Two In-Based Organic−Inorganic Hybrid Compounds with Reversible Phase Transition Derived from Order-Disorder Changes of Cations or Anions

2021 ◽  
Author(s):  
Yin-Qiang Zhang ◽  
Guan-Cheng Xu ◽  
Min Li

Solid-state phase transition materials have been received extraordinary interest due to their rich physical properties, such as the thermal, dielectric, and ferroelectric properties. Here, two In-based organic-inorganic hybrid compounds, (C6H5CH2CH2NH3)3[InBr5(H2O)]...


2020 ◽  
Vol 49 (21) ◽  
pp. 7252-7257 ◽  
Author(s):  
Xiuli You ◽  
Jiaojiao Yao ◽  
Zhenhong Wei

Two discrete tin based organic–inorganic hybrid compounds [(FMBA)2SnX6] (X = Cl and Br) showed reversible phase transition and dielectric anomaly above 400 K which were originated from the order-disorder of a fluorine-substituted organic amine.



2003 ◽  
Vol 32 (11) ◽  
pp. 1002-1003 ◽  
Author(s):  
Seiji Watase ◽  
Takayuki Kitamura ◽  
Nobuko Kanehisa ◽  
Masami Nakamoto ◽  
Yasushi Kai ◽  
...  


2019 ◽  
Vol 270 ◽  
pp. 226-230 ◽  
Author(s):  
Yanhuan Hao ◽  
Shuyao Wen ◽  
Jiaojiao Yao ◽  
Zhenhong Wei ◽  
Xiuxiu Zhang ◽  
...  




2021 ◽  
Author(s):  
Yao Liu ◽  
Yu-Kong Li ◽  
Ting-Ting Ying ◽  
Yu-Hui Tan ◽  
Yun Zhi Tang ◽  
...  

Organic-inorganic hybrid metal halides with dielectric properties have attracted widespread attention due to their applications in the field of optoelectronics. Here, we successfully synthesized a novel dielectric material (C8H18BrN)2SnBr6 (1),...



2020 ◽  
Vol 282 ◽  
pp. 121104 ◽  
Author(s):  
Jiang ZhenTao ◽  
Hao Yanhuan ◽  
Wang Hui ◽  
Zhang Xiuxiu ◽  
Yao Jiaojiao ◽  
...  


1987 ◽  
Vol 2 (1) ◽  
pp. 36-38 ◽  
Author(s):  
M. Auray ◽  
M. Quarton ◽  
P. Tarte

AbstractTwo molybdates MIV (MoO4)2 (with MIV = Hf or Zr) were synthesized by solid state reaction between MIVO2 and MoO3. Zirconium molybdate undergoes a reversible phase transition at 952 K.Hf(MoO4)2 and H.T. Zr(MoQ4)2, obtained as single crystals, are trigonal, space group with Z = 6; the cell dimensions are respectively a = 10.1005(3), c = 11.7230(5)Å; V = 1035.76(11)Å3; Dm(298 K) = 4.78(4), Dx = 4.792 Mg m−3 and a = 10.1409(3), c = 11.7097(5)Å; V = 1042.88(11)Å3; Dm (298 K) = 3.91(4), Dx = 3.926 Mg m−3.L.T. Zr(MoO4)2, indexed by the Visser automatic indexing program (1969) was found to be monoclinic, possible space group P2, P21 or Pm with Z = 4; the cell dimensions are a = 9.7557(5), b = 7.9373(5), c = 7.4631(4)Å, β = 97.959°(5); V = 572.3(5)Å Dm(298 K) = 4.74(5), Dx = 4.770 Mg m−3. Powder diffraction data were obtained at 293 K on a counter diffractometer with Ni-filtered copper radiation ( = 1.5418 Å).



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