Simulations of Heat Supply Performance of a Deep Borehole Heat Exchanger under Different Scheduled Operation Conditions

With the changing world energy structure, the development of renewable energy sources is gradually accelerating. Among them, close attention has been given to geothermal energy because of its abundant resources and supply stability. In this article, a deep borehole heat exchanger (DBHE) is coupled with a heat pump system to calculate the heat supply and daily electricity consumption of the system. To make better use of the peaks and valleys in electricity prices, the following three daily operating modes were studied: 24-h operation (Mode 1), 8-h operation plus 16-h non-operation (Mode 2), and two cycles of 4-h operation and 8-h non-operation (Mode 3). Simulation results show that scheduled non-continuous operation can effectively improve the outlet temperature of the heat extraction fluid circulating in the DBHE. The heat extraction rates of Mode 1 is 190.9 kW for mass flowrate of 9 kg/s; in Mode 2 and Mode 3 cases, the rates change to 304.7 kW and 293.0 kW, respectively. The daily operational electricity cost of Mode 1 is the greatest because of 24-h operation; due to scheduled non-continuous operation, the daily operational electricity cost of Mode 3 is only about 66% of that of Mode 2. After an 8-month period without heating, the formation-temperature can be restored within 4 °C of its original state; 90% recovery of the formation-temperature can be achieved by the end of the second month of the non-operation season.

Study on Distribution of Wellbore Temperature in Gas Drilling with Gradient Equations

Precise calculation of gas temperature profile is the key to gas drilling design. It is traditionally assumed that the gas temperature distribution in the wellbore is equal to the formation temperature, without considering the influence of fluid flow and Joule-Thomson cooling effect. This paper puts forward a gradient equation method for gas temperature distribution in wellbore considering gas flow and Joule-Thomson local cooling of the bit. The method applies pressure, temperature, density, and velocity equations to gas flow in drillstrings and annulus. The solution of the gradient equation is in the form of the fourth-order Runge-Kutta equation. Bottom wellbore temperatures measured at depths of 700 to 2000 m in an actual well are consistent with those predicted by the gradient method. Due to the Joule-Thomson cooling effect at the bit nozzle, the temperature drops by about 30°C. The sensitivity analysis is carried out by gradient method, and the results show that the temperature drop range of different nozzle sizes can reach 60°C due to the Joule-Thomson cooling effect. Stable temperature curves can be established within a few minutes of the gas cycle. Due to the influence of gas flow and Joule-Thomson cooling, the gas temperature in the wellbore deviates significantly from the geothermal temperature in the formation under the flow condition. The temperature of the gas in drillstrings increases as the drill depth increases and then decreases rapidly near the bottom of the hole. As the gas flows upward along the annulus, the gas temperature rises first, surpasses the formation temperature, and then decreases gradually along the geothermal gradient trend.

Effect of CeO2 Size on Microstructure, Synthesis Mechanism and Refining Performance of Al-Ti-C Alloy

The effects of CeO2 size on the microstructure and synthesis mechanism of Al-Ti-C alloy were investigated using a quenching experiment method. A scanning calorimetry experiment was used to investigate the synthesis mechanism of TiC, the aluminum melt in situ reaction was carried out to synthesize master alloys and its refining performance was estimated. The results show that the Al-Ti-C-Ce system is mainly composed of α-Al, Al3Ti, TiC and Ti2Al20Ce. The addition of CeO2 obviously speeds up the progress of the reaction, reduces the size of Al3Ti and TiC and lowers the formation temperature of second-phase particles. When the size of CeO2 is 2–4 μm, the promotion effect on the system is most obvious. The smaller the size of CeO2, the smaller the size of Al3Ti and TiC and the lower the formation temperature. Al-Ti-C-Ce master alloy has a significant refinement effect on commercial pure aluminum. When the CeO2 size is 2–4 μm, the grain size of commercial pure aluminum is refined to 227 μm by Al-Ti-C-Ce master alloy.

Thorium, uranium and rare earth mineralization in rocks of the Ugakhan gold deposit, Bodaibo ore region (Irkutsk oblast)

The paper reports on the results of studies of ore-bearing rocks of the Ugakhan gold deposit (Bodaybo district): metasandstones, metasiltstones and carbonaceous shales. The rocks consist of quartz, feldspar (albite, orthoclase), Fe-Mg chlorite, mica (muscovite, sericite) and carbonates (calcite, dolomite, anker-ite) and accessory titanite, rutile, tourmaline, zircon and apatite. All rocks contain fragments of microfossils exhibiting striking concentric zonation with alternated dark (carbonaceous matter) and light (carbonate-mica material) layers. In a range from metasandstones to carbonaceous shales, the rocks exhibit an increase in mica amount and the content (up to 3%) of carbonaceous matter, as well as the formation of regeneration rims around relict tourmaline and zircon. The REE mineralization includes silicates (REE-bearing epidote, thorite), fuorocarbonates (bastnesite) and phosphates (monazite, xenotime, ankylite), which are closely related to U minerals (uraninite, cofnite). Bastnesite, ankylite and thorite formed due to the decomposition of earlier REE-bearing epidote, whereas monazite and xenotime are the products of decomposition of apatite. Uraninite formed during lithifcation of matrix of carbon-bearing rocks and is replaced by cofnite. The thermal analysis of carbonaceous matter and the formation temperature of chlorite calculated using chlorite geothermometer (296–371 °С) indicate the transformation of rocks under conditions of sericite-chlorite subfacies of greenschist facies of metamorphism.

Formation of giant iron oxide-copper-gold deposits by superimposed, episodic hydrothermal pulses

Iron oxide-copper-gold deposits are a globally important source of copper, gold and critical commodities. However, they possess a range of characteristics related to a variety of tectono-magmatic settings that make development of a general genetic model challenging. Here we investigate micro-textural and compositional variations in actinolite, to constrain the thermal evolution of the Candelaria iron oxide-copper-gold deposit in Chile. We identify at least two mineralization stages comprising an early 675–800 °C iron oxide-apatite type mineralization overprinted by a later copper-rich fluid at around 550–700 °C. We propose that these distinct stages were caused by episodic pulses of injection of magmatic-hydrothermal fluids from crystallizing magmas at depth. We suggest that the mineralisation stages we identify were the result of temperature gradients attributable to changes in the magmatic source, rather than variations in formation depth, and that actinolite chemistry can be used as a proxy for formation temperature in iron oxide-copper-gold systems.

Carbon Isotope Fractionation during the Formation of CO2 Hydrate and Equilibrium Pressures of 12CO2 and 13CO2 Hydrates

Knowledge of carbon isotope fractionation is needed in order to discuss the formation and dissociation of naturally occurring CO2 hydrates. We investigated carbon isotope fractionation during CO2 hydrate formation and measured the three-phase equilibria of 12CO2–H2O and 13CO2–H2O systems. From a crystal structure viewpoint, the difference in the Raman spectra of hydrate-bound 12CO2 and 13CO2 was revealed, although their unit cell size was similar. The δ13C of hydrate-bound CO2 was lower than that of the residual CO2 (1.0–1.5‰) in a formation temperature ranging between 226 K and 278 K. The results show that the small difference between equilibrium pressures of ~0.01 MPa in 12CO2 and 13CO2 hydrates causes carbon isotope fractionation of ~1‰. However, the difference between equilibrium pressures in the 12CO2–H2O and 13CO2–H2O systems was smaller than the standard uncertainties of measurement; more accurate pressure measurement is required for quantitative discussion.