Silica coating of Zn2Al/4-hydroxy-3-methoxybenzoic acid nanocomposites via seeded polymerization technique

2005 ◽  
Vol 89 (1) ◽  
pp. 154-158 ◽  
Author(s):  
Ahmed Mohamed El-Toni ◽  
Shu Yin ◽  
Tsugio Sato
2006 ◽  
Vol 252 (14) ◽  
pp. 5063-5070 ◽  
Author(s):  
Ahmed Mohamed El-Toni ◽  
Shu Yin ◽  
Tsugio Sato

Author(s):  
Yoshio Kobayashi ◽  
Kiyoto Misawa ◽  
Masaki Kobayashi ◽  
Motohiro Takeda ◽  
Mikio Konno ◽  
...  

e-Polymers ◽  
2005 ◽  
Vol 5 (1) ◽  
Author(s):  
Yoshio Kobayashi ◽  
Kiyoto Misawa ◽  
Masaki Kobayashi ◽  
Motohiro Takeda ◽  
Mikio Konno ◽  
...  

AbstractSubmicron-sized polystyrene spheres incorporating fluorescence dyes (fluorescent microspheres) were coated with silica by means of a seeded polymerization technique based on the Stöber method. Silica-coating of the fluorescent microspheres with a size of 100 nm was performed in the presence of 0 - 10 g/l polyvinylpyrrolidone (PVP), 1 - 13 mol/l water, 0 - 0.8 mol/l aq. ammonia and 0.00038 - 0.2 mol/l tetraethoxyorthosilicate (TEOS). The addition of PVP was found to suppress the generation of free silica particles and produced no shell-free fluorescent microspheres improving the uniformity of shell thickness of silicacoated fluorescent microspheres. Silica shell thickness increased from 11 to 63 nm with increasing TEOS concentration at 10 g/l PVP, 0.4 mol/l aq. ammonia and 11 mol/l water. Silica-coated fluorescent microspheres showed more stable fluorescence to laser-irradiation than uncoated fluorescent microspheres.


2006 ◽  
Vol 45 ◽  
pp. 673-678 ◽  
Author(s):  
Ahmed Mohamed El-Toni ◽  
Shu Yin ◽  
Tsugio Sato

Calcia-doped ceria is of potential interest as an ultraviolet (UV) radiation blocking material in personal care products because of its excellent UV light absorption property and low catalytic ability for the oxidation of organic materials superior to undoped ceria. The performance of calcia doped ceria needs more enhancement through further control of its oxidation catalytic activity and improvement of its covering ability. In order to reduce the oxidation catalytic activity further, calcia-doped ceria was coated with amorphous silica by means of seeded polymerization technique. Generally, nanoparticles of calcia doped ceria do not provide a good coverage for human skin because of the agglomeration of the nanoparticles. The platy particles are required to enhance the covering ability of calcia doped ceria. This can be accomplished by synthesis of calcia-doped ceria/plate-like material (e.g., potassium lithium titanate (K0.8Li0.27Ti1.73O4) and mica) nanocomposite with subsequent silica coating. Calcia-doped ceria/plate-like material was prepared by soft chemical method followed by silica coating via seeded polymerization technique. Silica coated calcia-doped ceria/plate-like material nanocomposite was characterized by X-ray diffraction, SEM, TEM, XPS and FT-IR.


2006 ◽  
Vol 45 ◽  
pp. 685-690
Author(s):  
Tsugio Sato ◽  
Ahmed Mohamed El-Toni ◽  
Shu Yin ◽  
Rui Xing Li ◽  
Hisao Hidaka

White nanoparticles of calcia-doped ceria were prepared from the precipitate by reacting CeCl3-CaCl2 mixed solution with NaOH solution at pH 12 and the oxidation with hydrogen peroxide solution at 40oC, followed by the calcination at 700oC for 1 h. The sample before calcination contained significant amount of OH- in the lattice and was yellow, but the powders calcined above 700oC were white, indicating that cationic defect formed by replacing O2- with OH- played as the color center. Calcia-doped ceria particles were coated with amorphous silica by means of seeded polymerization technique using hydrolysis of tetraethylorthosilicate (TEOS) or acid hydrolysis of sodium silicate. The silica coating by seeded polymerization with TEOS was much more efficient for the reduction of catalytic activity of ceria for the oxidation of organic materials than that by acid hydrolysis of sodium silicate. It is confirmed that ceria particles caused far less damage to the DNA plasmids upon UV illumination than either the titania or the zinc oxide reference pigments.


Author(s):  
J. W. Mellowes ◽  
C. M. Chun ◽  
I. A. Aksay

Mullite (3Al2O32SiO2) can be fabricated by transient viscous sintering using composite particles which consist of inner cores of a-alumina and outer coatings of amorphous silica. Powder compacts prepared with these particles are sintered to almost full density at relatively low temperatures (~1300°C) and converted to dense, fine-grained mullite at higher temperatures (>1500°C) by reaction between the alumina core and the silica coating. In order to achieve complete mullitization, optimal conditions for coating alumina particles with amorphous silica must be achieved. Formation of amorphous silica can occur in solution (homogeneous nucleation) or on the surface of alumina (heterogeneous nucleation) depending on the degree of supersaturation of the solvent in which the particles are immersed. Successful coating of silica on alumina occurs when heterogeneous nucleation is promoted and homogeneous nucleation is suppressed. Therefore, one key to successful coating is an understanding of the factors such as pH and concentration that control silica nucleation in aqueous solutions. In the current work, we use TEM to determine the optimal conditions of this processing.


TAPPI Journal ◽  
2016 ◽  
Vol 15 (8) ◽  
pp. 515-521 ◽  
Author(s):  
EIJA KENTTÄ ◽  
HANNA KOSKELA ◽  
SARA PAUNONEN ◽  
KARITA KINNUNEN-RAUDASKOSKI ◽  
TUOMO HJELT

This paper reports experiments on silica coating formulations that are suitable for application as a thin pigment layer with foam coating technique on a paper web. To understand the foaming properties of nanosilica dispersions, the critical micelle concentration, foam half-life time, and foam bubble size stability were determined with three different foaming agents. The results indicate that the bubble stability measurement is a useful characterization method for foam coating purposes. Pilot foam coating trials were done and the effects of the chosen foaming agents were studied on the properties of the nanosilica-coated paper. The surface hydrophilicity of silica coated paper was related not only to silica pigment, but also to the chemical nature of the foaming agent. Standard paper properties were not affected by the thin silica coating.


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