Metal organic framework-supported N -heterocyclic carbene palladium complex: A highly efficient and reusable heterogeneous catalyst for Suzuki-Miyaura C-C coupling reaction

2017 ◽  
Vol 253 ◽  
pp. 102-111 ◽  
Author(s):  
Mehrnaz Bahadori ◽  
Shahram Tangestaninejad ◽  
Majid Moghadam ◽  
Valiollah Mirkhani ◽  
Adam Mechler ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Palladium Complex ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

Production of ultra-deep sulfur-free diesels using a sustainable catalytic system based on UiO-66(Zr)

2015 ◽  
Vol 51 (72) ◽  
pp. 13818-13821 ◽  
Author(s):  
Carlos M. Granadeiro ◽  
Susana O. Ribeiro ◽  
Mohamed Karmaoui ◽  
Rita Valença ◽  
Jorge C. Ribeiro ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Catalytic System ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Highly Efficient ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

The porous metal–organic framework UiO-66(Zr) is a remarkable and highly efficient heterogeneous catalyst for the production of sulfur-free diesels.

Ferrocenyl metal–organic framework hollow microspheres for in situ loading palladium nanoparticles as a heterogeneous catalyst

2019 ◽  
Vol 48 (24) ◽  
pp. 8995-9003 ◽  
Author(s):  
Zheng Deng ◽  
Yi Guo ◽  
Zhuoyi Li ◽  
Xiaobin Wang ◽  
Xinsheng Peng ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Pd Nanoparticles ◽  
Hollow Microspheres ◽  
Highly Efficient ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

Zn–Fc MOF hollow microspheres were prepared for the in situ reduction of Pd2+ into Pd nanoparticles as a highly efficient heterogeneous catalyst.

scholarly journals A base-free Chan–Lam reaction catalyzed by an easily assembled Cu(II)-carboxylate metal-organic framework

2021 ◽  
pp. 174751982110265
Author(s):  
Xinhai Zhang ◽  
Jianhua Qin ◽  
Ruixuan Ma ◽  
Lei Shi
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
High Catalytic Activity ◽  
Arylboronic Acids ◽  
Metal Organic ◽  
Organic Framework

A new copper(II) metal-organic framework is constructed as a sustainable copper heterogeneous catalyst. Cu-DPTCA, with high catalytic activity, can effectively promote the Chan–Lam coupling reaction of arylboronic acids and amines without adding any base or additive.

scholarly journals Synthesis of diphenyl sulfide from iodobenzene and thiophenol using Metal-Organic Framework Cu2(NDC)2(DABCO) as an efficient heterogeneous catalyst

2020 ◽  
Vol 9 (4) ◽  
pp. 70-76
Author(s):  
Chi Nguyen Van ◽  
Giao Dang Huynh ◽  
Tung Nguyen Thanh ◽  
Anh Phan Nguyen Quynh ◽  
Nam Phan Thanh Son
Keyword(s):  
Electron Microscopy ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
Copper Nitrate ◽  
Major Product ◽  
Solid Catalyst ◽  
Diphenyl Sulfide ◽  
Metal Organic ◽  
Organic Framework

A metal-organic framework Cu2(NDC)2(DABCO) was synthesized from copper nitrate trihydrate, 2,6-Napthalenedicarboxylic acid (H2NDC), and 1,4-diazabicyclo[2.2.2]octane (DABCO) by solvothermal method. Its physicochemical properties were confirmed by several techniques such as X-ray powder diffraction (PXRD), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Cu2(NDC)2(DABCO) appeared as well-shaped crystals. To get diphenyl sulfide as desired product from the C-S cross coupling reaction of iodobenzene and thiophenol, the Cu2(NDC)2(DABCO) was used as heterogeneous catalyst  in the presence of LiO-tBu as base. The results showed that the transformation could proceed with more than 93% reaction conversion being obtained after 6 h at 120 oC when using 5 mol% Cu2(NDC)2(DABCO) catalyst in the presence of LiO-tBu. The solid catalyst could be recovered and reused five times without a significant degradation in catalytic activity. The coupling reaction could only proceed to achieve major product in the presence of the Cu2(NDC)2(DABCO catalyst.

A porous metal–organic framework containing multiple active Cu2+sites for highly efficient cross dehydrogenative coupling reaction

2015 ◽  
Vol 44 (5) ◽  
pp. 2038-2041 ◽  
Author(s):  
Shu-Lan Zhu ◽  
Sha Ou ◽  
Min Zhao ◽  
Hong Shen ◽  
Chuan-De Wu
Keyword(s):  
Metal Organic Framework ◽  
Coupling Reaction ◽  
Porous Metal ◽  
Highly Efficient ◽  
Highly Active ◽  
Dehydrogenative Coupling ◽  
Metal Organic ◽  
Organic Framework

A 3D porous metal–organic framework, containing multiple coordination unsaturated CuIIsites, is highly active in the catalytic cross dehydrogenative coupling reaction.

Oriented assembly of copper metal–organic framework membranes as tandem catalysts to enhance C–H hydroxyalkynylation reactions with regiocontrol

CrystEngComm ◽  
2020 ◽  
Vol 22 (4) ◽  
pp. 802-810
Author(s):  
Chao Huang ◽  
Kaifang Zhu ◽  
Guizhen Lu ◽  
Yingying Zhang ◽  
Dandan Wang ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Bulk Crystals ◽  
Copper Metal ◽  
Highly Efficient ◽  
Metal Organic ◽  
Cu Foam ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

The continuous and uniform MOF-based membrane (1a) as a highly efficient heterogeneous catalyst was fabricated on porous Cu foam to significantly outperform bulk crystals 1 to execute C–H hydroxyalkynylation reactions with regiocontrol.

A size-matched POM@MOF composite catalyst for highly efficient and recyclable ultra-deep oxidative fuel desulfurization

2018 ◽  
Vol 5 (7) ◽  
pp. 1563-1569 ◽  
Author(s):  
Yun-Lei Peng ◽  
Jingyi Liu ◽  
Hai-Feng Zhang ◽  
Dong Luo ◽  
Dan Li
Keyword(s):  
Heterogeneous Catalyst ◽  
Phosphotungstic Acid ◽  
Metal Organic Framework ◽  
Oxidative Desulfurization ◽  
Composite Catalyst ◽  
Highly Efficient ◽  
Keggin Type ◽  
Catalytic Oxidative Desulfurization ◽  
Metal Organic ◽  
Organic Framework

A composite of Keggin-type phosphotungstic acid (H3PW12O40) encapsulated in sized-matched metal–organic framework UiO-67 (PW12@UiO-67) was prepared as a heterogeneous catalyst for extractive and catalytic oxidative desulfurization systems (ECODS).

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