Preparation of Co-MOF derived Co(OH)2/multiwalled carbon nanotubes as an efficient bifunctional electro catalyst for hydrazine and hydrogen peroxide detections

Author(s):  
Narasimha Murthy Umesh ◽  
Karuppasamy Kohila rani ◽  
Rajkumar Devasenathipathy ◽  
Balasubramanian Sriram ◽  
Yi-Xin Liu ◽  
...  
2002 ◽  
Vol 01 (03n04) ◽  
pp. 277-283 ◽  
Author(s):  
M. CROSTON ◽  
J. LANGSTON ◽  
R. SANGOI ◽  
K. S. V. SANTHANAM

The oxidation of p-toluidine in acetonitrile by hydrogen peroxide is a very slow reaction which produces 4,4'-dimethylazoxybenzene as the product. The presence of functionalized multiwalled carbon nanotubes (CNT) in the above reaction produces 4,4'-dimethylazobenzene. The reactions have been followed by GC/MS, which show the following mass nos.: 226,92 (without CNT) and 210,120,92,28 (with CNT). UV-VIS absorption spectroscopy shows maximum corresponding to 4,4'-dimethylazobenzene at 444 nm. The rate of formation of 4,4'-dimethylazobenzene has been determined as 0.0093 s -1.


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