Dielectric and nonlinear optical dual switching in an organic–inorganic hybrid relaxor [(CH3)3PCH2OH][Cd(SCN)3]

[(CH3)3PCH2OH][Cd(SCN)3] exhibits dielectric and nonlinear optical dual switching with reversible phase transition as an organic–inorganic hybrid relaxor.

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Reversible phase transition, switchable dielectric response in In(III)‐based organic–inorganic hybrid compound: [C 3 H 8 N] 3 InBr 6

Applied Organometallic Chemistry ◽

10.1002/aoc.6354 ◽

2021 ◽

Author(s):

Yin‐Qiang Zhang ◽

Min Li ◽

Guan‐Cheng Xu

Keyword(s):

Phase Transition ◽

Dielectric Response ◽

Hybrid Compound ◽

Inorganic Hybrid ◽

Compound C ◽

Reversible Phase Transition ◽

Reversible Phase

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A single layered organic-inorganic hybrid compound [(FBMA)2PbBr4] with reversible phase transition and intense fluorescent property

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2018.11.012 ◽

2019 ◽

Vol 270 ◽

pp. 226-230 ◽

Cited By ~ 2

Author(s):

Yanhuan Hao ◽

Shuyao Wen ◽

Jiaojiao Yao ◽

Zhenhong Wei ◽

Xiuxiu Zhang ◽

...

Keyword(s):

Phase Transition ◽

Fluorescent Property ◽

Hybrid Compound ◽

Inorganic Hybrid ◽

Reversible Phase Transition ◽

Reversible Phase

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Ba3Mg3(BO3)3F3 polymorphs with reversible phase transition and high performances as ultraviolet nonlinear optical materials

Nature Communications ◽

10.1038/s41467-018-05575-w ◽

2018 ◽

Vol 9 (1) ◽

Cited By ~ 88

Author(s):

Miriding Mutailipu ◽

Min Zhang ◽

Hongping Wu ◽

Zhihua Yang ◽

Yihan Shen ◽

...

Keyword(s):

Phase Transition ◽

Optical Materials ◽

Nonlinear Optical ◽

Nonlinear Optical Materials ◽

Reversible Phase Transition ◽

Reversible Phase

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Multisequential reversible phase transition materials with Semiconducting and fluorescence properties：(C8H18BrN)2SnBr6

New Journal of Chemistry ◽

10.1039/d1nj04448f ◽

2021 ◽

Author(s):

Yao Liu ◽

Yu-Kong Li ◽

Ting-Ting Ying ◽

Yu-Hui Tan ◽

Yun Zhi Tang ◽

...

Keyword(s):

Phase Transition ◽

Dielectric Properties ◽

Dielectric Material ◽

Fluorescence Properties ◽

Metal Halides ◽

Inorganic Hybrid ◽

Reversible Phase Transition ◽

Reversible Phase

Organic-inorganic hybrid metal halides with dielectric properties have attracted widespread attention due to their applications in the field of optoelectronics. Here, we successfully synthesized a novel dielectric material (C8H18BrN)2SnBr6 (1),...

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Two bilayer organic-inorganic hybrid perovskite compounds exhibiting reversible phase transition and dielectric anomalies

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2019.121104 ◽

2020 ◽

Vol 282 ◽

pp. 121104 ◽

Cited By ~ 1

Author(s):

Jiang ZhenTao ◽

Hao Yanhuan ◽

Wang Hui ◽

Zhang Xiuxiu ◽

Yao Jiaojiao ◽

...

Keyword(s):

Phase Transition ◽

Inorganic Hybrid ◽

Hybrid Perovskite ◽

Reversible Phase Transition ◽

Reversible Phase

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Reversible Phase Transition, Switchable Second‐Order Nonlinear Optical and Dielectric Properties in a Bismuth(III)‐Based Compound: (R)‐3‐(Fluoropyrrolidinium) 2 BiBr 5

European Journal of Inorganic Chemistry ◽

10.1002/ejic.202000064 ◽

2020 ◽

Vol 2020 (17) ◽

pp. 1631-1634

Author(s):

BiQin Wang ◽

Yan Li ◽

Hao Xie

Keyword(s):

Phase Transition ◽

Dielectric Properties ◽

Nonlinear Optical ◽

Second Order ◽

Reversible Phase Transition ◽

Reversible Phase

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Tin based organic–inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

Dalton Transactions ◽

10.1039/d0dt01401j ◽

2020 ◽

Vol 49 (21) ◽

pp. 7252-7257 ◽

Cited By ~ 2

Author(s):

Xiuli You ◽

Jiaojiao Yao ◽

Zhenhong Wei

Keyword(s):

Phase Transition ◽

Dielectric Anomaly ◽

Organic Amine ◽

Inorganic Hybrid ◽

Hybrid Compounds ◽

Reversible Phase Transition ◽

Hybrid Semiconductors ◽

Reversible Phase

Two discrete tin based organic–inorganic hybrid compounds [(FMBA)2SnX6] (X = Cl and Br) showed reversible phase transition and dielectric anomaly above 400 K which were originated from the order-disorder of a fluorine-substituted organic amine.

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Above Room Temperature Reversible Phase Transition Induces Distinct Dielectric and Nonlinear Optical Switching Response Behavior in Crown-Ether-Based Supramolecular Clathrate

Crystals ◽

10.3390/cryst9040184 ◽

2019 ◽

Vol 9 (4) ◽

pp. 184 ◽

Cited By ~ 1

Author(s):

Jing Jing ◽

Fan Jiang ◽

Yan-Li Wei ◽

Chao Shi ◽

Heng-Yun Ye ◽

...

Keyword(s):

Phase Transition ◽

Crown Ether ◽

Optical Switching ◽

Nonlinear Optical ◽

Thermal Hysteresis ◽

Switching Behavior ◽

Stimuli Responsive ◽

Scanning Calorimetry ◽

Reversible Phase Transition ◽

Reversible Phase

Stimuli-responsive materials with coexisting nonlinear optical (NLO) and dielectric properties are technologically important, which enable simultaneous conversion of optoelectronic properties between different states under external stimuli. By rationally screening guest cations (C6H5NF2)+ in the crown-ether inclusion system, we synthesized a crown-ether supramolecular compound [(C6H5NF2)(18-crown-6)][PF6] (1). Differential scanning calorimetry (DSC) showed that 1 undergoes a reversible phase transition above room temperatures (305 K/292 K), with a thermal hysteresis of 13 K. Temperature-dependent dielectric and NLO measurements show that the compound exhibits two distinct switching response behaviors. Structural analysis indicates that the order–disorder change of the host molecule 18-crown-6 and the guest organic cation during the phase transition induces the dielectric and NLO switching behavior of the compound.

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Two In-Based Organic−Inorganic Hybrid Compounds with Reversible Phase Transition Derived from Order-Disorder Changes of Cations or Anions

Dalton Transactions ◽

10.1039/d1dt01935j ◽

2021 ◽

Author(s):

Yin-Qiang Zhang ◽

Guan-Cheng Xu ◽

Min Li

Keyword(s):

Phase Transition ◽

Solid State ◽

Physical Properties ◽

Ferroelectric Properties ◽

Inorganic Hybrid ◽

Hybrid Compounds ◽

Reversible Phase Transition ◽

Reversible Phase

Solid-state phase transition materials have been received extraordinary interest due to their rich physical properties, such as the thermal, dielectric, and ferroelectric properties. Here, two In-based organic-inorganic hybrid compounds, (C6H5CH2CH2NH3)3[InBr5(H2O)]...

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Reversible phase transition driven by order–disorder transformations of metal-halide moieties in [(C6H14)NH2]2·CuBr4

Journal of Materials Chemistry C ◽

10.1039/c6tc02034h ◽

2016 ◽

Vol 4 (32) ◽

pp. 7537-7540 ◽

Cited By ~ 25

Author(s):

Muhammad Adnan Asghar ◽

Shuquan Zhang ◽

Tariq Khan ◽

Zhihua Sun ◽

Aurang Zeb ◽

...

Keyword(s):

Phase Transition ◽

Order Phase Transition ◽

Hybrid Material ◽

Metal Halide ◽

Inorganic Hybrid ◽

First Order ◽

First Order Phase Transition ◽

Reversible Phase Transition ◽

First Order Phase ◽

Reversible Phase

[(C6H14)NH2]2·CuBr4 (1), an organic–inorganic hybrid material, undergoes a reversible first-order phase transition around 194 K, triggered by the order–disorder transformation of metal-coordinated halogen atoms.

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