Acoustic performance of a metascreen-based coating for maritime applications

Time and frequency domain numerical models are developed to investigate the acoustic performance of metasurface coatings for marine applications. The coating designs are composed of periodic air-filled cavities embedded in a soft elastic medium, which is attached to a hard backing and submerged in water. Numerical results for a metamaterial coating with cylindrical cavities are favourably compared with analytical and experimental results from the literature. Frequencies associated with peak sound absorption as a function of the geometric parameters of the cavities and material properties of the host medium are predicted. Variation in the cavity dimensions that modifies the cylindrical-shaped cavities to flat disks or thin needles is modelled. Results reveal that high sound absorption occurs when either the diameter or length of the cavities is reduced. Physical mechanisms governing sound absorption for the various cavity designs are described.

Open-source implementation of the discrete-dipole approximation for a scatterer in an absorbing host medium

Theoretical description of light scattering by single particles is a well-developed field, but most of it applies to particles located in vacuum or non-absorbing host medium. Although the case of absorbing host medium has also been discussed in literature, a complete description and unambiguous definition of scattering quantities are still lacking. Similar situation is for simulation methods – some computer codes exist, but their choice is very limited, compared to the case of vacuum. Here we describe the extension of the popular open-source code ADDA to support the absorbing host medium. It is based on the discrete dipole approximation and is, thus, applicable to particles with arbitrary shape and internal structure. We performed test simulations for spheres and compared them with that using the Lorenz-Mie theory. Moreover, we developed a unified description of the energy budget for scattering by a particle in a weakly absorbing host medium, relating all existing local (expressed as volume integrals over scatterer volume) and far-field scattering quantities.

Electron-energy-loss spectroscopy and cathodoluminescence for particles inside substrate

To simulate the interaction of a nanoparticle with an electron beam, we previously developed a theoretical description for the general case of a particle fully embedded in an infinite arbitrary host medium. The theory is based on the volume-integral variant of frequency-domain Maxwell’s equations and, therefore, is naturally applicable in the discrete-dipole approximation. The fully-embedded approximation allows fast numerical simulations of the experiments for particles inside a substrate since the host medium discretization is not needed. In this work, we study how applicable the fully-embedded approach is for realistic scenarios with relatively thin substrates. In particular, we performed test simulations for a silver sphere both inside an infinite host medium and inside a finite box or sphere. For the host medium, we considered two non-absorbing cases (the denser one causes Cherenkov radiation), as well as an absorbing case. The peak positions in the obtained spectra approximately agree between substrates a few times thicker than the sphere and the infinite one. However, a much thicker substrate (of the order of μm) would be required to have a qualitative agreement for absolute peak amplitudes. The developed algorithm is implemented in the open-source code ADDA, allowing one to rigorously and efficiently simulate electron-energy-loss spectroscopy and cathodoluminescence by particles of arbitrary shape and internal structure embedded into any homogeneous host medium.

Effect of ring-shaped clusters on magnetic hyperthermia: modelling approach

Experiments demonstrate that magnetic nanoparticles, embedded in a tissue, very often form heterogeneous structures of various shapes and topologies. These structures (clusters) can significantly affect macroscopical properties of the composite system, in part its ability to generate heat under an alternating magnetic field (so-called magnetic hyperthermia). If the energy of magnetic interaction between the particles significantly exceeds the thermal energy of the system, the particles can form the closed ring-shaped clusters. In this work, we propose a relatively simple model of the heat production by the particles united in the ‘ring’ and immobilized in a host medium. Mathematically, this model is based on the phenomenological Debye equation of kinetics of the particles remagnetization. Magnetic interaction between all particles in the cluster is taken into account. Our results show that the appearance of the clusters can significantly decrease the thermal effect. This article is part of the theme issue ‘Transport phenomena in complex systems (part 1)’.

Synthesis and Simulation of Nano-Composite Metamaterial for Broadband Negative Refractive Index in Visible Spectral Regime

In this paper, a nano-metamaterial with the structure of Ag-SiO2-PbTe is proposed that has a random arrangement in the host medium of expanded polystyrene (foam) for the realization of a broadband negative refractive index at the visible spectrum. The negative refractive index for the purposed meta-material was obtained from the plasmonic resonance in the core and outer layer for both electric and magnetic components of light. Here, we use different radii for the outer layer of nanoparticles to create the broadband negative permeability. In this way, the doped semiconductor nanoparticles are included in the host medium to create the broadband negative permittivity. The overlap between the spectrum of the negative permittivity and permeability introduces the broadband negative refractive index at the visible band. The novel introduced structure creates the broadband negative refractive index and it is simple and practical for fabrication. For the realization of the proposed material, synthesis and characterization of the designed nanocomposite structure are investigated. To this end, the absorption and the transmission coefficients of the synthesized material are measured and compared with theoretical results. The obtained results indicate that the numerical simulations using Mie theory have good agreement with the experimental results.

Plasmonic Properties of Bimetallic Quantum Dot Ag@Au Core-Shell Nanostructures Embedded in Non-Absorptive Host Medium

This studies the plasmonic properties of the bimetallic quantum dot Ag@Au core-shell nanostructures embedded in the non-absorbent host medium. Local field enhancement factor and coefficient of absorption of Ag-core and Au-shell are primarily studied based on quasi-static approximation of classical electrodynamics for 6-10 nm composite radius. In this quantum dot geometry, two set of plasmonic resonances in visible spectral region are observed: the first resonance associated with inner interface of gold (Ag@Au) and the second resonance associated with outer interface of gold (Au@medium). The two plasmonic resonances are close each other and enhanced when the size of composite decreased for a fixed core size while shifted to in opposite direction and the amplitude of peak decreased when the core size is increased for a fixed composite size. For the optimized size of core/composite or shell thickness and other parameters to the desired values, such type of composites are recommended for various applications like; photocatalysis, biomedical, nano-optoelectronics.

Extinction, absorption, and scattering of light by plasmonic spheres embedded in an absorbing host medium

Although the general Lorenz-Mie formalism for spheres in an absorbing host has been developed, no correct analytical expressions in the small-particle limit have been published so far. Here, we derive...

Theory of optical tweezing of dielectric microspheres in chiral host media and its applications

We report for the first time the theory of optical tweezers of spherical dielectric particles embedded in a chiral medium. We develop a partial-wave (Mie) expansion to calculate the optical force acting on a dielectric microsphere illuminated by a circularly-polarized, highly focused laser beam. When choosing a polarization with the same handedness of the medium, the axial trap stability is improved, thus allowing for tweezing of high-refractive-index particles. When the particle is displaced off-axis by an external force, its equilibrium position is rotated around the optical axis by the mechanical effect of an optical torque. Both the optical torque and the angle of rotation are greatly enhanced in the presence of a chiral host medium when considering radii a few times larger than the wavelength. In this range, the angle of rotation depends strongly on the microsphere radius and the chirality parameter of the host medium, opening the way for a quantitative characterization of both parameters. Measurable angles are predicted even in the case of naturally occurring chiral solutes, allowing for a novel all-optical method to locally probe the chiral response at the nanoscale.