Preparation of bifunctional core-shell structured Cu/TS-1@MCM-41 molecular sieves for synthesis of aniline by benzene in one step amination

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Kang Xue ◽  
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Jihai Duan
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Naohito Uemura ◽  
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Materials ◽  
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Vol 9 (9) ◽  
pp. 718 ◽  
Author(s):  
Yanli Zhang ◽  
Xiangming He ◽  
Li Wang ◽  
Jian Gao ◽  
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L. A. Matkovskaya ◽  
V. N. Solomakha ◽  
Yu. G. Gol’tsov

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Changqing Ma ◽  
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Xinbin Ma

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Tushar Shinde ◽  
Naděžda Žilková ◽  
Zdeněk Bastl

A commercially available Hoveyda–Grubbs type catalyst (RC303 Zhannan Pharma) was immobilized on mesoporous molecular sieves MCM-41 and on SBA-15 by direct interaction with the sieve wall surface. The immobilized catalysts exhibited high activity and nearly 100% selectivity in several types of alkene metathesis reactions. Ru leaching was found to depend on the substrate and solvent used (the lowest leaching was found for ring-closing metathesis of 1,7-octadiene in cyclohexane – 0.04% of catalyst Ru content). Results of XPS, UV–vis and NMR spectroscopy showed that at least 76% of the Ru content was bound to the support surface non-covalently and could be removed from the catalyst by washing with THF.


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