inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

Dalton Transactions ◽

10.1039/d0dt01401j ◽

2020 ◽

Vol 49 (21) ◽

pp. 7252-7257 ◽

Cited By ~ 2

Author(s):

Xiuli You ◽

Jiaojiao Yao ◽

Zhenhong Wei

Keyword(s):

Phase Transition ◽

Dielectric Anomaly ◽

Organic Amine ◽

Inorganic Hybrid ◽

Hybrid Compounds ◽

Reversible Phase Transition ◽

Hybrid Semiconductors ◽

Reversible Phase

Two discrete tin based organic–inorganic hybrid compounds [(FMBA)2SnX6] (X = Cl and Br) showed reversible phase transition and dielectric anomaly above 400 K which were originated from the order-disorder of a fluorine-substituted organic amine.

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Two In-Based Organic−Inorganic Hybrid Compounds with Reversible Phase Transition Derived from Order-Disorder Changes of Cations or Anions

Dalton Transactions ◽

10.1039/d1dt01935j ◽

2021 ◽

Author(s):

Yin-Qiang Zhang ◽

Guan-Cheng Xu ◽

Min Li

Keyword(s):

Phase Transition ◽

Solid State ◽

Physical Properties ◽

Ferroelectric Properties ◽

Inorganic Hybrid ◽

Hybrid Compounds ◽

Reversible Phase Transition ◽

Reversible Phase

Solid-state phase transition materials have been received extraordinary interest due to their rich physical properties, such as the thermal, dielectric, and ferroelectric properties. Here, two In-based organic-inorganic hybrid compounds, (C6H5CH2CH2NH3)3[InBr5(H2O)]...

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Reversible phase transition driven by order–disorder transformations of metal-halide moieties in [(C6H14)NH2]2·CuBr4

Journal of Materials Chemistry C ◽

10.1039/c6tc02034h ◽

2016 ◽

Vol 4 (32) ◽

pp. 7537-7540 ◽

Cited By ~ 25

Author(s):

Muhammad Adnan Asghar ◽

Shuquan Zhang ◽

Tariq Khan ◽

Zhihua Sun ◽

Aurang Zeb ◽

...

Keyword(s):

Phase Transition ◽

Order Phase Transition ◽

Hybrid Material ◽

Metal Halide ◽

Inorganic Hybrid ◽

First Order ◽

First Order Phase Transition ◽

Reversible Phase Transition ◽

First Order Phase ◽

Reversible Phase

[(C6H14)NH2]2·CuBr4 (1), an organic–inorganic hybrid material, undergoes a reversible first-order phase transition around 194 K, triggered by the order–disorder transformation of metal-coordinated halogen atoms.

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Temperature‐Induced Reversible Phase Transition with Switchable Dielectric Response in a A 2 BX 4 ‐Type Hybrid Compound: [TEAMA] 2 [CdBr 4 ] (TEAMA=(CH 3 CH 2 ) 3 NCH 3 )

European Journal of Inorganic Chemistry ◽

10.1002/ejic.202000961 ◽

2021 ◽

Author(s):

Qin‐Wen Wang ◽

Zhi‐Xin Gong ◽

Le Ye ◽

Jia‐Jun Ma ◽

Qi Xu ◽

...

Keyword(s):

Phase Transition ◽

Dielectric Response ◽

Hybrid Compound ◽

Reversible Phase Transition ◽

Reversible Phase

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Phase transition and switchable dielectric behaviours in an organic–inorganic hybrid compound: (3-nitroanilinium) 2 (18-crown-6) 2 (H 2 PO 4 ) 2 (H 3 PO 4 ) 3 (H 2 O)

Royal Society Open Science ◽

10.1098/rsos.180738 ◽

2018 ◽

Vol 5 (10) ◽

pp. 180738 ◽

Cited By ~ 2

Author(s):

Yang Liu ◽

Chun-li Zhu ◽

Xiao-yuan Zheng ◽

Liu-lei Qin ◽

Shuang-xi Yang ◽

...

Keyword(s):

Phase Transition ◽

Nitro Group ◽

Dielectric Material ◽

Variable Temperature ◽

Three Dimensional ◽

Dielectric Anisotropy ◽

Scanning Calorimetry ◽

Hybrid Compound ◽

Inorganic Hybrid ◽

Reversible Phase Transition

An organic–inorganic hybrid compound with an extensive three-dimensional (3D) crystal structure, (3-nitroanilinium) 2 (18-crown-6) 2 (H 2 PO 4 ) 2 (H 3 PO 4 ) 3 (H 2 O) ( 1 ), was synthesized under slow evaporation conditions. Differential scanning calorimetry measurements indicated that 1 underwent a reversible phase transition at ca 231 K with a hysteresis width of 10 K. Variable-temperature X-ray single-crystal diffraction revealed that the phase transition of 1 can be ascribed to coupling of pendulum-like motions of its nitro group with proton transfer in O–H···O hydrogen bonds of the 3D framework. The temperature dependence of its dielectric permittivity demonstrated a step-like change in the range of 150–280 K with remarkable dielectric anisotropy, making 1 a promising switchable dielectric material. Potential energy calculations further supported the possibility of dynamic motion of the cationic nitro group. Overall, our findings may inspire the development of other switchable dielectric phase transition materials by introducing inorganic anions into organic–inorganic hybrid systems.

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Dielectric and nonlinear optical dual switching in an organic–inorganic hybrid relaxor [(CH3)3PCH2OH][Cd(SCN)3]

Inorganic Chemistry Frontiers ◽

10.1039/c7qi00300e ◽

2017 ◽

Vol 4 (9) ◽

pp. 1445-1450 ◽

Cited By ~ 11

Author(s):

Xuan Zheng ◽

Ping-Ping Shi ◽

Yang Lu ◽

Lin Zhou ◽

Ji-Xing Gao ◽

...

Keyword(s):

Phase Transition ◽

Nonlinear Optical ◽

Inorganic Hybrid ◽

Reversible Phase Transition ◽

Reversible Phase

[(CH3)3PCH2OH][Cd(SCN)3] exhibits dielectric and nonlinear optical dual switching with reversible phase transition as an organic–inorganic hybrid relaxor.

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