Self-assembling behaviour of chiral calamitic monoacrylates targeted for polymer stabilisation of polar smectic phases in chiral liquid crystals

2021 ◽  
Vol 331 ◽  
pp. 115723
Author(s):  
Ewelina Dmochowska ◽  
Jakub Herman ◽  
Michał Czerwiński ◽  
Sergei Stulov ◽  
Alexej Bubnov ◽  
...  
Keyword(s):  
Liquid Crystals ◽  
Self Assembling ◽  
Smectic Phases ◽  
Chiral Liquid Crystals

scholarly journals Three-dimensional crystals of adaptive knots

Science ◽  
2019 ◽  
Vol 365 (6460) ◽  
pp. 1449-1453 ◽  
Author(s):  
Jung-Shen B. Tai ◽  
Ivan I. Smalyukh
Keyword(s):  
Numerical Modeling ◽  
Liquid Crystals ◽  
Colloidal Particles ◽  
Three Dimensional ◽  
Host Medium ◽  
Self Assembling ◽  
And Topology ◽  
Complex Boundary ◽  
Chiral Liquid Crystals ◽  
Helical Field

Starting with Gauss and Kelvin, knots in fields were postulated to behave like particles, but experimentally they were found only as transient features or required complex boundary conditions to exist and could not self-assemble into three-dimensional crystals. We introduce energetically stable, micrometer-sized knots in helical fields of chiral liquid crystals. While spatially localized and freely diffusing in all directions, they resemble colloidal particles and atoms, self-assembling into crystalline lattices with open and closed structures. These knots are robust and topologically distinct from the host medium, though they can be morphed and reconfigured by weak stimuli under conditions such as those in displays. A combination of energy-minimizing numerical modeling and optical imaging uncovers the internal structure and topology of individual helical field knots and the various hierarchical crystalline organizations that they form.

Dynamic Spirals of Nanoparticles in Light-Responsive Polygonal Fields

2019 ◽  
Author(s):  
Tetiana Orlova ◽  
Rémi Plamont ◽  
Alexis Depauw ◽  
Nathalie Katsonis
Keyword(s):  
Liquid Crystals ◽  
Soft Matter ◽  
Large Scale ◽  
Anisotropic Matter ◽  
Self Assembling ◽  
Localized Structures ◽  
Potential Applications ◽  
Biological World ◽  
Chiral Liquid Crystals ◽  
Topological Singularities

Nanoparticles tend to aggregate in an uncontrollable fashion once integrated into soft matter and consequently, self-assembling nanoparticles into large-scale, regular, well-defined patterns remains an ongoing challenge towards the design and realization of smart hybrid materials. The patterns of nanoparticles that have been reported in liquid crystals are static so far, and this lack of responsiveness extends to assemblies of nanoparticles formed in topological singularities and other localized structures of anisotropic matter. Here, we demonstrate the realization of light-responsive spirals of gold nanoparticles, by using a templating strategy that is common in the biological world. Specifically, we use polygonal fields of liquid crystals that incorporate molecular photo-switches in their composition, as light-responsive chiral templates. We also show that light modifies the period of the dynamic spirals of nanoparticles. These results confirm that using chiral liquid crystals as dynamic templates constitutes a versatile strategy towards soft photonic nanomaterials, and we anticipate that the possibility to control the period of the nanoparticulated pattern can find potential applications in the field of plasmonic sensing. <br>

Dynamic Spirals of Nanoparticles in Light-Responsive Polygonal Fields

2019 ◽  
Author(s):  
Tetiana Orlova ◽  
Rémi Plamont ◽  
Alexis Depauw ◽  
Nathalie Katsonis
Keyword(s):  
Liquid Crystals ◽  
Soft Matter ◽  
Large Scale ◽  
Anisotropic Matter ◽  
Self Assembling ◽  
Localized Structures ◽  
Potential Applications ◽  
Biological World ◽  
Chiral Liquid Crystals ◽  
Topological Singularities

Nanoparticles tend to aggregate in an uncontrollable fashion once integrated into soft matter and consequently, self-assembling nanoparticles into large-scale, regular, well-defined patterns remains an ongoing challenge towards the design and realization of smart hybrid materials. The patterns of nanoparticles that have been reported in liquid crystals are static so far, and this lack of responsiveness extends to assemblies of nanoparticles formed in topological singularities and other localized structures of anisotropic matter. Here, we demonstrate the realization of light-responsive spirals of gold nanoparticles, by using a templating strategy that is common in the biological world. Specifically, we use polygonal fields of liquid crystals that incorporate molecular photo-switches in their composition, as light-responsive chiral templates. We also show that light modifies the period of the dynamic spirals of nanoparticles. These results confirm that using chiral liquid crystals as dynamic templates constitutes a versatile strategy towards soft photonic nanomaterials, and we anticipate that the possibility to control the period of the nanoparticulated pattern can find potential applications in the field of plasmonic sensing. <br>

Microscopic ordering in smectic phases of liquid crystals

1990 ◽  
Vol 51 (18) ◽  
pp. 2015-2022 ◽  
Author(s):  
M. Zgonik ◽  
M. Rey-Lafon ◽  
C. Destrade ◽  
C. Leon ◽  
H.T. Nguyen
Keyword(s):  
Liquid Crystals ◽  
Smectic Phases

Evidence of two new ordered smectic phases in ferroelectric liquid crystals

1978 ◽  
Vol 39 (5) ◽  
pp. 548-553 ◽  
Author(s):  
J. Doucet ◽  
P. Keller ◽  
A.M. Levelut ◽  
P. Porquet
Keyword(s):  
Liquid Crystals ◽  
Ferroelectric Liquid Crystals ◽  
Smectic Phases

A 2*2 fiber optic switch using chiral liquid crystals

1990 ◽  
Vol 2 (2) ◽  
pp. 147-149 ◽  
Author(s):  
N.K. Shankar ◽  
J.A. Morris ◽  
C.P. Yakymyshyn ◽  
C.R. Pollock
Keyword(s):  
Liquid Crystals ◽  
Fiber Optic ◽  
Chiral Liquid Crystals

scholarly journals Optical Response Associated with the Orientation and Structure of Liquid Crystals with Respect to Phosphatidylcholine Concentration

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 678
Author(s):  
Yuqi Han ◽  
Yan Jiang ◽  
Wei Guo ◽  
Bing Li ◽  
Lu Zhang ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Reflectance Spectrum ◽  
Optical Response ◽  
The Self ◽  
Cholesteric Liquid Crystals ◽  
Anchoring Effect ◽  
Self Assembling ◽  
Sensitization Effect ◽  
Structure Of Liquid

Based on the anchoring effect due to the self-assembling behavior of the phospholipid molecules at the interface between the liquid crystal and water phases on the orientation of liquid crystals, the optical response associated with the orientation and structure of liquid crystals with respect to the concentration of 1,2-didodecanoyl-sn-glycero-3-phosphocholine solution has been investigated. The optical response owing to changes in the orientation and structure of the mixed cholesteric liquid crystals with respect to the change in the concentration of phosphatidylcholine has been obtained. Moreover, the feasibility of using as-prepared mixed cholesteric liquid crystals to measure the phosphatidylcholine concentration has been verified. A methodology to measure the reflectance spectrum by using mixed cholesteric liquid crystals to sensitize the phosphatidylcholine concentration has been further realized. The sensitization effect of the mixed cholesteric liquid crystals on the measurement of phosphatidylcholine concentration was also verified.

OPTICAL ACTIVITY AND LIGHT SCATTERING IN HIGHLY CHIRAL LIQUID CRYSTALS

1992 ◽  
Vol 06 (08) ◽  
pp. 425-446 ◽  
Author(s):  
PETER J. COLLINGS
Keyword(s):  
Liquid Crystals ◽  
Light Scattering ◽  
Optical Activity ◽  
Smectic A ◽  
Scattering Effects ◽  
Smectic A Phase ◽  
Blue Phases ◽  
Chiral Liquid Crystals

Theoretical and experimental optical activity and light scattering work in highly chiral liquid crystals is reviewed, starting from the early studies twenty years ago and ending with the most current investigations. Pretransitional effects in the isotropic and smectic A phases of highly chiral liquid crystals are discussed, as well as optical activity and light scattering effects in both the blue phases and smectic A * phase.

Sign in / Sign up

Export Citation Format

Share Document