Improving surface sulfidization of azurite with ammonium bisulfate and its contribution to sulfidization flotation

2021 ◽  
Vol 171 ◽  
pp. 107072
Author(s):  
Qiuyue Sheng ◽  
Wanzhong Yin ◽  
Bin Yang ◽  
Shaohang Cao ◽  
Haoran Sun ◽  
...  
Keyword(s):  
Author(s):  
Yufan Bu ◽  
Limin Wang ◽  
Xiaoyang Wei ◽  
Lei Deng ◽  
Defu Che

Nitrogen oxide (NOx) emitted from boilers in coal-fired power plant may be reduced by 90 percent through the application of the selective catalytic reduction (SCR). However, the escaped ammonia from the SCR systems could react with sulfur oxides (SOx) in the flue gas to form ammonium bisulfate (ABS) in exhaust systems. The blockage and corrosion caused by ABS seriously impact the rotary air preheater (RAPH), which would not only increase operating cost on ash-blowing and cleaning but also lead to unplanned outage. To solve the problem, in this paper a novel preheater system is proposed. A single preheater is split into two sub-preheaters, between which the main flue gas flow is mixed with the recirculated flue gas from outlet of the lower-temperature preheater. After the mixing point, a reaction chamber and a precipitator are installed. A numerical finite difference method (FDM) is employed to model the RAPH and obtain the accurate temperature distribution of fluid and heat transfer elements. The initial formation temperatures of (NH4)2SO4 and ABS are 200 °C and 170 °C, respectively, according to the flue gas composition in this work. By calculation, this split design of the RAPH is believed to be effective in reducing deposition of ABS.


AIHAJ ◽  
1984 ◽  
Vol 45 (8) ◽  
pp. 567-571
Author(s):  
K.W. TU
Keyword(s):  

2019 ◽  
Vol 118 ◽  
pp. 03056
Author(s):  
Su Pan ◽  
Pengfeng Yu ◽  
Linbo Liu ◽  
Jing Han ◽  
Xiao Shen

In order to solve the problem of abnormal rise of the differential pressure of the revolving air preheater on 300MW unit, we analysed the causes of abnormal rise of the differential pressure of the air preheater and evaluated performances of control measures, through historical data mining and on-site inspection of the unit. The results show that, with the gradual decrease of environment temperature with the decrease of the exhaust gas temperature, the ashes in flue gas are bound by acid liquid produced by condensation of flue gas, and the adhesion areas of the ammonium bisulfate produced in the denitration process are enlarged. However the original set ash blowing pressure can no longer satisfy the requirements of the air preheater, giving rise to the differential pressure of the air preheater on both sides to rise. The reason of the higher differential pressure of the unilateral air preheater is that the large ammonia injection amount, leading to the increases of ammonia escape of the denitrification system. So the side of the air on preheater ammonium bisulfate type blockage is more serious. After the Measures of Adjusting distribution coefficient of ammonia supply valve on both sides, increasing the dust blowing frequency and pressure of the air preheater, the differential pressure of air preheater on both sides are close to the consistent. The decrease amplitude of the differential pressure of the air preheater on 280MW is about 300-500Pa.


1981 ◽  
Vol 85 (24) ◽  
pp. 3730-3733 ◽  
Author(s):  
A. W. Stelson ◽  
J. H. Seinfeld
Keyword(s):  

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